Anticorrosion epoxy coatings from Al and Zn based pigments were synthesized by adjusting their volume ratios, aiming at their increasing anticorrosion performances. The anticorrosion properties were examined via elec-...Anticorrosion epoxy coatings from Al and Zn based pigments were synthesized by adjusting their volume ratios, aiming at their increasing anticorrosion performances. The anticorrosion properties were examined via elec- trochemical impedance spectroscopy, Tafel polarization curve analysis and salt spray test. The coating morphologies before and after the salt spray tests were studied via scanning electron microscopy(SEM). The elemental and chemical compositions of the corroded surfaces of the coatings were analyzed by means of X-ray photoelectron spectroscopy(XPS). The results indicate that the coating composed of Al/Zn at 10:1(volume ratio) displays the maximum anticorrosion performances, which are superior to those of pristine Al or Zn based pigment.展开更多
为提高有机颜料在水中的分散性(D.E.),研究了颜料P.R.254、P.R.255和P.V.19在紫外光照射下的表面改性。经紫外光照射后,颜料在水中的D.E.均得到明显提高,即使经过长时间静置(如24h),其D.E.仍比未处理的样品高。对于P.R.255,D.E.可提高74...为提高有机颜料在水中的分散性(D.E.),研究了颜料P.R.254、P.R.255和P.V.19在紫外光照射下的表面改性。经紫外光照射后,颜料在水中的D.E.均得到明显提高,即使经过长时间静置(如24h),其D.E.仍比未处理的样品高。对于P.R.255,D.E.可提高74.0%;对于P.R.254,D.E.可提高67 4%;对于P.V.19,D E 可提高100.0%。在相同光强度下,对于P.R.255和P.V.19,照射时间越长,颜料的D.E.越好;对于P.R.254,照射时间延长,D.E.下降,但仍比未处理样品高。光强度对颜料D.E.的影响无规律性。还比较了处理后颜料的色光、透明度、墨色及流动性。展开更多
基金Supported by the National High Technology Research and Development Program of China(Nos.2010AA09Z203, 2010AA065104), the National Natural Science Foundation of China(Nos.51003099, 51102219) and the National Key Technology Research and Development Program of the Ministry of Science and Technology of China(No.2012BAB 15B02).
文摘Anticorrosion epoxy coatings from Al and Zn based pigments were synthesized by adjusting their volume ratios, aiming at their increasing anticorrosion performances. The anticorrosion properties were examined via elec- trochemical impedance spectroscopy, Tafel polarization curve analysis and salt spray test. The coating morphologies before and after the salt spray tests were studied via scanning electron microscopy(SEM). The elemental and chemical compositions of the corroded surfaces of the coatings were analyzed by means of X-ray photoelectron spectroscopy(XPS). The results indicate that the coating composed of Al/Zn at 10:1(volume ratio) displays the maximum anticorrosion performances, which are superior to those of pristine Al or Zn based pigment.
文摘为提高有机颜料在水中的分散性(D.E.),研究了颜料P.R.254、P.R.255和P.V.19在紫外光照射下的表面改性。经紫外光照射后,颜料在水中的D.E.均得到明显提高,即使经过长时间静置(如24h),其D.E.仍比未处理的样品高。对于P.R.255,D.E.可提高74.0%;对于P.R.254,D.E.可提高67 4%;对于P.V.19,D E 可提高100.0%。在相同光强度下,对于P.R.255和P.V.19,照射时间越长,颜料的D.E.越好;对于P.R.254,照射时间延长,D.E.下降,但仍比未处理样品高。光强度对颜料D.E.的影响无规律性。还比较了处理后颜料的色光、透明度、墨色及流动性。