Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalys...Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalysts. Many catalysts including transition metal oxides, mixed metal oxides, and sup‐ported noble metals have been developed. Among these catalysts, the porous ones attract much attention. In this review, we focus on recent advances in the synthesis of ordered mesoporous and macroporous transition metal oxides, perovskites, and supported noble metal catalysts and their catalytic oxidation of VOCs. The porous catalysts outperformed their bulk counterparts. This excel‐lent catalytic performance was due to their high surface areas, high concentration of adsorbed oxy‐gen species, low temperature reducibility, strong interaction between noble metal and support and highly dispersed noble metal nanoparticles and unique porous structures. Catalytic oxidation of carbon monoxide over typical catalysts was also discussed. We made conclusive remarks and pro‐posed future work for the removal of VOCs.展开更多
With a rising energy demand and anabatic environmental crisis arising from the fast growth in human population and society economics,numerous efforts have been devoted to explore and design plentiful multifunctional m...With a rising energy demand and anabatic environmental crisis arising from the fast growth in human population and society economics,numerous efforts have been devoted to explore and design plentiful multifunctional materials for meeting highefficiency energy transfer processes,which happen in various developed energy conversion and storage systems.As a special kind of multi-metal oxides,perovskite with attractive physical and chemical properties,is becoming a rapidly rising star on the horizon of high-performance catalytic materials with substantial research behaviors worldwide.The porous nanostructure in targeted catalysts is favorable to the catalytic activity and thus improves the overall efficiency of these energy-related installations.In this review paper,recent advances made in the porous perovskite nanostructures for catalyzing several anodic or cathodic reactions in fuel cells and metal-air batteries are comprehensively summarized.Plenty of general preparation methods employed to attain porous perovskite-type oxides are provided,followed by a further discussion about the influence of various strategies on structures and catalytic properties of the porous perovskites.Furthermore,deep insights gathered in the future development of porous perovskite-based materials for energy conversion and storage technologies are also provided.展开更多
A 3-dimensional unit cell model is developed for analyzing effective thermal conductivity of xonotlite-aerogelcomposite insulation material based on its microstructure features. Effective thermal conductivity comparis...A 3-dimensional unit cell model is developed for analyzing effective thermal conductivity of xonotlite-aerogelcomposite insulation material based on its microstructure features. Effective thermal conductivity comparisonsbetween xonotlite-type calcium silicate and aerogel as well as xonotlite-aerogel composite insulation material arepresented. It is shown that the density of xonotlite-type calcium silicate is the key factor affecting the effectivethermal conductivity of xonotlite-aerogel composite insulation material, and the density of aerogel has little influence.The effective thermal conductivity can be lowered greatly by composite of the two materials at an elevatedtemperature.展开更多
A macroscopic yield criterion has been derived in the present work for a double saturated porous medium with a spheroidal pore at the mesocale and spherical pores at the microscale.These two types of pores are well se...A macroscopic yield criterion has been derived in the present work for a double saturated porous medium with a spheroidal pore at the mesocale and spherical pores at the microscale.These two types of pores are well separated at two different scales.The meso spheroidal pore saturated by a pore pressure which is different from the one in the micro spherical pores.A Drucker-Prager type criterion is adopted for the solid phase at the microscopic scale to describe its asymmetric behavior between tension and compression.The methodology to formulate this criterion is based on the limit analysis approach of a spheroidal volume containing a confocal spheroidal pore subjected to a uniform strain rate boundary conditions.The matrix at the mesoscopic scale obeys to a general elliptic yield criterion.Based on a two-step homogenization step,the influence of meso-pore shape(spherical,prolate or oblate),micro-porosity,meso-porosity and the effect of pore pressures at different scales are taken into account explicitly by this macroscopic yield criterion.展开更多
Two new compounds with microporous Co3[MnMo9O32].15H2O(1) and Cu3[MnMo9O32].15H2O(2) have been synthesized,and characterized by IR,element analysis,TG and single-crystal X-ray analysis.The structure analyses reveal th...Two new compounds with microporous Co3[MnMo9O32].15H2O(1) and Cu3[MnMo9O32].15H2O(2) have been synthesized,and characterized by IR,element analysis,TG and single-crystal X-ray analysis.The structure analyses reveal that compounds 1 and 2 are isostructural.In crystal,the Waugh-type polyoxoanions [MnMo9O32]6-are connected by Co2+ or Cu2+ cations to a 3D open-framework,which possesses channels along the [1 2 2] direction of approximately 8.27 × 11.97 .The photocatalytic performances of compounds 1 and 2 for photodegradation of RhB with UV irradiation have been studied,which show a good photocatalytic activity for photodegradation of RhB.展开更多
Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling perform...Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling performances.Herein,a bimetal ZnMn-based metal-organic framework(ZnMn-MOF)is engineered for in situ conversion of MnO-encapsulated porous carbon(MnO/PC)composite.The templating and activation effects of coordinated Zn endow the converted PC matrix with a highly porous structure.This enhances the compatibility of PC matrix with MnO particles,resulting in the full encapsulation of MnO particles in the PC matrix.More significantly,the PC matrix provides enough void space to buffer the volume change,which fully wraps the MnO without crack or fracture during repeated cycling.As a result,MnO/PC shows high charge storage capability,extraordinary rate performance,and long-term cycling stability at the same time.Thus MnO/PC exhibits high delithiation capacities of 768mA h g^(-1)at 0.1Ag^(-1)and 487mA h g^(-1)at a high rate of 0.7Ag^(-1),combined with an unattenuated cycling performance after 500 cycles at 0.3Ag^(-1).More significantly,MnO/PC demonstrates a well-matched performance with the capacitive activated carbon electrode in a Li-ion capacitor(LIC)full cell.LIC demonstrates a high specific energy of 153.6W h kg^(-1)at 210W kg^(-1),combined with a specific energy of 71.8W h kg^(-1)at a high specific power of 63.0kW kg^(-1).展开更多
The purpose of this study is to present a library of analytical solutions for the three-dimensional contaminant transport in uniform flow field in porous media with the first-order decay,linear sorption,and zero-order...The purpose of this study is to present a library of analytical solutions for the three-dimensional contaminant transport in uniform flow field in porous media with the first-order decay,linear sorption,and zero-order production.The library is constructed using Green's function method(GFM)in combination with available solutions.The library covers a wide range of solutions for various conditions.The aquifer can be vertically finite,semi-infinitive or infinitive,and laterally semi-infinitive or infinitive.The geometry of the sources can be of point,line,plane or volumetric body;and the source release can be continuous,instantaneous,or by following a given function over time.Dimensionless forms of the solutions are also proposed.A computer code FlowCAS is developed to calculate the solutions.Calculated results demonstrate the correctness of the presented solutions.The library is widely applicable to solve contaminant transport problems of one-or multiple-dimensions in uniform flow fields.展开更多
In the paper,the asymptotic behavior of the solution for the parabolic equation system of porous media coupled by three variables and with weighted nonlocal boundaries and nonlinear internal sources is studied.by cons...In the paper,the asymptotic behavior of the solution for the parabolic equation system of porous media coupled by three variables and with weighted nonlocal boundaries and nonlinear internal sources is studied.by constructing the upper and lower solutions with the ordinary differential equation as well as introducing the comparison theorem,the global existence and finite time blow-up of the solution of parabolic equations of porous media coupled by the power function and the logarithm function are obtained.The differential inequality technique is used to obtain the lower bounds on the blow up time of the above equations under Dirichlet and Neumann boundaryconditions.展开更多
基金supported by the National High Technology Research and Development Program (863 Program,2015AA034603)the National Natural Science Foundation of China (21377008,201077007,20973017)+1 种基金Foundation on the Creative Research Team Construction Promotion Project of Beijing Municipal InstitutionsScientific Research Base Construction-Science and Technology Creation Platform National Materials Research Base Construction~~
文摘Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalysts. Many catalysts including transition metal oxides, mixed metal oxides, and sup‐ported noble metals have been developed. Among these catalysts, the porous ones attract much attention. In this review, we focus on recent advances in the synthesis of ordered mesoporous and macroporous transition metal oxides, perovskites, and supported noble metal catalysts and their catalytic oxidation of VOCs. The porous catalysts outperformed their bulk counterparts. This excel‐lent catalytic performance was due to their high surface areas, high concentration of adsorbed oxy‐gen species, low temperature reducibility, strong interaction between noble metal and support and highly dispersed noble metal nanoparticles and unique porous structures. Catalytic oxidation of carbon monoxide over typical catalysts was also discussed. We made conclusive remarks and pro‐posed future work for the removal of VOCs.
