通过分析不同粗糙度下的316L不锈钢在0.01 mol/L Na Cl溶液中小孔腐蚀早期的电流波动,研究了粗糙度与不锈钢亚稳态孔蚀电位Em和稳定孔蚀电位Eb之间的关系,以及粗糙度(Ra)对亚稳态小孔生长机制的影响。结果表明,Em和Eb均随Ra的对数的增...通过分析不同粗糙度下的316L不锈钢在0.01 mol/L Na Cl溶液中小孔腐蚀早期的电流波动,研究了粗糙度与不锈钢亚稳态孔蚀电位Em和稳定孔蚀电位Eb之间的关系,以及粗糙度(Ra)对亚稳态小孔生长机制的影响。结果表明,Em和Eb均随Ra的对数的增大而线性下降;Ra增大,亚稳孔的平均形核率和平均寿命增大,生长速率变化不大,但是同样的生长速率下粗糙表面的亚稳孔具有更强的可持续生长能力,加之高的形核频率导致强的腐蚀累积效应促进了亚稳态小孔向稳定孔的转变。展开更多
采用极化曲线、电化学交流阻抗谱、X射线衍射仪(XRD)测试残余应力、扫描电镜(SEM)测试腐蚀形貌从实验上研究了强激光冲击对7075铝合金等离子弧焊接头电化学腐蚀行为的影响。研究结果表明,激光冲击后7075铝合金焊接头表面残余应力由拉应...采用极化曲线、电化学交流阻抗谱、X射线衍射仪(XRD)测试残余应力、扫描电镜(SEM)测试腐蚀形貌从实验上研究了强激光冲击对7075铝合金等离子弧焊接头电化学腐蚀行为的影响。研究结果表明,激光冲击后7075铝合金焊接头表面残余应力由拉应力变成压应力,从而使得铝合金等离子弧焊接头的自腐蚀电位和点蚀电位提高,激光冲击4次后自腐蚀电位正移700 m V,点蚀电位正移约为1000 m V,极化曲线上出现了电位范围至712.9 m V的阳极钝化区间。经过激光冲击处理细化晶粒,7075铝合金焊接头的显微孔洞数量和气穴的体积减少,组织致密性提高,溶液中Cl等原子的渗入被有效阻止,从而降低了腐蚀速率,使自腐蚀电流密度降低了1个数量级。激光冲击使焊接头处晶粒沿β相分布变得均匀,β相与α基相构成的微电偶的活性降低,钝化电阻比冲击前提高了近30倍,浓差极化现象大为改善。展开更多
Corrosion behavior of 2024 Al-Cu-Mg alloy of different tempers was assessed by potentiodynamic polarization studies in 3.5% NaCl solution, 3.5% NaCI＋I.0% H2O2 solution and 3.5% NaCl solution at pH 12. Polarization cu...Corrosion behavior of 2024 Al-Cu-Mg alloy of different tempers was assessed by potentiodynamic polarization studies in 3.5% NaCl solution, 3.5% NaCI＋I.0% H2O2 solution and 3.5% NaCl solution at pH 12. Polarization curves showed shifting of corrosion potential （φPcor） towards more negative potential with increasing ageing time and shifting of φcorr in the positive direction with the addition of H2O2 in NaCl solution. Polarization curves in 3.5% NaCl solution at pH 12 exhibited distinct passivity phenomenon. Optical micrographs of the corroded surfaces showed general corrosion, extensive pitting and intergranular corrosion as well. Cyclic potentiodynamic polarization curves exhibited wide hysteresis loop and the mode of corrosion attack confirmed that the alloy states are susceptible to pit growth damage. Attempts were made to explain the observed corrosion behavior of the alloy of various tempers in different electrolytes with the help of microstructural features.展开更多
文摘通过分析不同粗糙度下的316L不锈钢在0.01 mol/L Na Cl溶液中小孔腐蚀早期的电流波动,研究了粗糙度与不锈钢亚稳态孔蚀电位Em和稳定孔蚀电位Eb之间的关系,以及粗糙度(Ra)对亚稳态小孔生长机制的影响。结果表明,Em和Eb均随Ra的对数的增大而线性下降;Ra增大,亚稳孔的平均形核率和平均寿命增大,生长速率变化不大,但是同样的生长速率下粗糙表面的亚稳孔具有更强的可持续生长能力,加之高的形核频率导致强的腐蚀累积效应促进了亚稳态小孔向稳定孔的转变。
文摘采用极化曲线、电化学交流阻抗谱、X射线衍射仪(XRD)测试残余应力、扫描电镜(SEM)测试腐蚀形貌从实验上研究了强激光冲击对7075铝合金等离子弧焊接头电化学腐蚀行为的影响。研究结果表明,激光冲击后7075铝合金焊接头表面残余应力由拉应力变成压应力,从而使得铝合金等离子弧焊接头的自腐蚀电位和点蚀电位提高,激光冲击4次后自腐蚀电位正移700 m V,点蚀电位正移约为1000 m V,极化曲线上出现了电位范围至712.9 m V的阳极钝化区间。经过激光冲击处理细化晶粒,7075铝合金焊接头的显微孔洞数量和气穴的体积减少,组织致密性提高,溶液中Cl等原子的渗入被有效阻止,从而降低了腐蚀速率,使自腐蚀电流密度降低了1个数量级。激光冲击使焊接头处晶粒沿β相分布变得均匀,β相与α基相构成的微电偶的活性降低,钝化电阻比冲击前提高了近30倍,浓差极化现象大为改善。
文摘Corrosion behavior of 2024 Al-Cu-Mg alloy of different tempers was assessed by potentiodynamic polarization studies in 3.5% NaCl solution, 3.5% NaCI＋I.0% H2O2 solution and 3.5% NaCl solution at pH 12. Polarization curves showed shifting of corrosion potential （φPcor） towards more negative potential with increasing ageing time and shifting of φcorr in the positive direction with the addition of H2O2 in NaCl solution. Polarization curves in 3.5% NaCl solution at pH 12 exhibited distinct passivity phenomenon. Optical micrographs of the corroded surfaces showed general corrosion, extensive pitting and intergranular corrosion as well. Cyclic potentiodynamic polarization curves exhibited wide hysteresis loop and the mode of corrosion attack confirmed that the alloy states are susceptible to pit growth damage. Attempts were made to explain the observed corrosion behavior of the alloy of various tempers in different electrolytes with the help of microstructural features.
