以壬酸、油酸、新润滑油及对应的氧化润滑油为分散样品,以-10号军用柴油为分散介质,在施加64 V直流偏置电压和长时间静置的条件下,介电谱分析技术表征的不同分散体系的介电亚微相态变化规律为:0.3 m L分散样品与3 m L分散介质形成的均...以壬酸、油酸、新润滑油及对应的氧化润滑油为分散样品,以-10号军用柴油为分散介质,在施加64 V直流偏置电压和长时间静置的条件下,介电谱分析技术表征的不同分散体系的介电亚微相态变化规律为:0.3 m L分散样品与3 m L分散介质形成的均匀分散体系的介电谱实部响应数据与柴油分散介质几乎没有差异;壬酸和油酸均匀分散体系与柴油分散介质的介电谱虚部响应数据差异极小,新润滑油和对应氧化润滑油形成的均匀分散体系与柴油分散介质的介电虚部响应数据有明显差异。0.3 m L分散样品在3 m L分散介质中分散时,壬酸、油酸、新润滑油及对应的氧化润滑油体系的介电谱实部和虚部响应数据与柴油分散介质之间的差异具有不同特点,且施加直流偏置电压对分散过程有较大促进作用。研究结果证明,介电谱能够较好地表征不同分散体系的介电亚微相态特征。展开更多
α-MnO2 nanotubes and their supported Au-Pd alloy nanocatalysts were prepared using hydrothermal and polyvinyl alcohol-protected reduction methods, respectively. Their catalytic activity for the oxidation of toluene/m...α-MnO2 nanotubes and their supported Au-Pd alloy nanocatalysts were prepared using hydrothermal and polyvinyl alcohol-protected reduction methods, respectively. Their catalytic activity for the oxidation of toluene/m-xylene, acetone/ethyl acetate, acetone/m-xylene and ethyl acetate/m-xylene mixtures was evaluated. It was found that the interaction between Au-Pd alloy nanoparticles and α-MnO2 nanotubes significantly improved the reactivity of lattice oxygen, and the 0.91 wt.% Au0.48 Pd/α-MnO2 nanotube catalyst outperformed the α-MnO2 nanotube catalyst in the oxidation of toluene, m-xylene, ethyl acetate and acetone. Over the0.91 wt.% Au0.48 Pd/α-MnO2 nanotube catalyst,（i） toluene oxidation was greatly inhibited in the toluene/m-xylene mixture, while m-xylene oxidation was not influenced;（ii） acetone and ethyl acetate oxidation suffered a minor impact in the acetone/ethyl acetate mixture; and（iii） m-xylene oxidation was enhanced whereas the oxidation of the oxygenated VOCs（volatile organic compounds） was suppressed in the acetone/m-xylene or ethyl acetate/m-xylene mixtures. The competitive adsorption of these typical VOCs on the catalyst surface induced an inhibitive effect on their oxidation, and increasing the temperature favored the oxidation of the VOCs. The mixed VOCs could be completely oxidized into CO2 and H2 O below 320°C at a space velocity of 40,000 m L/（g·hr）. The 0.91 wt.% Au0.48 Pd/α-MnO2 nanotube catalyst exhibited high catalytic stability as well as good tolerance to water vapor and CO2 in the oxidation of the VOC mixtures. Thus, the α-MnO2 nanotube-supported noble metal alloy catalysts hold promise for the efficient elimination of VOC mixtures.展开更多
文摘以壬酸、油酸、新润滑油及对应的氧化润滑油为分散样品,以-10号军用柴油为分散介质,在施加64 V直流偏置电压和长时间静置的条件下,介电谱分析技术表征的不同分散体系的介电亚微相态变化规律为:0.3 m L分散样品与3 m L分散介质形成的均匀分散体系的介电谱实部响应数据与柴油分散介质几乎没有差异;壬酸和油酸均匀分散体系与柴油分散介质的介电谱虚部响应数据差异极小,新润滑油和对应氧化润滑油形成的均匀分散体系与柴油分散介质的介电虚部响应数据有明显差异。0.3 m L分散样品在3 m L分散介质中分散时,壬酸、油酸、新润滑油及对应的氧化润滑油体系的介电谱实部和虚部响应数据与柴油分散介质之间的差异具有不同特点,且施加直流偏置电压对分散过程有较大促进作用。研究结果证明,介电谱能够较好地表征不同分散体系的介电亚微相态特征。
基金supported by the Natural Science Foundation of China(Nos.21622701,21477005,U1507108,and 21676028)National Key R&D Program of China(No.2016YFC0204800)+3 种基金Foundation for the Author of National Excellent Doctoral Dissertation of China(No.201462)Beijing Nova Program(No.Z141109001814106)Beijing Municipal Natural Science Foundation(No.2132015)Natural Science Foundation of Beijing Municipal Commission of Education(No.KM201410005008)
文摘α-MnO2 nanotubes and their supported Au-Pd alloy nanocatalysts were prepared using hydrothermal and polyvinyl alcohol-protected reduction methods, respectively. Their catalytic activity for the oxidation of toluene/m-xylene, acetone/ethyl acetate, acetone/m-xylene and ethyl acetate/m-xylene mixtures was evaluated. It was found that the interaction between Au-Pd alloy nanoparticles and α-MnO2 nanotubes significantly improved the reactivity of lattice oxygen, and the 0.91 wt.% Au0.48 Pd/α-MnO2 nanotube catalyst outperformed the α-MnO2 nanotube catalyst in the oxidation of toluene, m-xylene, ethyl acetate and acetone. Over the0.91 wt.% Au0.48 Pd/α-MnO2 nanotube catalyst,（i） toluene oxidation was greatly inhibited in the toluene/m-xylene mixture, while m-xylene oxidation was not influenced;（ii） acetone and ethyl acetate oxidation suffered a minor impact in the acetone/ethyl acetate mixture; and（iii） m-xylene oxidation was enhanced whereas the oxidation of the oxygenated VOCs（volatile organic compounds） was suppressed in the acetone/m-xylene or ethyl acetate/m-xylene mixtures. The competitive adsorption of these typical VOCs on the catalyst surface induced an inhibitive effect on their oxidation, and increasing the temperature favored the oxidation of the VOCs. The mixed VOCs could be completely oxidized into CO2 and H2 O below 320°C at a space velocity of 40,000 m L/（g·hr）. The 0.91 wt.% Au0.48 Pd/α-MnO2 nanotube catalyst exhibited high catalytic stability as well as good tolerance to water vapor and CO2 in the oxidation of the VOC mixtures. Thus, the α-MnO2 nanotube-supported noble metal alloy catalysts hold promise for the efficient elimination of VOC mixtures.
