The solvent debinding of water soluble binder in powder injection moulding (MIM) was investigated systematically, including the effects of solvent types, temperature and the thickness of green parts on the solvent deb...The solvent debinding of water soluble binder in powder injection moulding (MIM) was investigated systematically, including the effects of solvent types, temperature and the thickness of green parts on the solvent debinding rate. After studying the debinding of a green part with a thickness of 4.26 mm, it was found that, the debinding rate of polyethylene glycol(PEG) in water and alcohol was high initially, and then decreased; however, it would increase with temperature increasing. At room temperature, the dissolution rate of PEG in water was higher than that in alcohol, but the latter would be much faster with temperature increasing because the debinding activation energy in alcohol was 51.44 kJ·mol -1 ·K -1 , much higher than 24.23 kJ·mol -1 ·K -1 in water. With a green part thickness larger than 4.26 mm, the debinding was controlled by diffusion; but with that smaller than 2.36 mm, the debinding was controlled by both dissolution and diffusion.展开更多
Most of dental implants are made from titanium or titanium based alloys.However, one of the drawback of such implants is high cost due to the technological difficulties in casting method or machining.In this work, pow...Most of dental implants are made from titanium or titanium based alloys.However, one of the drawback of such implants is high cost due to the technological difficulties in casting method or machining.In this work, powder injection moulding（PIM） method has been used in order to explore lower cost implants without minimising the biocorrosion resistance of the titanium.Corrosion resistance of titanium specimens, produced by powder injection moulding method（PIM-Ti）, in physiologic serum and artificial saliva was investigated.Commercially pure bulk Ti（CP-Ti） was used as control sample.Surface oxidation was also carried out to both PIMTi and CP-Ti samples.Microstructure and corrosion resistance were investigated using microhardness, X-ray diffraction（XRD）, scanning electron microscopy（SEM） and potentiodynamic polarization experiments.Resulting microstructure of PIM-Ti samples contained porosity as compared to CP-Ti control samples.Microhardness of PIM-Ti samples varied with varying applied load whereas it was free from applied load for CP-Ti control samples.Polarisation measurements and SEM analysis revealed that corrosion behaviour of PIM-Ti was reasonably as good as CP-Ti both in as-produced and oxidized conditions in physiologic serum and artificial saliva in spite of its porous structure.展开更多
文摘The solvent debinding of water soluble binder in powder injection moulding (MIM) was investigated systematically, including the effects of solvent types, temperature and the thickness of green parts on the solvent debinding rate. After studying the debinding of a green part with a thickness of 4.26 mm, it was found that, the debinding rate of polyethylene glycol(PEG) in water and alcohol was high initially, and then decreased; however, it would increase with temperature increasing. At room temperature, the dissolution rate of PEG in water was higher than that in alcohol, but the latter would be much faster with temperature increasing because the debinding activation energy in alcohol was 51.44 kJ·mol -1 ·K -1 , much higher than 24.23 kJ·mol -1 ·K -1 in water. With a green part thickness larger than 4.26 mm, the debinding was controlled by diffusion; but with that smaller than 2.36 mm, the debinding was controlled by both dissolution and diffusion.
文摘Most of dental implants are made from titanium or titanium based alloys.However, one of the drawback of such implants is high cost due to the technological difficulties in casting method or machining.In this work, powder injection moulding（PIM） method has been used in order to explore lower cost implants without minimising the biocorrosion resistance of the titanium.Corrosion resistance of titanium specimens, produced by powder injection moulding method（PIM-Ti）, in physiologic serum and artificial saliva was investigated.Commercially pure bulk Ti（CP-Ti） was used as control sample.Surface oxidation was also carried out to both PIMTi and CP-Ti samples.Microstructure and corrosion resistance were investigated using microhardness, X-ray diffraction（XRD）, scanning electron microscopy（SEM） and potentiodynamic polarization experiments.Resulting microstructure of PIM-Ti samples contained porosity as compared to CP-Ti control samples.Microhardness of PIM-Ti samples varied with varying applied load whereas it was free from applied load for CP-Ti control samples.Polarisation measurements and SEM analysis revealed that corrosion behaviour of PIM-Ti was reasonably as good as CP-Ti both in as-produced and oxidized conditions in physiologic serum and artificial saliva in spite of its porous structure.
