A novel polymer-supported metallocene catalyst has been prepared. The polymer-support-ed metallocene displayed considerably high activity in ethylene polymerization, the highest being 3.62× 107 g/(mol · h), ...A novel polymer-supported metallocene catalyst has been prepared. The polymer-support-ed metallocene displayed considerably high activity in ethylene polymerization, the highest being 3.62× 107 g/(mol · h), the molecular weight of the polyethylene produced was Mn = 1.29 × 105 , about 3～4 times those prepared by corresponding homogeneous zirconocenes. The polymer-supported metallocene poly(styrene-acrylamide)supported zirconocene]keeps thecharacteristics of homogeneous metallocene catalysts, and offers some features, such as adaptable togas phase and slurry processes; easy to prepare in low cost; relatively high activity and lowerMAO/Zr ratio ; lower inorganic residues in the polyolefins as compared to those using SiO2, Al2O3 orMgCl2; unitary active structure, no complex surface as with SiO2; good control of morphology of theresulting polymer.展开更多
A new polymer-supported metallocene catalyst has been prepared, The polymer-supported metallocene displayed considerably high activity in ethylene polymerization, the highest being 3.62x10(7) gPE/molZr.h, the molecula...A new polymer-supported metallocene catalyst has been prepared, The polymer-supported metallocene displayed considerably high activity in ethylene polymerization, the highest being 3.62x10(7) gPE/molZr.h, the molecular weight of the polyethylene produced was Mn = 1.29x10(5). about 3-4 times those of corresponding homogeneous zirconocenes. The polymer-supported metallocene keeps the characteristics of homogeneous metallocene catalysts, and offers some features, such as adaptable to gas phase and slurry processes: easy to prepare in low cost: relatively high activity and lower MAO/Zr ratio; lower inorganic residues in the polyolefins as compared to cases of SiO2, Al2O3 or MgCl2; unitary active structure, no complex surface as with SiO2; good control of morphology of the resulting polymer.展开更多
Applying chemical flooding in petroleum reservoirs turns into interesting subject of the recent researches.Developing strategies of the aforementioned method are more robust and precise when they consider both economi...Applying chemical flooding in petroleum reservoirs turns into interesting subject of the recent researches.Developing strategies of the aforementioned method are more robust and precise when they consider both economical point of views(net present value(NPV))and technical point of views(recovery factor(RF)).In the present study huge attempts are made to propose predictive model for specifying efficiency of chemical flooding in oil reservoirs.To gain this goal,the new type of support vector machine method which evolved by Suykens and Vandewalle was employed.Also,high precise chemical flooding data banks reported in previous works were employed to test and validate the proposed vector machine model.According to the mean square error(MSE),correlation coefficient and average absolute relative deviation,the suggested LSSVM model has acceptable reliability;integrity and robustness.Thus,the proposed intelligent based model can be considered as an alternative model to monitor the efficiency of chemical flooding in oil reservoir when the required experimental data are not available or accessible.展开更多
D-72 resin supported nickel-copper catalysts prepared by solvated metal atom impregnation (SMAI) were studied by magnetic measurements and X-ray photoelectron spectroscopy (XPS). The Ni particles on the catalysts are ...D-72 resin supported nickel-copper catalysts prepared by solvated metal atom impregnation (SMAI) were studied by magnetic measurements and X-ray photoelectron spectroscopy (XPS). The Ni particles on the catalysts are very highly dispersed and display superparamagnetic behaviour. Ni-Cu alloy clusters were found to be formed. The surface compositions are different from the bulk concentrations. In contrast with the surface enrichment in copper generally observed on conventional Ni-Cu catalysts, the surfaces of these catalysts are enriched in nickel. The nickel is in both zero and valent states, while copper is mainly in metallic state. Catalytic data show that the formation of Ni-Cu alloy clusters has a profound effect on the catalytic activities of the catalysts in the hydrogenation of furfural. The activity of the Ni:Cu ratio of one bimetallic catalysts is much higher than that of the Ni or Cu monometallic catalyst.展开更多
