This study evaluates the pozzolanicity of Nyiragongo volcano lava flows in Congo by an indirect method using mortars with different rock powder proportions. The clinker used is a locally produced alite clinker, whose ...This study evaluates the pozzolanicity of Nyiragongo volcano lava flows in Congo by an indirect method using mortars with different rock powder proportions. The clinker used is a locally produced alite clinker, whose chemical and mineralogical composition was determined by XRF, Bogue and Taylor formulas. The lava flows were collected from the 2002, 2010 and 2021 eruption sites, and were characterized by XRF, CIPW normative mineralogy and geomechanical tests. The results show that Nyiragongo rocks are ultrabasic, silica- and alkali-rich, and contain minerals like nepheline, wollastonite and leucite. They satisfy the natural pozzolan criterion, and have pozzolanic activity indices above 70%. These rocks also have high RC and LA resistances, ranging from 190 MPa to 45 MPa, and from 18% to 32.6%, respectively. The rock powder addition in the mortars reduces mechanical resistances and increases setting times, except for a 5% replacement rate, which speeds up hardening. Nyiragongo lava can be used as a pozzolanic addition to produce a CEM II/B-P 32.5 cement.展开更多
The assessment of magnesium sulphate attack on concretes containing rice husk ash （RHA, 20wt% of the cementitious materials） with various average particle sizes was investigated. The total cementitious materials wer...The assessment of magnesium sulphate attack on concretes containing rice husk ash （RHA, 20wt% of the cementitious materials） with various average particle sizes was investigated. The total cementitious materials were 390 kg and the water-to-binder ratio （W/B） was 0.53 for all mixtures. Specimens were initially cured in water for 7 d and then immersed in the 3wt% magnesium sulphate solution for up to 111 d of exposure. The specimens were subjected to drying-wetting cycles to accelerate sulphate attack. In addition to the visual monitoring of the specimens, the concrete specimens were subsequently tested for compressive strength, dynamic modulus of elasticity, and length and mass changes. The results show that the specimens exposed to sulphate attack exhibit higher strength and dynamic modulus than those kept in water. The length change is negligible and can be attributed to the normal swelling of concrete. On the other hand, concretes suffers mass loss and surface spalling and softening; the fine RHA-concrete results in a better resistance. For the accelerated sulphate attack method used in this study, mass change and visual monitoring are recommended for assessing the deterioration degree and the effectiveness of supplementary cementitious materials to resist sulphate attack.展开更多
In order to determine the effect of Natural Pozzolan （NP） content on the mechanical properties and durability characteristics on Engineered Cementitious Composites （ECC） as repair material. This study focused on t...In order to determine the effect of Natural Pozzolan （NP） content on the mechanical properties and durability characteristics on Engineered Cementitious Composites （ECC） as repair material. This study focused on the evaluation of the most factors influencing compatibility between the repair material and the base concrete including mechanicals properties such as, compressive and flexural strengths, elastic modulus, capillary absorption and drying shrinkage. The experimental results showed that natural pozzolan reduces the compressive strength and the flexuraI strength of ECC at all ages. The elastic modulus of ECC was remarkably lower than that of normal-strength concrete. This lower ~oung＇s modulus is desirable for repair concrete, because it prevents the stresses induced by restrained shrinkage. In addition, the incorporation of high-volume natural pozzolan decreases significantly the coefficient of capillary absorption at long term and increases the drying shrinkage. Generally, based on the results obtained in the present experimental investigation, ECC can be used effectively as an overlay material over existing parent concrete.展开更多
Four raw deposits clayey materials in Burkina Faso have been characterized using X-ray diffraction, infrared spectroscopy and ICP-AES to evaluate their suitability to be used as pozzolan in cement. The samples have be...Four raw deposits clayey materials in Burkina Faso have been characterized using X-ray diffraction, infrared spectroscopy and ICP-AES to evaluate their suitability to be used as pozzolan in cement. The samples have been activated by thermal treatment at 730°C during 5 hours. The obtained metakaolin was investigated by means of complementary techniques for their use as pozzolan in building materials. Fineness, surface area and amorphousness of metakaolins were the dominant factors which influenced their pozzolan reactivity. The compressive strengths of blended specimens were slightly increased with metakaolins named MK1 and MK2 than the reference for the substitution of 20 - 25 wt%. This was due to the metakaolins’ pozzolan reactivity and their filler effects which promoted CSH formation and reduced pores in the specimens. MK1 and MK2 were suitable for replacement of Portland cement in the field of building materials.展开更多
