A brief overview of the past and present state of art in the field of H2S solid oxide fuel cell is presented.Electrochemical performance of a proton-conducting solid oxide fuel cell having the configuration of H2S,（M...A brief overview of the past and present state of art in the field of H2S solid oxide fuel cell is presented.Electrochemical performance of a proton-conducting solid oxide fuel cell having the configuration of H2S,（MoS2+NiS）/Li2SO4-Al2O3/Pt,air was investigated.The experimental results showed that electrolyte materials like Li2SO4-Al2O3, and anode substances such as MoS2+NiS showed good chemical stability under the operating conditions of a fuel cell using H2S as the fuel, and that binary metal sulfides such as MoS2+NiS as an anode catalyst was superior to a single metal sulfide of MoS2 which sublimes above 450 ℃, and better than Pt which could be detached and resulted in the degradation of anode due to the formation of PtS.The proton-conducting and cell performance was improved at elevated temperatures due to the increase of electrochemical reaction rate and the reduction of cell resistance.OCV values around 1.0 V were observed.The maximum current and power density values obtained at 600 ℃ were 20 mA·cm -2 and 4 mW· cm -2, and as high as 200 mA· cm -2 and 55 mW· cm -2 were achieved at 700 ℃, respectively.Three different anode catalysts, Pt, MoS2+NiS and MoS2+NiS+Ag were described.The conductance of cell increased and the cell performance was improved with Ag powder added to anode catalysts.Current density up to 250 mA· cm -2 and power density up to 70 mW· cm -2 were achieved with the anode catalyst MoS2+NiS+Ag compared to those with MoS2+NiS at 700 ℃.展开更多
The development of proton,oxygen-ion,and electron mixed conducting materials,known as triple-conduction materials,as cathodes for proton-conducting solid oxide fuel cells(H-SOFCs)is highly desired because they can inc...The development of proton,oxygen-ion,and electron mixed conducting materials,known as triple-conduction materials,as cathodes for proton-conducting solid oxide fuel cells(H-SOFCs)is highly desired because they can increase fuel cell performance by extending the reaction active area.Although oxygen-ion and electron conductions can be measured directly,proton conduction in these oxides is usually estimated indirectly.Because of the instability of cathode materials in a reducing environment,direct measurement of proton conduction in cathode oxide is difficult.The La0.8Sr0.2Sc0.5Fe0.5O3–δ(LSSF)cathode material is proposed for H-SOFCs in this study,which can survive in an H_(2)-containing atmosphere,allowing measurement of proton conduction in LSSF by hydrogen permeation technology.Furthermore,LSSF is discovered to be a unique proton and electron mixed-conductive material with limited oxygen diffusion capability that is specifically designed for H-SOFCs.The LSSF is an appealing cathode choice for H-SOFCs due to its outstanding CO_(2)tolerance and matched thermal expansion coefficient,producing a record-high performance of 2032 mW cm^(−2)at 700℃and good long-term stability under operational conditions.The current study reveals that a new type of proton–electron mixed conducting cathode can provide promising performance for H-SOFCs,opening the way for developing high-performance cathodes.展开更多
A series of novel organic-inorganic hybrid proton-conducting electrolyte membranes with silane-crosslinked sulfonated poly(aryl ether ketone)(SC-SPAEK) networks was prepared via a simple procedure that includes soluti...A series of novel organic-inorganic hybrid proton-conducting electrolyte membranes with silane-crosslinked sulfonated poly(aryl ether ketone)(SC-SPAEK) networks was prepared via a simple procedure that includes solution casting and acid treatment. The organosilicon pendants of the silane-grafted SPAEK, which were expected to serve as coupling and crosslinking agents, were found to play a key role in the homogenous dispersion of inorganic particles and improved the performance of hybrid membranes. The hybrid membranes exhibited enhanced proton conductivity, and SC-SPAEK/TiO2-4 showed an extremely high proton conductivity of 0.1472 S/cm at 100℃. The crosslinked hybrid membranes also demonstrated good chemical resistance, oxidative stability, and mechanical properties. The crosslinked hybrid membranes with excellent comprehensive performance may be a promising material for proton exchange membrane fuel cells.展开更多