A new chelating polymer support has been prepared by suspension copolymerization of synthesized N,N'-bis(3- allyl salicylidene)ethylenediamine monomer Schiff base (N,N'-BSEDA) with styrene (St) and divinylbenz...A new chelating polymer support has been prepared by suspension copolymerization of synthesized N,N'-bis(3- allyl salicylidene)ethylenediamine monomer Schiff base (N,N'-BSEDA) with styrene (St) and divinylbenzene (DVB) using azobisisobutyronitrile (AIBN) as initiator in the presence of poly(vinyl alcohol). The content and complexation ability of monomer Schiff base (N,N'-BSEDA) for cobalt ions in prepared crosslinked polymer beads have shown dependence on the amount of DVB used in reaction mixture. The amount of monomer Schiff base (N,N '-BSEDA) in crosslinked beads showed a substantial decreasing trend at high concentration of DVB in the reaction mixture (> 1.5 mol dm-3), hence the efficiency of complexation (EC%) and cobalt ion loading (EL%) of polymer beads showed a decreasing trend. The structure of monomer Schiff base (N,N'-BSEDA) and its cobalt complex on polymer support was elucidated by IR, UV and magnetic measurements. The catalytic activity of polymer bound cobalt Schiff base complex was evaluated by analyzing kinetic data of decomposition of hydrogen peroxide in the presence of either supported cobalt complex or free cobalt complex. The activation energy for the decomposition of hydrogen peroxide by polymer supported cobalt complex was found to be low (33.37 kJ mol-1) in comparison with unsupported cobalt complex (56.35 kJ mol-1). On the basis of experimental observations, reaction steps are proposed and a suitable rate expression derived.展开更多
Support vector regression (SVR) combined with particle swarm optimization (PSO) for its parameter optimization, was proposed to establish a model to predict the thermal conductivity of polymer-based composites under d...Support vector regression (SVR) combined with particle swarm optimization (PSO) for its parameter optimization, was proposed to establish a model to predict the thermal conductivity of polymer-based composites under different mass fractions of fillers (mass fraction of polyethylene (PE) and mass fraction of polystyrene (PS)). The prediction performance of SVR was compared with those of other two theoretical models of spherical packing and flake packing. The result demonstrated that the estimated errors by leave-one-out cross validation (LOOCV) test of SVR models, such as mean absolute error (MAE) and mean absolute percentage error (MAPE), all are smaller than those achieved by the two theoretical models via applying identical samples. It is revealed that the generalization ability of SVR model is superior to those of the two theoretical models. This study suggests that SVR can be used as a powerful approach to foresee the thermal property of polymer-based composites under different mass fractions of polyethylene and polystyrene fillers.展开更多
文摘A novel polymer-supported metallocene catalyst has been prepared. The polymer-support-ed metallocene displayed considerably high activity in ethylene polymerization, the highest being 3.62× 107 g/(mol · h), the molecular weight of the polyethylene produced was Mn = 1.29 × 105 , about 3～4 times those prepared by corresponding homogeneous zirconocenes. The polymer-supported metallocene poly(styrene-acrylamide)supported zirconocene]keeps thecharacteristics of homogeneous metallocene catalysts, and offers some features, such as adaptable togas phase and slurry processes; easy to prepare in low cost; relatively high activity and lowerMAO/Zr ratio ; lower inorganic residues in the polyolefins as compared to those using SiO2, Al2O3 orMgCl2; unitary active structure, no complex surface as with SiO2; good control of morphology of theresulting polymer.
文摘A new polymer-supported metallocene catalyst has been prepared, The polymer-supported metallocene displayed considerably high activity in ethylene polymerization, the highest being 3.62x10(7) gPE/molZr.h, the molecular weight of the polyethylene produced was Mn = 1.29x10(5). about 3-4 times those of corresponding homogeneous zirconocenes. The polymer-supported metallocene keeps the characteristics of homogeneous metallocene catalysts, and offers some features, such as adaptable to gas phase and slurry processes: easy to prepare in low cost: relatively high activity and lower MAO/Zr ratio; lower inorganic residues in the polyolefins as compared to cases of SiO2, Al2O3 or MgCl2; unitary active structure, no complex surface as with SiO2; good control of morphology of the resulting polymer.