基金the funding support(Project Number.PolyU 152214/17E)from Research Grant Council,University Grants Committee,Hong Kong SARthe financial support from National Nature Science Foundation of China under contract No.21878158the National Key Research and Development Program of China under contract No.2018YFB0905402
文摘With a rising energy demand and anabatic environmental crisis arising from the fast growth in human population and society economics,numerous efforts have been devoted to explore and design plentiful multifunctional materials for meeting highefficiency energy transfer processes,which happen in various developed energy conversion and storage systems.As a special kind of multi-metal oxides,perovskite with attractive physical and chemical properties,is becoming a rapidly rising star on the horizon of high-performance catalytic materials with substantial research behaviors worldwide.The porous nanostructure in targeted catalysts is favorable to the catalytic activity and thus improves the overall efficiency of these energy-related installations.In this review paper,recent advances made in the porous perovskite nanostructures for catalyzing several anodic or cathodic reactions in fuel cells and metal-air batteries are comprehensively summarized.Plenty of general preparation methods employed to attain porous perovskite-type oxides are provided,followed by a further discussion about the influence of various strategies on structures and catalytic properties of the porous perovskites.Furthermore,deep insights gathered in the future development of porous perovskite-based materials for energy conversion and storage technologies are also provided.
基金supported by the National Natural Science Foundation of China (No.50806021)Program for Changjiang Scholars and Inn ovative Researeh Team in University (PCSIRT0720).
文摘A 3-dimensional unit cell model is developed for analyzing effective thermal conductivity of xonotlite-aerogelcomposite insulation material based on its microstructure features. Effective thermal conductivity comparisonsbetween xonotlite-type calcium silicate and aerogel as well as xonotlite-aerogel composite insulation material arepresented. It is shown that the density of xonotlite-type calcium silicate is the key factor affecting the effectivethermal conductivity of xonotlite-aerogel composite insulation material, and the density of aerogel has little influence.The effective thermal conductivity can be lowered greatly by composite of the two materials at an elevatedtemperature.
文摘A macroscopic yield criterion has been derived in the present work for a double saturated porous medium with a spheroidal pore at the mesocale and spherical pores at the microscale.These two types of pores are well separated at two different scales.The meso spheroidal pore saturated by a pore pressure which is different from the one in the micro spherical pores.A Drucker-Prager type criterion is adopted for the solid phase at the microscopic scale to describe its asymmetric behavior between tension and compression.The methodology to formulate this criterion is based on the limit analysis approach of a spheroidal volume containing a confocal spheroidal pore subjected to a uniform strain rate boundary conditions.The matrix at the mesoscopic scale obeys to a general elliptic yield criterion.Based on a two-step homogenization step,the influence of meso-pore shape(spherical,prolate or oblate),micro-porosity,meso-porosity and the effect of pore pressures at different scales are taken into account explicitly by this macroscopic yield criterion.
基金financially supported by the National Natural Science Foundation of China(20701005 & 20701006)the Fundamental Research Funds for the Central Universitues,Postdoctoral Station Foundation of Ministry of Education(20060200002)+1 种基金the Testing Foundation of Northeast Normal University(NENU),Science and Technology Creation Foundation of NENU(NENU-STC07009)the Program for Changjiang Scholars and Innovative Research Team in University
文摘Two new compounds with microporous Co3[MnMo9O32].15H2O(1) and Cu3[MnMo9O32].15H2O(2) have been synthesized,and characterized by IR,element analysis,TG and single-crystal X-ray analysis.The structure analyses reveal that compounds 1 and 2 are isostructural.In crystal,the Waugh-type polyoxoanions [MnMo9O32]6-are connected by Co2+ or Cu2+ cations to a 3D open-framework,which possesses channels along the [1 2 2] direction of approximately 8.27 × 11.97 .The photocatalytic performances of compounds 1 and 2 for photodegradation of RhB with UV irradiation have been studied,which show a good photocatalytic activity for photodegradation of RhB.