文摘A brief overview of the past and present state of art in the field of H2S solid oxide fuel cell is presented.Electrochemical performance of a proton-conducting solid oxide fuel cell having the configuration of H2S,（MoS2+NiS）/Li2SO4-Al2O3/Pt,air was investigated.The experimental results showed that electrolyte materials like Li2SO4-Al2O3, and anode substances such as MoS2+NiS showed good chemical stability under the operating conditions of a fuel cell using H2S as the fuel, and that binary metal sulfides such as MoS2+NiS as an anode catalyst was superior to a single metal sulfide of MoS2 which sublimes above 450 ℃, and better than Pt which could be detached and resulted in the degradation of anode due to the formation of PtS.The proton-conducting and cell performance was improved at elevated temperatures due to the increase of electrochemical reaction rate and the reduction of cell resistance.OCV values around 1.0 V were observed.The maximum current and power density values obtained at 600 ℃ were 20 mA·cm -2 and 4 mW· cm -2, and as high as 200 mA· cm -2 and 55 mW· cm -2 were achieved at 700 ℃, respectively.Three different anode catalysts, Pt, MoS2+NiS and MoS2+NiS+Ag were described.The conductance of cell increased and the cell performance was improved with Ag powder added to anode catalysts.Current density up to 250 mA· cm -2 and power density up to 70 mW· cm -2 were achieved with the anode catalyst MoS2+NiS+Ag compared to those with MoS2+NiS at 700 ℃.
基金National Natural Science Foundation of China,Grant/Award Numbers:52272216,51972183Hundred Youth Talents Program of HunanStartup Funding for Talents at University of South China。
文摘The development of proton,oxygen-ion,and electron mixed conducting materials,known as triple-conduction materials,as cathodes for proton-conducting solid oxide fuel cells(H-SOFCs)is highly desired because they can increase fuel cell performance by extending the reaction active area.Although oxygen-ion and electron conductions can be measured directly,proton conduction in these oxides is usually estimated indirectly.Because of the instability of cathode materials in a reducing environment,direct measurement of proton conduction in cathode oxide is difficult.The La0.8Sr0.2Sc0.5Fe0.5O3–δ(LSSF)cathode material is proposed for H-SOFCs in this study,which can survive in an H_(2)-containing atmosphere,allowing measurement of proton conduction in LSSF by hydrogen permeation technology.Furthermore,LSSF is discovered to be a unique proton and electron mixed-conductive material with limited oxygen diffusion capability that is specifically designed for H-SOFCs.The LSSF is an appealing cathode choice for H-SOFCs due to its outstanding CO_(2)tolerance and matched thermal expansion coefficient,producing a record-high performance of 2032 mW cm^(−2)at 700℃and good long-term stability under operational conditions.The current study reveals that a new type of proton–electron mixed conducting cathode can provide promising performance for H-SOFCs,opening the way for developing high-performance cathodes.
基金Supported by the National Natural Science Foundation of China(Nos.51873076,21404013)tlie Science and Technology Development Project of Jilin Province,China(Nos.20170101110JC,20180201076GX,20180201075GX)the Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,China(No.201826).
文摘A series of novel organic-inorganic hybrid proton-conducting electrolyte membranes with silane-crosslinked sulfonated poly(aryl ether ketone)(SC-SPAEK) networks was prepared via a simple procedure that includes solution casting and acid treatment. The organosilicon pendants of the silane-grafted SPAEK, which were expected to serve as coupling and crosslinking agents, were found to play a key role in the homogenous dispersion of inorganic particles and improved the performance of hybrid membranes. The hybrid membranes exhibited enhanced proton conductivity, and SC-SPAEK/TiO2-4 showed an extremely high proton conductivity of 0.1472 S/cm at 100℃. The crosslinked hybrid membranes also demonstrated good chemical resistance, oxidative stability, and mechanical properties. The crosslinked hybrid membranes with excellent comprehensive performance may be a promising material for proton exchange membrane fuel cells.