Alkali activated binder, commonly known as geopolymer cement, has replaced Portland cement in the production of mortar and concrete globally over the past few years. The density, particle size distribution, and specif...Alkali activated binder, commonly known as geopolymer cement, has replaced Portland cement in the production of mortar and concrete globally over the past few years. The density, particle size distribution, and specific surface area (SSA) are important physical parameters affecting strength and durability of alkali activated binders. This study carried out tests for physical and chemical properties of the natural pozzolan and calcium hydroxide and then determines the influence of alkali solution (sodium silicate and sodium hydroxide) on strength development of natural pozzolan calcium hydroxide binders. The particle size distribution (PSD), relative densities (RD), and specific surface areas (SSA) of powder natural pozzolan and calcium hydroxide materials and for the mixture of natural pozzolan and calcium hydroxide were determined by using Blaine air permeability apparatus. The optimum proportion of 75% natural pozzolan and 25% calcium hydroxide was obtained which produces the compressive strength of 7.5 MPa at 28 days cured paste. The mixture of natural pozzolan and calcium hydroxide were further grinded at three different finenesses and the particle size gradation, specific densities, specific surface areas and mean particles sizes for the mixture were determined. The compressive strength of alkali activated binders increased with increasing curing period and fineness. The maximum compressive strength for 28 days cured specimens was 26.1 MPa which was obtained at a solution of 8 moles sodium hydroxide concentration. The test results showed that natural pozzolan materials can be used to make geopolymer binders for mortars and concretes. The geopolymer binders for mortars and concretes reduce green gas emission from cement factory but also it can be used to produce durable mortar and concrete with comparable strengths with mortars and concrete made from conventional Portland cement.展开更多
The mechanical and physical properties of TUFF from Korsimoro (Burkina Faso) were investigated for use as admixtures in clinker to make pozzolanic cement. Six different cement mortar specimens were prepared by replaci...The mechanical and physical properties of TUFF from Korsimoro (Burkina Faso) were investigated for use as admixtures in clinker to make pozzolanic cement. Six different cement mortar specimens were prepared by replacing clinker with TUFF in ratios of 0%, 5%, 8%, 10%, 13% and 15% by mass. The flexural and compressive strengths of the specimens were determined at the ages of 2, 7, 28 and 60 days. The effects of the TUFF replacement ratio on workability, setting time and volume expansion were also examined. Based on the results, it was concluded that Korsimoro TUFF has pozzolanic activity and is suitable for use as an alternative adherent material in the cement industry.展开更多
Calcined clay pozzolan has been used to replace varying portions of high alkali Portland limestone cement in order to study its effect on the alkali-silica reaction (ASR). Portland limestone cement used for the study ...Calcined clay pozzolan has been used to replace varying portions of high alkali Portland limestone cement in order to study its effect on the alkali-silica reaction (ASR). Portland limestone cement used for the study had a total Na2Oeq of 4.32. Mortar-bar expansion decreased as pozzolan content in the cement increased. The highest expansion was recorded for reference bars with no pozzolan, reaching a maximum of 0.35% at 42 days whilst the expansion was reduced by between 42.5% and 107.8% at 14 days and between 9.4% and 16.4% at 84 days with increasing calcined clay pozzolan content. Mortar bars with 25% pozzolan were the least expansive recording expansion less than 0.1% at all test ages. X-ray diffractometry of the hydrated blended cement paste powders showed the formation of stable calcium silicates in increasing quantities whilst the presence of expansive alkali-silica gel, responsible for ASR expansion, decreased as pozzolan content increased. The study confirms that calcined clay pozzolan has an influence on ASR in mortar bars and causes a significant reduction in expansion at a replacement level of 25%.展开更多