文摘Applying chemical flooding in petroleum reservoirs turns into interesting subject of the recent researches.Developing strategies of the aforementioned method are more robust and precise when they consider both economical point of views(net present value(NPV))and technical point of views(recovery factor(RF)).In the present study huge attempts are made to propose predictive model for specifying efficiency of chemical flooding in oil reservoirs.To gain this goal,the new type of support vector machine method which evolved by Suykens and Vandewalle was employed.Also,high precise chemical flooding data banks reported in previous works were employed to test and validate the proposed vector machine model.According to the mean square error(MSE),correlation coefficient and average absolute relative deviation,the suggested LSSVM model has acceptable reliability;integrity and robustness.Thus,the proposed intelligent based model can be considered as an alternative model to monitor the efficiency of chemical flooding in oil reservoir when the required experimental data are not available or accessible.
文摘D-72 resin supported nickel-copper catalysts prepared by solvated metal atom impregnation (SMAI) were studied by magnetic measurements and X-ray photoelectron spectroscopy (XPS). The Ni particles on the catalysts are very highly dispersed and display superparamagnetic behaviour. Ni-Cu alloy clusters were found to be formed. The surface compositions are different from the bulk concentrations. In contrast with the surface enrichment in copper generally observed on conventional Ni-Cu catalysts, the surfaces of these catalysts are enriched in nickel. The nickel is in both zero and valent states, while copper is mainly in metallic state. Catalytic data show that the formation of Ni-Cu alloy clusters has a profound effect on the catalytic activities of the catalysts in the hydrogenation of furfural. The activity of the Ni:Cu ratio of one bimetallic catalysts is much higher than that of the Ni or Cu monometallic catalyst.
文摘A new chelating polymer support has been prepared by suspension copolymerization of synthesized N,N'-bis(3- allyl salicylidene)ethylenediamine monomer Schiff base (N,N'-BSEDA) with styrene (St) and divinylbenzene (DVB) using azobisisobutyronitrile (AIBN) as initiator in the presence of poly(vinyl alcohol). The content and complexation ability of monomer Schiff base (N,N'-BSEDA) for cobalt ions in prepared crosslinked polymer beads have shown dependence on the amount of DVB used in reaction mixture. The amount of monomer Schiff base (N,N '-BSEDA) in crosslinked beads showed a substantial decreasing trend at high concentration of DVB in the reaction mixture (> 1.5 mol dm-3), hence the efficiency of complexation (EC%) and cobalt ion loading (EL%) of polymer beads showed a decreasing trend. The structure of monomer Schiff base (N,N'-BSEDA) and its cobalt complex on polymer support was elucidated by IR, UV and magnetic measurements. The catalytic activity of polymer bound cobalt Schiff base complex was evaluated by analyzing kinetic data of decomposition of hydrogen peroxide in the presence of either supported cobalt complex or free cobalt complex. The activation energy for the decomposition of hydrogen peroxide by polymer supported cobalt complex was found to be low (33.37 kJ mol-1) in comparison with unsupported cobalt complex (56.35 kJ mol-1). On the basis of experimental observations, reaction steps are proposed and a suitable rate expression derived.
基金supported by the Program for New Century Excellent Talents in University of China (Grant No. NCET-07-0903)the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Ministry of Education, China (Grant No. 2008101-1)+2 种基金the Fundamental Research Funds for the Central Universities (Grant Nos. CDJXS10101107, CDJXS10100037)the Natural Science Foundation of Chongqing, China (Grant No. CSTC2006BB5240)the Innovative Talent Training Project of the Third Stage of "211 Project", Chongqing University (Grant No. S-09109)
文摘Support vector regression (SVR) combined with particle swarm optimization (PSO) for its parameter optimization, was proposed to establish a model to predict the thermal conductivity of polymer-based composites under different mass fractions of fillers (mass fraction of polyethylene (PE) and mass fraction of polystyrene (PS)). The prediction performance of SVR was compared with those of other two theoretical models of spherical packing and flake packing. The result demonstrated that the estimated errors by leave-one-out cross validation (LOOCV) test of SVR models, such as mean absolute error (MAE) and mean absolute percentage error (MAPE), all are smaller than those achieved by the two theoretical models via applying identical samples. It is revealed that the generalization ability of SVR model is superior to those of the two theoretical models. This study suggests that SVR can be used as a powerful approach to foresee the thermal property of polymer-based composites under different mass fractions of polyethylene and polystyrene fillers.
