Graphene,a rapidly rising star on the horizon of material science,has a unique two-dimensional nanostructure as well as exceptional mechanical and electronic properties.Despite its short history,graphene has exhibited...Graphene,a rapidly rising star on the horizon of material science,has a unique two-dimensional nanostructure as well as exceptional mechanical and electronic properties.Despite its short history,graphene has exhibited great potential in various applications.In order to implement the potential applications,functionalization of graphene is necessary to obtain uniform dispersions for good processability.Two kinds are dominant for functionalization such as covalent and non-covalent methods.The former is based on the formation of covalent bonds,and the latter the interaction among molecules.In this review,we summarized briefly the recent progress of functionalized graphene sheets (FGs) in different fields,such as optoelectronic materials,sensors,energy storage materials,catalytic,reinforcing components and so on,and also prospected the development trend of FGs in the future.展开更多
Metal-halide perovskites are novel optoelectronic materials that are considered good candidates for solar harvesting and light emitting applications. In this study, we develop a reproducible and low-cost approach for ...Metal-halide perovskites are novel optoelectronic materials that are considered good candidates for solar harvesting and light emitting applications. In this study, we develop a reproducible and low-cost approach for synthesizing high- quality cesium lead halide perovskite （CsPbX3, X = CI, Br, and I or C1/Br and I/Br） nanocrystals （NCs） by direct heating of precursors in octadecene in air. Experimental results show that the particle size and composition of as-prepared CsPbX3 nanocrystals can be successfully tuned by a simple variation of reaction temperature. The emission peak positions of the as-prepared nanocrystals can be conveniently tuned from the UV to the NIR （360-700 nm） region, and the quantum yield of the as-obtained samples （green and red emissions） can reach up to 87%. The structures and chemical compositions of the as-obtained NCs were characterized by transmission electron microscopy, X-ray diffraction, and elemental analysis. This proposed synthetic route can yield large amounts of high-quality NCs with a one-batch reaction, usually on the gram scale, and could pave the way for further applications of perovskite-based light-emitting and photovoltaic solar cells.展开更多
A review on the research and development of electronic and optoelectronic materials in China, including the main scientific activities in this field, is presented. The state\|of\|the\|arts and prospects of the electro...A review on the research and development of electronic and optoelectronic materials in China, including the main scientific activities in this field, is presented. The state\|of\|the\|arts and prospects of the electronic and optoelectronic materials in China are briefly introduced, such as those of silicon crystals, compound semiconductors, synthetic crystals,especially nonlinear optical crystals and rare\|earth permanent magnets materials, etc., with a greater emphasis on Chinese scientist’s contributions to the frontier area of nanomaterials and nanostructures in the past few years. A new concept of the trip chemistry proposed by Dr.Liu Zhongfan from Peking University has also been described. Finally the possible research grants and the national policy to support the scientific research have been discussed.展开更多
Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, ...Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH,suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 50873074, 51011140072)the National Basic Research Program of China ("973" Project) (Grant No. 2010CB934700)the Natural Science Foundation of Tianjin City (Grant No. 10JCZDJC22400)
文摘Graphene,a rapidly rising star on the horizon of material science,has a unique two-dimensional nanostructure as well as exceptional mechanical and electronic properties.Despite its short history,graphene has exhibited great potential in various applications.In order to implement the potential applications,functionalization of graphene is necessary to obtain uniform dispersions for good processability.Two kinds are dominant for functionalization such as covalent and non-covalent methods.The former is based on the formation of covalent bonds,and the latter the interaction among molecules.In this review,we summarized briefly the recent progress of functionalized graphene sheets (FGs) in different fields,such as optoelectronic materials,sensors,energy storage materials,catalytic,reinforcing components and so on,and also prospected the development trend of FGs in the future.
基金This work was supported by the National Natural Science Foundation of China （Nos. 21373097 and 51072067）.
文摘Metal-halide perovskites are novel optoelectronic materials that are considered good candidates for solar harvesting and light emitting applications. In this study, we develop a reproducible and low-cost approach for synthesizing high- quality cesium lead halide perovskite （CsPbX3, X = CI, Br, and I or C1/Br and I/Br） nanocrystals （NCs） by direct heating of precursors in octadecene in air. Experimental results show that the particle size and composition of as-prepared CsPbX3 nanocrystals can be successfully tuned by a simple variation of reaction temperature. The emission peak positions of the as-prepared nanocrystals can be conveniently tuned from the UV to the NIR （360-700 nm） region, and the quantum yield of the as-obtained samples （green and red emissions） can reach up to 87%. The structures and chemical compositions of the as-obtained NCs were characterized by transmission electron microscopy, X-ray diffraction, and elemental analysis. This proposed synthetic route can yield large amounts of high-quality NCs with a one-batch reaction, usually on the gram scale, and could pave the way for further applications of perovskite-based light-emitting and photovoltaic solar cells.
文摘从p-n结太阳电池的理论模型和InxGa1-xN带隙的经验公式出发,结合实际材料参数,通过改变In组分来调节InxGa1-xN带隙。计算了标准太阳光谱AM1.5光子通量及该光谱下InxGa1-xN单结和InxGa1-xN/Ga P异质双结太阳电池的光电转换效率。结果显示,InxGa1-xN单结太阳电池的最大转换效率是27.28%,与之对应的In组分为0.82。InxGa1-xN/Ga P异质双结太阳电池的最高转换效率为30.75%,对应的In组分是0.74。这些结果可作为设计制备In Ga N太阳电池的理论依据。
文摘A review on the research and development of electronic and optoelectronic materials in China, including the main scientific activities in this field, is presented. The state\|of\|the\|arts and prospects of the electronic and optoelectronic materials in China are briefly introduced, such as those of silicon crystals, compound semiconductors, synthetic crystals,especially nonlinear optical crystals and rare\|earth permanent magnets materials, etc., with a greater emphasis on Chinese scientist’s contributions to the frontier area of nanomaterials and nanostructures in the past few years. A new concept of the trip chemistry proposed by Dr.Liu Zhongfan from Peking University has also been described. Finally the possible research grants and the national policy to support the scientific research have been discussed.
基金financially supported by the National Natural Science Foundation of China (Nos. 21504047, 21774061)the Six Peak Talents Foundation of Jiangsu Province (No. XCL-CXTD009)+1 种基金Natural Science Foundation of Jiangsu Province (No. BK20150834)Synergetic Innovation Center for Organic Electronics and Information Displays
文摘Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH,suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers.