The objective of this study is to find alternative materials that can be used as an addition in cement in order to produce ecological and economical cement. Three pozzolans coming from different volcanic regions of Ca...The objective of this study is to find alternative materials that can be used as an addition in cement in order to produce ecological and economical cement. Three pozzolans coming from different volcanic regions of Cameroon (Penja, Tombel and Foumbot) were sampling. Mechanical compressions on 40 × 40 × 160 mm3 mortar specimens were made with partial replacements of 2%, 4%, 6% and 8% of the pozzolans in Portland cement and physical analyzes on the mortar powders were carried out. The values of the activity indices of different pozzolans obtained are in the normative range. The compressive strength of motars decreases at all ages with the proportion of cement substitution. The compressive strength values up to 40 Mpa are obtained for a substitution of 6% for the pozzolans from Penja, Tombel and 8% for the pozzolan from Foumbot. Pozzolan from Foumbot which contains the highest percentage of SiO2 offers a maximum substitution rate and therefore optimally reduces the production costs of Portland cement. Physical tests show that specific surfaces increase with an additions of pozzolans from Tombel and Penja.展开更多
文摘This study evaluates the pozzolanicity of Nyiragongo volcano lava flows in Congo by an indirect method using mortars with different rock powder proportions. The clinker used is a locally produced alite clinker, whose chemical and mineralogical composition was determined by XRF, Bogue and Taylor formulas. The lava flows were collected from the 2002, 2010 and 2021 eruption sites, and were characterized by XRF, CIPW normative mineralogy and geomechanical tests. The results show that Nyiragongo rocks are ultrabasic, silica- and alkali-rich, and contain minerals like nepheline, wollastonite and leucite. They satisfy the natural pozzolan criterion, and have pozzolanic activity indices above 70%. These rocks also have high RC and LA resistances, ranging from 190 MPa to 45 MPa, and from 18% to 32.6%, respectively. The rock powder addition in the mortars reduces mechanical resistances and increases setting times, except for a 5% replacement rate, which speeds up hardening. Nyiragongo lava can be used as a pozzolanic addition to produce a CEM II/B-P 32.5 cement.
文摘The assessment of magnesium sulphate attack on concretes containing rice husk ash （RHA, 20wt% of the cementitious materials） with various average particle sizes was investigated. The total cementitious materials were 390 kg and the water-to-binder ratio （W/B） was 0.53 for all mixtures. Specimens were initially cured in water for 7 d and then immersed in the 3wt% magnesium sulphate solution for up to 111 d of exposure. The specimens were subjected to drying-wetting cycles to accelerate sulphate attack. In addition to the visual monitoring of the specimens, the concrete specimens were subsequently tested for compressive strength, dynamic modulus of elasticity, and length and mass changes. The results show that the specimens exposed to sulphate attack exhibit higher strength and dynamic modulus than those kept in water. The length change is negligible and can be attributed to the normal swelling of concrete. On the other hand, concretes suffers mass loss and surface spalling and softening; the fine RHA-concrete results in a better resistance. For the accelerated sulphate attack method used in this study, mass change and visual monitoring are recommended for assessing the deterioration degree and the effectiveness of supplementary cementitious materials to resist sulphate attack.
文摘In order to determine the effect of Natural Pozzolan （NP） content on the mechanical properties and durability characteristics on Engineered Cementitious Composites （ECC） as repair material. This study focused on the evaluation of the most factors influencing compatibility between the repair material and the base concrete including mechanicals properties such as, compressive and flexural strengths, elastic modulus, capillary absorption and drying shrinkage. The experimental results showed that natural pozzolan reduces the compressive strength and the flexuraI strength of ECC at all ages. The elastic modulus of ECC was remarkably lower than that of normal-strength concrete. This lower ~oung＇s modulus is desirable for repair concrete, because it prevents the stresses induced by restrained shrinkage. In addition, the incorporation of high-volume natural pozzolan decreases significantly the coefficient of capillary absorption at long term and increases the drying shrinkage. Generally, based on the results obtained in the present experimental investigation, ECC can be used effectively as an overlay material over existing parent concrete.
文摘Four raw deposits clayey materials in Burkina Faso have been characterized using X-ray diffraction, infrared spectroscopy and ICP-AES to evaluate their suitability to be used as pozzolan in cement. The samples have been activated by thermal treatment at 730°C during 5 hours. The obtained metakaolin was investigated by means of complementary techniques for their use as pozzolan in building materials. Fineness, surface area and amorphousness of metakaolins were the dominant factors which influenced their pozzolan reactivity. The compressive strengths of blended specimens were slightly increased with metakaolins named MK1 and MK2 than the reference for the substitution of 20 - 25 wt%. This was due to the metakaolins’ pozzolan reactivity and their filler effects which promoted CSH formation and reduced pores in the specimens. MK1 and MK2 were suitable for replacement of Portland cement in the field of building materials.
