采用碱活化过一硫酸盐(peroxymonosulfate,PMS)对环丙沙星(ciprofloxacin,CIP)的去除进行了系统地研究.结果表明,碱活化PMS体系能够高效地去除CIP.通过自由基捕获实验确定了单线态氧(~1O_2)和超氧自由基(O_2^-·)是反应体系中的主...采用碱活化过一硫酸盐(peroxymonosulfate,PMS)对环丙沙星(ciprofloxacin,CIP)的去除进行了系统地研究.结果表明,碱活化PMS体系能够高效地去除CIP.通过自由基捕获实验确定了单线态氧(~1O_2)和超氧自由基(O_2^-·)是反应体系中的主要活性物种.NaOH浓度、PMS浓度、反应温度和共存阴离子等对CIP在碱活化PMS体系中的去除均有一定影响.随着NaOH和PMS浓度的增加,CIP的降解均呈现出先增加后降低的趋势.提高反应温度能够加大CIP的反应速率,经过阿伦尼乌斯方程拟合得到的反应活化能为5.09 k J·mol^(-1).不同的阴离子对CIP的去除呈现不同的影响:Cl^-、SO_4^(2-)和NO_3^-对CIP的降解没有呈现明显的作用,H_2PO_4^(2-)能够有效地抑制环丙沙星的去除,而CO_3^(2-)极大地促进了反应进程.通过UPLC-MS/MS可检测到10种降解产物,CIP分子结构中的哌嗪环易于受到活性物种的攻击.展开更多
Spontaneous combustion is one of the serious problems in the mining of sulfide ore deposits. The relevant factors, e.g. oxygen absorption quantity, mass increase, contents of water soluble iron ions and sulfate ion of...Spontaneous combustion is one of the serious problems in the mining of sulfide ore deposits. The relevant factors, e.g. oxygen absorption quantity, mass increase, contents of water soluble iron ions and sulfate ion of sulfide ore samples in the oxidation process were investigated both in theory and experiment. The results from the investigation show that there is no general interpretation relation among the oxygen absorption quantity, the contents of sulfate ion and water soluble iron ions during the oxidation process of sulfide ores at ambient temperature. However, there is a linear relationship between the mass increase of the sulfide ore samples in the oxidation process at ambient temperature and the quantity of oxygen absorption. Therefore, the simple and cheap mass scaling method is suitable for predicting the oxygen absorption performance of sulfide ores at ambient temperature in place of the expensive and complicated chemical method used hitherto. Furthermore, combined with other items of breeding fire test, the mass increase potential can also be used to predict the spontaneous combustion tendency of sulfide ores.展开更多
文摘采用碱活化过一硫酸盐(peroxymonosulfate,PMS)对环丙沙星(ciprofloxacin,CIP)的去除进行了系统地研究.结果表明,碱活化PMS体系能够高效地去除CIP.通过自由基捕获实验确定了单线态氧(~1O_2)和超氧自由基(O_2^-·)是反应体系中的主要活性物种.NaOH浓度、PMS浓度、反应温度和共存阴离子等对CIP在碱活化PMS体系中的去除均有一定影响.随着NaOH和PMS浓度的增加,CIP的降解均呈现出先增加后降低的趋势.提高反应温度能够加大CIP的反应速率,经过阿伦尼乌斯方程拟合得到的反应活化能为5.09 k J·mol^(-1).不同的阴离子对CIP的去除呈现不同的影响:Cl^-、SO_4^(2-)和NO_3^-对CIP的降解没有呈现明显的作用,H_2PO_4^(2-)能够有效地抑制环丙沙星的去除,而CO_3^(2-)极大地促进了反应进程.通过UPLC-MS/MS可检测到10种降解产物,CIP分子结构中的哌嗪环易于受到活性物种的攻击.
文摘Spontaneous combustion is one of the serious problems in the mining of sulfide ore deposits. The relevant factors, e.g. oxygen absorption quantity, mass increase, contents of water soluble iron ions and sulfate ion of sulfide ore samples in the oxidation process were investigated both in theory and experiment. The results from the investigation show that there is no general interpretation relation among the oxygen absorption quantity, the contents of sulfate ion and water soluble iron ions during the oxidation process of sulfide ores at ambient temperature. However, there is a linear relationship between the mass increase of the sulfide ore samples in the oxidation process at ambient temperature and the quantity of oxygen absorption. Therefore, the simple and cheap mass scaling method is suitable for predicting the oxygen absorption performance of sulfide ores at ambient temperature in place of the expensive and complicated chemical method used hitherto. Furthermore, combined with other items of breeding fire test, the mass increase potential can also be used to predict the spontaneous combustion tendency of sulfide ores.
