For the aqueous Zn-ion battery,dendrite formation,corrosion,and interfacial parasitic reactions are major issues,which greatly inhibits their practical application.How to develop a method of Zn construction or treatme...For the aqueous Zn-ion battery,dendrite formation,corrosion,and interfacial parasitic reactions are major issues,which greatly inhibits their practical application.How to develop a method of Zn construction or treatment to solve these issues for Zn anodes are still great challenges.Herein,a simple and cheap metal passivation technique is proposed for Zn anodes from a corrosion science perspective.Similar to the metal anticorrosion engineering,the formed interfacial protective layer in a chemical way can sufficiently solve the corrosion issues.Furthermore,the proposed passivity approach can reconstruct Zn surface-preferred crystal planes,exposing more(002)planes and improving surface hydrophilicity,which inhibits the formation of Zn dendrites and hydrogen evolution effectively.As expected,the passivated Zn achieves outstanding cycling life(1914 h)with low voltage polarization(<40 mV).Even at 6 mA cm^(−2) and 3 mA h cm^(−2),it can achieve stable Zn deposition over 460 h.The treated Zn anode coupled with MnO_(2) cathode shows prominently reinforced full batteries service life,making it a potential Zn anode candidate for excellent performance aqueous Zn-ion batteries.The proposed passivation approach provides a guideline for other metal electrodes preparation in various batteries and establishes the connections between corrosion science and batteries.展开更多
Seven in-situ tests were carried out in far field to study the blast mitigation effect of a kind of water filled plastic wall. Test results show that the mitigation effect of water filled plastic wall is remarkable. T...Seven in-situ tests were carried out in far field to study the blast mitigation effect of a kind of water filled plastic wall. Test results show that the mitigation effect of water filled plastic wall is remarkable. The maximum reduction of peak reflected overpressure reaches up to 94.53%, as well as 36.3% of the minimum peak reflected overpressure reduction in the scaled distance ranging from 1.71 m/kg1/3 to 3.42 m/kg1/3. Parametric studies were also carried out. The effects of the scaled gauge height, water/charge scaled distance(the distance between the explosive charge and the water wall), water wall scaled height and water/structure scaled distance(the distance between the water wall and the structure) were systematically investigated and compared with the usual rigid anti-blast wall. It is concluded that these parameters affect the mitigation effects of plastic water wall on blast loadings significantly, which is basically consistent to the trend of usual rigid anti-blast wall. Some formulae are also derived based on the numerical and test results, providing a simple but reliable prediction model to evaluate the peak overpressure of mitigated blast loadings on the structures.展开更多
基金financialy supported by the National Key R&D Program of China(Grant No.2018YFB0905400)the National Natural Science Foundation of China(Grant Nos.22075331,51702376)+2 种基金the Fundamental Research Funds for the Central Universities(19lgzd02)the Guangdong Pearl River Talents Plan(2019QN01L117)the National Thousand Youth Talents Project of the Chinese Government
文摘For the aqueous Zn-ion battery,dendrite formation,corrosion,and interfacial parasitic reactions are major issues,which greatly inhibits their practical application.How to develop a method of Zn construction or treatment to solve these issues for Zn anodes are still great challenges.Herein,a simple and cheap metal passivation technique is proposed for Zn anodes from a corrosion science perspective.Similar to the metal anticorrosion engineering,the formed interfacial protective layer in a chemical way can sufficiently solve the corrosion issues.Furthermore,the proposed passivity approach can reconstruct Zn surface-preferred crystal planes,exposing more(002)planes and improving surface hydrophilicity,which inhibits the formation of Zn dendrites and hydrogen evolution effectively.As expected,the passivated Zn achieves outstanding cycling life(1914 h)with low voltage polarization(<40 mV).Even at 6 mA cm^(−2) and 3 mA h cm^(−2),it can achieve stable Zn deposition over 460 h.The treated Zn anode coupled with MnO_(2) cathode shows prominently reinforced full batteries service life,making it a potential Zn anode candidate for excellent performance aqueous Zn-ion batteries.The proposed passivation approach provides a guideline for other metal electrodes preparation in various batteries and establishes the connections between corrosion science and batteries.
基金Projects(2015CB058003,2012CB026204)supported by the National Basic Research Program of ChinaProjects(51238007,51210012)supported by the National Natural Science Foundation of China
文摘Seven in-situ tests were carried out in far field to study the blast mitigation effect of a kind of water filled plastic wall. Test results show that the mitigation effect of water filled plastic wall is remarkable. The maximum reduction of peak reflected overpressure reaches up to 94.53%, as well as 36.3% of the minimum peak reflected overpressure reduction in the scaled distance ranging from 1.71 m/kg1/3 to 3.42 m/kg1/3. Parametric studies were also carried out. The effects of the scaled gauge height, water/charge scaled distance(the distance between the explosive charge and the water wall), water wall scaled height and water/structure scaled distance(the distance between the water wall and the structure) were systematically investigated and compared with the usual rigid anti-blast wall. It is concluded that these parameters affect the mitigation effects of plastic water wall on blast loadings significantly, which is basically consistent to the trend of usual rigid anti-blast wall. Some formulae are also derived based on the numerical and test results, providing a simple but reliable prediction model to evaluate the peak overpressure of mitigated blast loadings on the structures.
