The volatile organic compounds in male and female urine were analyzed using P&T/GC-MS.More than 70 VOCs in samples were identified.Identification of compound were based on NIST05 library and relative references.Co...The volatile organic compounds in male and female urine were analyzed using P&T/GC-MS.More than 70 VOCs in samples were identified.Identification of compound were based on NIST05 library and relative references.Compounds in double urines included short-chain alcohols,ketones,aldehyde,sulfether,aliphatic hydrocarbon,aromatic hydrocarbon and chlorinated hydrocarbon.The nicotine in urine was identified.The source of VOCs in urine was briefly discussed in the article.展开更多
In modern gas turbines, rim seal located between the stator-disc and rotor-disc is used to prevent hot-gas ingestion into the inner stage-gap of high pressure turbine. However, the purge flow supplied to the cavity th...In modern gas turbines, rim seal located between the stator-disc and rotor-disc is used to prevent hot-gas ingestion into the inner stage-gap of high pressure turbine. However, the purge flow supplied to the cavity through the rim seal interacts with the main flow, producing additional aerodynamic loss due to the mixing process which plays a significant role in the formation, development and evolution of downstream secondary flow. In this paper, a set of cascade representative of low aspect ratio turbine is selected to numerically investigate the influence of upstream cavity purge flow on the hub secondary flow structure and aerodynamic loss. Cascade with/without upstream cavity and four different purge mass flow rates are all taken into account in this simulation. Then, a deep insight into the loss mechanism of interaction between purge flow and main flow is gained. The results show that the presence of cavity and purge flow has a significant impact on the main flow which not only changes the vortex structure in both the passage and upstream cavity, but also alters the cascade exit flow angle distribution along the spanwise. Moreover, aerodynamic loss in the cascade rises with the increase of purge flow rate while the sealing effect is also enhanced. Therefore, the effect of upstream cavity purge flow must be considered in the process of turbine aerodynamic design. What is more, it is necessary to minimize the purge flow rate in order to reduce aerodynamic loss on the premise of satisfying cooling requirements.展开更多
A sequential method for the determination of dimethyl sulfur compounds, including dimethylsulfide （DMS）, dimethylsulfonio- propionate （DMSP） and dimethylsulfoxide （DMSO）, in seawater samples has been developed. ...A sequential method for the determination of dimethyl sulfur compounds, including dimethylsulfide （DMS）, dimethylsulfonio- propionate （DMSP） and dimethylsulfoxide （DMSO）, in seawater samples has been developed. Detection limit of 2.5 pmol of DMS in 25 mL sample, corresponding to 0.10 nmol/L, was achieved. Recoveries for dimethyl sulfur compounds were in the range of 68.6- 78.3%. The relative standard deviations （R.S.D.s） for DMS, DMSP and DMSO determination were 3.0, 5.4 and 7.4%, respectively.展开更多
Aroma of Chinese steamed bread（CSB） is one of the important parameters that determines the overall quality attributes and consumer acceptance. However, the aroma profile of CSB still remains poorly understood, mainl...Aroma of Chinese steamed bread（CSB） is one of the important parameters that determines the overall quality attributes and consumer acceptance. However, the aroma profile of CSB still remains poorly understood, mainly because of relying on only a single method for aroma extraction in previous studies. Therefore, the objective of this study was to determine the volatile aroma compounds of five different samples of CSB using three different aroma extraction methods, namely solid-phase microextraction（SPME）, simultaneous distillation–extraction（SDE）, and purge and trap（PT）. All samples showed a unique aroma profile, which could be attributed to their unique microbial consortia.（E）-2-Nonenal and（E,E）-2,4-decadienal were the most prevalent aromatic compounds revealed by SDE, which have not been reported previously, while ethanol and acetic acid proved to be the most dominant compounds by both SPME and PT. Our approach of combining three different aroma extraction methods provided better insights into the aroma profile of CSB, which had remained largely unknown in previous studies.展开更多
In order to suppressing the particle deposition on vortex finder,a series of gas cyclones with the secondary swirling clean gas were developed inspired by the gas purge effect.Effects of the width and extension length...In order to suppressing the particle deposition on vortex finder,a series of gas cyclones with the secondary swirling clean gas were developed inspired by the gas purge effect.Effects of the width and extension length of the flow channel as well as the secondary inlet velocity and running time on the particle deposition pattern,the deposited particle mass and the cyclones'performance were experimentally investigated,respectively.The results show that the ultrafine particles(Stokes number Stk<0.0358)are mainly loose deposited on the walls under the secondary gas.Compare to the conventional cyclone with single tangential inlet,the total deposited particle mass of the improved cyclone has a maximum reduction more than 60%,and the collecting efficiency is increased up to 97.5%under the basically same pressure drop.The corresponding no-deposition area is increased by about 13%,and remains constant in spite of extending the running time.Moreover,an interesting phenomenon named"self-cleaning effect"of the vortex finder was captured for the gas cyclones,and mechanism of the secondary clean gas on the particle deposition is preliminarily analyzed.The results can deepen the understanding of the particle deposition on the vortex finder and guide the design of the anti-coking gas cyclones.展开更多
The pollution of VOCs was studied on both side of highway.With the determination method of purge and trap concentration coupled with gas chromatography-mass spectrometry,we found that the degree of pollution near the ...The pollution of VOCs was studied on both side of highway.With the determination method of purge and trap concentration coupled with gas chromatography-mass spectrometry,we found that the degree of pollution near the highway was not very bad.展开更多
文摘The volatile organic compounds in male and female urine were analyzed using P&T/GC-MS.More than 70 VOCs in samples were identified.Identification of compound were based on NIST05 library and relative references.Compounds in double urines included short-chain alcohols,ketones,aldehyde,sulfether,aliphatic hydrocarbon,aromatic hydrocarbon and chlorinated hydrocarbon.The nicotine in urine was identified.The source of VOCs in urine was briefly discussed in the article.