文摘Alkali activated binder, commonly known as geopolymer cement, has replaced Portland cement in the production of mortar and concrete globally over the past few years. The density, particle size distribution, and specific surface area (SSA) are important physical parameters affecting strength and durability of alkali activated binders. This study carried out tests for physical and chemical properties of the natural pozzolan and calcium hydroxide and then determines the influence of alkali solution (sodium silicate and sodium hydroxide) on strength development of natural pozzolan calcium hydroxide binders. The particle size distribution (PSD), relative densities (RD), and specific surface areas (SSA) of powder natural pozzolan and calcium hydroxide materials and for the mixture of natural pozzolan and calcium hydroxide were determined by using Blaine air permeability apparatus. The optimum proportion of 75% natural pozzolan and 25% calcium hydroxide was obtained which produces the compressive strength of 7.5 MPa at 28 days cured paste. The mixture of natural pozzolan and calcium hydroxide were further grinded at three different finenesses and the particle size gradation, specific densities, specific surface areas and mean particles sizes for the mixture were determined. The compressive strength of alkali activated binders increased with increasing curing period and fineness. The maximum compressive strength for 28 days cured specimens was 26.1 MPa which was obtained at a solution of 8 moles sodium hydroxide concentration. The test results showed that natural pozzolan materials can be used to make geopolymer binders for mortars and concretes. The geopolymer binders for mortars and concretes reduce green gas emission from cement factory but also it can be used to produce durable mortar and concrete with comparable strengths with mortars and concrete made from conventional Portland cement.
文摘The mechanical and physical properties of TUFF from Korsimoro (Burkina Faso) were investigated for use as admixtures in clinker to make pozzolanic cement. Six different cement mortar specimens were prepared by replacing clinker with TUFF in ratios of 0%, 5%, 8%, 10%, 13% and 15% by mass. The flexural and compressive strengths of the specimens were determined at the ages of 2, 7, 28 and 60 days. The effects of the TUFF replacement ratio on workability, setting time and volume expansion were also examined. Based on the results, it was concluded that Korsimoro TUFF has pozzolanic activity and is suitable for use as an alternative adherent material in the cement industry.
文摘Calcined clay pozzolan has been used to replace varying portions of high alkali Portland limestone cement in order to study its effect on the alkali-silica reaction (ASR). Portland limestone cement used for the study had a total Na2Oeq of 4.32. Mortar-bar expansion decreased as pozzolan content in the cement increased. The highest expansion was recorded for reference bars with no pozzolan, reaching a maximum of 0.35% at 42 days whilst the expansion was reduced by between 42.5% and 107.8% at 14 days and between 9.4% and 16.4% at 84 days with increasing calcined clay pozzolan content. Mortar bars with 25% pozzolan were the least expansive recording expansion less than 0.1% at all test ages. X-ray diffractometry of the hydrated blended cement paste powders showed the formation of stable calcium silicates in increasing quantities whilst the presence of expansive alkali-silica gel, responsible for ASR expansion, decreased as pozzolan content increased. The study confirms that calcined clay pozzolan has an influence on ASR in mortar bars and causes a significant reduction in expansion at a replacement level of 25%.
文摘The objective of this study is to find alternative materials that can be used as an addition in cement in order to produce ecological and economical cement. Three pozzolans coming from different volcanic regions of Cameroon (Penja, Tombel and Foumbot) were sampling. Mechanical compressions on 40 × 40 × 160 mm3 mortar specimens were made with partial replacements of 2%, 4%, 6% and 8% of the pozzolans in Portland cement and physical analyzes on the mortar powders were carried out. The values of the activity indices of different pozzolans obtained are in the normative range. The compressive strength of motars decreases at all ages with the proportion of cement substitution. The compressive strength values up to 40 Mpa are obtained for a substitution of 6% for the pozzolans from Penja, Tombel and 8% for the pozzolan from Foumbot. Pozzolan from Foumbot which contains the highest percentage of SiO2 offers a maximum substitution rate and therefore optimally reduces the production costs of Portland cement. Physical tests show that specific surfaces increase with an additions of pozzolans from Tombel and Penja.