基金supported by the National Natural Science Foundation of China(21905148)China Postdoctoral Science Foundation(2019T120567 and 2017M612184)+2 种基金the 1000-Talents Planthe World-Class Discipline Programthe Taishan Scholars Advantageous and Distinctive Discipline Program of Shandong province for supporting the research team of energy storage materials.
文摘Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling performances.Herein,a bimetal ZnMn-based metal-organic framework(ZnMn-MOF)is engineered for in situ conversion of MnO-encapsulated porous carbon(MnO/PC)composite.The templating and activation effects of coordinated Zn endow the converted PC matrix with a highly porous structure.This enhances the compatibility of PC matrix with MnO particles,resulting in the full encapsulation of MnO particles in the PC matrix.More significantly,the PC matrix provides enough void space to buffer the volume change,which fully wraps the MnO without crack or fracture during repeated cycling.As a result,MnO/PC shows high charge storage capability,extraordinary rate performance,and long-term cycling stability at the same time.Thus MnO/PC exhibits high delithiation capacities of 768mA h g^(-1)at 0.1Ag^(-1)and 487mA h g^(-1)at a high rate of 0.7Ag^(-1),combined with an unattenuated cycling performance after 500 cycles at 0.3Ag^(-1).More significantly,MnO/PC demonstrates a well-matched performance with the capacitive activated carbon electrode in a Li-ion capacitor(LIC)full cell.LIC demonstrates a high specific energy of 153.6W h kg^(-1)at 210W kg^(-1),combined with a specific energy of 71.8W h kg^(-1)at a high specific power of 63.0kW kg^(-1).
基金This research was supported by National Scientific Supporting Plan of China(Grand No.2006BAC06B05).
文摘The purpose of this study is to present a library of analytical solutions for the three-dimensional contaminant transport in uniform flow field in porous media with the first-order decay,linear sorption,and zero-order production.The library is constructed using Green's function method(GFM)in combination with available solutions.The library covers a wide range of solutions for various conditions.The aquifer can be vertically finite,semi-infinitive or infinitive,and laterally semi-infinitive or infinitive.The geometry of the sources can be of point,line,plane or volumetric body;and the source release can be continuous,instantaneous,or by following a given function over time.Dimensionless forms of the solutions are also proposed.A computer code FlowCAS is developed to calculate the solutions.Calculated results demonstrate the correctness of the presented solutions.The library is widely applicable to solve contaminant transport problems of one-or multiple-dimensions in uniform flow fields.
基金supported by Natural Science Basic Research Project of Shaanxi Province(2019JM-534)Soft Science Project of Shaanxi Province(2019KRM169)+3 种基金Project of Qi Fang Education Research Institute of Xian International University(21mjy07)Special project support of the 14th five year plan of the China Association of Higher Education(Topic name:Research on the adaptability of specialty structure and industrial structure of Local Universities-a case study of Shaanxi Province,No:21DFD04)2021 youth innovation team construction scientific research plan project of Shaanxi Provincial Department of Education(21JP105)The Youth Innovation Team of Shaanxi Universities,Shaanxi educational science"14th five year plan"project(SGH21Y0308).
文摘In the paper,the asymptotic behavior of the solution for the parabolic equation system of porous media coupled by three variables and with weighted nonlocal boundaries and nonlinear internal sources is studied.by constructing the upper and lower solutions with the ordinary differential equation as well as introducing the comparison theorem,the global existence and finite time blow-up of the solution of parabolic equations of porous media coupled by the power function and the logarithm function are obtained.The differential inequality technique is used to obtain the lower bounds on the blow up time of the above equations under Dirichlet and Neumann boundaryconditions.