基金Key Laboratory Foundation (9140C4103091003C) for funding this work
文摘In modern gas turbines, rim seal located between the stator-disc and rotor-disc is used to prevent hot-gas ingestion into the inner stage-gap of high pressure turbine. However, the purge flow supplied to the cavity through the rim seal interacts with the main flow, producing additional aerodynamic loss due to the mixing process which plays a significant role in the formation, development and evolution of downstream secondary flow. In this paper, a set of cascade representative of low aspect ratio turbine is selected to numerically investigate the influence of upstream cavity purge flow on the hub secondary flow structure and aerodynamic loss. Cascade with/without upstream cavity and four different purge mass flow rates are all taken into account in this simulation. Then, a deep insight into the loss mechanism of interaction between purge flow and main flow is gained. The results show that the presence of cavity and purge flow has a significant impact on the main flow which not only changes the vortex structure in both the passage and upstream cavity, but also alters the cascade exit flow angle distribution along the spanwise. Moreover, aerodynamic loss in the cascade rises with the increase of purge flow rate while the sealing effect is also enhanced. Therefore, the effect of upstream cavity purge flow must be considered in the process of turbine aerodynamic design. What is more, it is necessary to minimize the purge flow rate in order to reduce aerodynamic loss on the premise of satisfying cooling requirements.
文摘A sequential method for the determination of dimethyl sulfur compounds, including dimethylsulfide （DMS）, dimethylsulfonio- propionate （DMSP） and dimethylsulfoxide （DMSO）, in seawater samples has been developed. Detection limit of 2.5 pmol of DMS in 25 mL sample, corresponding to 0.10 nmol/L, was achieved. Recoveries for dimethyl sulfur compounds were in the range of 68.6- 78.3%. The relative standard deviations （R.S.D.s） for DMS, DMSP and DMSO determination were 3.0, 5.4 and 7.4%, respectively.
基金supported by the National Natural Science Foundation of China(No.31371826)the China Postdoctoral Science Foundation(No.2016M592002)
文摘Aroma of Chinese steamed bread（CSB） is one of the important parameters that determines the overall quality attributes and consumer acceptance. However, the aroma profile of CSB still remains poorly understood, mainly because of relying on only a single method for aroma extraction in previous studies. Therefore, the objective of this study was to determine the volatile aroma compounds of five different samples of CSB using three different aroma extraction methods, namely solid-phase microextraction（SPME）, simultaneous distillation–extraction（SDE）, and purge and trap（PT）. All samples showed a unique aroma profile, which could be attributed to their unique microbial consortia.（E）-2-Nonenal and（E,E）-2,4-decadienal were the most prevalent aromatic compounds revealed by SDE, which have not been reported previously, while ethanol and acetic acid proved to be the most dominant compounds by both SPME and PT. Our approach of combining three different aroma extraction methods provided better insights into the aroma profile of CSB, which had remained largely unknown in previous studies.
基金the National Natural Science Foundation of China(grant No.51904088)Scientific Research Project of Colleges and Universities in Hebei Province(grant No.BJ2020042).
文摘In order to suppressing the particle deposition on vortex finder,a series of gas cyclones with the secondary swirling clean gas were developed inspired by the gas purge effect.Effects of the width and extension length of the flow channel as well as the secondary inlet velocity and running time on the particle deposition pattern,the deposited particle mass and the cyclones'performance were experimentally investigated,respectively.The results show that the ultrafine particles(Stokes number Stk<0.0358)are mainly loose deposited on the walls under the secondary gas.Compare to the conventional cyclone with single tangential inlet,the total deposited particle mass of the improved cyclone has a maximum reduction more than 60%,and the collecting efficiency is increased up to 97.5%under the basically same pressure drop.The corresponding no-deposition area is increased by about 13%,and remains constant in spite of extending the running time.Moreover,an interesting phenomenon named"self-cleaning effect"of the vortex finder was captured for the gas cyclones,and mechanism of the secondary clean gas on the particle deposition is preliminarily analyzed.The results can deepen the understanding of the particle deposition on the vortex finder and guide the design of the anti-coking gas cyclones.
文摘The pollution of VOCs was studied on both side of highway.With the determination method of purge and trap concentration coupled with gas chromatography-mass spectrometry,we found that the degree of pollution near the highway was not very bad.
