Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materia...Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.展开更多
Mineral oxidation leaching in the anode area is the key step in slurry electrolysis.By adopting the slow linear potential scanning method during slurry electrolysis,this study investigated the steady-state polarizatio...Mineral oxidation leaching in the anode area is the key step in slurry electrolysis.By adopting the slow linear potential scanning method during slurry electrolysis,this study investigated the steady-state polarization curve of a pure stibnite mineral on a graphite anode.In addition,the influence of the mineral particle size,liquid–solid ratio,stirring speed,and temperature on the collision oxidation of the mineral with the anode was studied.Based on the different oxidation reactions,the potential range can be divided into three intervals:the low-potential interval with a potential lower than 0.75 V,an intermediatepotential interval with a potential within 0.75–1.2 V,and a high-potential interval with a potential higher than 1.2 V.The collision oxidation of the mineral with the anode occurred in all three intervals.The oxidation of Sb(III)also appeared in the intermediate-and high-potential intervals,and chlorine evolution occurred in the high-potential interval.Therefore,the low-potential interval was determined to be a suitable potential interval for the slurry electrolysis process.In the low-potential interval,the particle size,liquid–solid ratio,and stirring speed had little effect on the oxidation rate of the minerals.As the temperature increased,the stibnite oxidation rate and exchange current density increased.Overall,the direct collision oxidation rate of stibnite was relatively low and the current densities under all the investigated conditions were lower than 0.4 mA·cm^(-2.This indicates that it is difficult to realize industrial production while relying solely on this process.展开更多
The Xu-Huai nappe extends from its northeastern end Taierzhuangin Shandong Province through Xuzhou in Jiangsu Province to Huaibei in Anhui Province. It has been found to be a complex one and contains two generations o...The Xu-Huai nappe extends from its northeastern end Taierzhuangin Shandong Province through Xuzhou in Jiangsu Province to Huaibei in Anhui Province. It has been found to be a complex one and contains two generations of folds, the earlier one of which presents itself as a recumbent or recline fold. Two kinds展开更多
Both the long-life and multi-mode versions of LIPS-200 ion thruster are under investigation in LIP(Lanzhou Institute of Physics).To confirm the feasible ranges of the beam current and accel(abbreviation for accelarati...Both the long-life and multi-mode versions of LIPS-200 ion thruster are under investigation in LIP(Lanzhou Institute of Physics).To confirm the feasible ranges of the beam current and accel(abbreviation for accelaration)grid potential to apply to the thruster,the wide-range beam perveance(the state of beam focus)and saddle point potential(the lowest potential along beamlet centerline)characteristics of LIPS-200 are studied with a test-verified PIC-MCC(Particle in Cell-Monte Carlo Collisions)model.These characteristics are investigated with both the initial and the eroded states of the accel grid aperture diameter.The results show that the feasible ranges of these parameters with respect to perveance/crossover(overfocused)limit extend as the operating time accumulates,while the feasible range of accel grid potential narrows due to a reduced EBSF(electron backstreaming failure)margin.The feasible ranges determined by the initial condition are:(i)the beam current up to 0.981 A,and(ii)the accel grid potential up to−85 V.A 23%enlargement of the aperture diameter would bring up to 48 V of EBSF margin loss.展开更多
基金supported by the National Natural Science Foundation of China(U21A20312,22172099,21975162,51902209)the Natural Science Foundation of Guangdong(2020A1515010840)the Shenzhen Science and Technology Program(SGDX20201103095802006,RCBS20200714114819161,JCYJ20190808111801674,JCYJ20200109105803806,RCYX20200714114535052)。
文摘Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.
基金supported by the National Key Research&Development Program of China(2019YFC1908404)the Major Science and Technology Projects of Qinghai Province(2018-GXA7)the National Natural Science Foundation of China(51604030)。
文摘Mineral oxidation leaching in the anode area is the key step in slurry electrolysis.By adopting the slow linear potential scanning method during slurry electrolysis,this study investigated the steady-state polarization curve of a pure stibnite mineral on a graphite anode.In addition,the influence of the mineral particle size,liquid–solid ratio,stirring speed,and temperature on the collision oxidation of the mineral with the anode was studied.Based on the different oxidation reactions,the potential range can be divided into three intervals:the low-potential interval with a potential lower than 0.75 V,an intermediatepotential interval with a potential within 0.75–1.2 V,and a high-potential interval with a potential higher than 1.2 V.The collision oxidation of the mineral with the anode occurred in all three intervals.The oxidation of Sb(III)also appeared in the intermediate-and high-potential intervals,and chlorine evolution occurred in the high-potential interval.Therefore,the low-potential interval was determined to be a suitable potential interval for the slurry electrolysis process.In the low-potential interval,the particle size,liquid–solid ratio,and stirring speed had little effect on the oxidation rate of the minerals.As the temperature increased,the stibnite oxidation rate and exchange current density increased.Overall,the direct collision oxidation rate of stibnite was relatively low and the current densities under all the investigated conditions were lower than 0.4 mA·cm^(-2.This indicates that it is difficult to realize industrial production while relying solely on this process.
文摘The Xu-Huai nappe extends from its northeastern end Taierzhuangin Shandong Province through Xuzhou in Jiangsu Province to Huaibei in Anhui Province. It has been found to be a complex one and contains two generations of folds, the earlier one of which presents itself as a recumbent or recline fold. Two kinds
基金Group independent research and development projects(No.YF-ZZYF-2021-132).
文摘Both the long-life and multi-mode versions of LIPS-200 ion thruster are under investigation in LIP(Lanzhou Institute of Physics).To confirm the feasible ranges of the beam current and accel(abbreviation for accelaration)grid potential to apply to the thruster,the wide-range beam perveance(the state of beam focus)and saddle point potential(the lowest potential along beamlet centerline)characteristics of LIPS-200 are studied with a test-verified PIC-MCC(Particle in Cell-Monte Carlo Collisions)model.These characteristics are investigated with both the initial and the eroded states of the accel grid aperture diameter.The results show that the feasible ranges of these parameters with respect to perveance/crossover(overfocused)limit extend as the operating time accumulates,while the feasible range of accel grid potential narrows due to a reduced EBSF(electron backstreaming failure)margin.The feasible ranges determined by the initial condition are:(i)the beam current up to 0.981 A,and(ii)the accel grid potential up to−85 V.A 23%enlargement of the aperture diameter would bring up to 48 V of EBSF margin loss.
