The pore structure and oil content of shales have an important influence on the oil mobility and enrichment.In this study,the lacustrine shale samples from the Qingshankou Formation(Q1)of Songliao Basin were selected....The pore structure and oil content of shales have an important influence on the oil mobility and enrichment.In this study,the lacustrine shale samples from the Qingshankou Formation(Q1)of Songliao Basin were selected.TOC,pyrolysis,XRD and nitrogen adsorption were performed on the original and extracted shale samples.Then the influence of mineral composition and organic matter(OM)on the development of nano-scale pore,the oil phase states and mobility were analyzed.The Q1 shale samples can be sub-divided into three types according to the isotherm characteristics.Type A samples are characterized by high kerogen content,with oil mainly existing in the free phase state.Type B samples are characterized by medium kerogen content,oil mainly exists in the absorbed phase state.Type C samples are characterized by low kerogen content,with trace oil found in the absorbed phase state.Nano-scale organic pores are well developed in the Q1 Formation.Oil is primarily found in the pore spaces with diameters less than 10 nm,this being the pore size threshold for mobile shale oil.When TOC>2.0 wt%and EOM>1.0 wt%,Q1 Formation shale oil mobility is high,resulting in prospective drilling targets.展开更多
Polylactic acid(PLA) is one of the most suitable candidates for environmental pollution treatment because of its biodegradability which will not cause secondary pollution to the environment after application.However,t...Polylactic acid(PLA) is one of the most suitable candidates for environmental pollution treatment because of its biodegradability which will not cause secondary pollution to the environment after application.However,there is still a lack of a green and facile way to prepare PLA oil-water separation materials.In this work,a water-assisted thermally induced phase separation method for the preparation of superhydrophobic PLA oil-water separation material with honeycomb-like structures is reported.The PLA material shows great ability in application and could adsorb 27.3 times oil to its own weight.In addition,it could also be applicated as a filter with excellent efficiency(50.9 m^3 m^(-2) h^(-1)).展开更多
基金financially supported by the National Natural Science Foundation of China(No.41972156)the Science and Technology Project of Heilongjiang Province(No.2020ZX05A01)
文摘The pore structure and oil content of shales have an important influence on the oil mobility and enrichment.In this study,the lacustrine shale samples from the Qingshankou Formation(Q1)of Songliao Basin were selected.TOC,pyrolysis,XRD and nitrogen adsorption were performed on the original and extracted shale samples.Then the influence of mineral composition and organic matter(OM)on the development of nano-scale pore,the oil phase states and mobility were analyzed.The Q1 shale samples can be sub-divided into three types according to the isotherm characteristics.Type A samples are characterized by high kerogen content,with oil mainly existing in the free phase state.Type B samples are characterized by medium kerogen content,oil mainly exists in the absorbed phase state.Type C samples are characterized by low kerogen content,with trace oil found in the absorbed phase state.Nano-scale organic pores are well developed in the Q1 Formation.Oil is primarily found in the pore spaces with diameters less than 10 nm,this being the pore size threshold for mobile shale oil.When TOC>2.0 wt%and EOM>1.0 wt%,Q1 Formation shale oil mobility is high,resulting in prospective drilling targets.
基金National Natural Science Foundation of China(Nos.51803190,11432003,11572290)National Key Research and Development Program of China(No.2016YFB0101602)+2 种基金China Postdoctoral Science Foundation(Nos.2018M642779,2019M652573,2019T120643)International Postdoctoral Exchange Fellowship Program,University Key Research Project of Henan Province(No.18A430031)Guangdong Province Pearl River Scholar Funded Scheme(2016)for financial support。
文摘Polylactic acid(PLA) is one of the most suitable candidates for environmental pollution treatment because of its biodegradability which will not cause secondary pollution to the environment after application.However,there is still a lack of a green and facile way to prepare PLA oil-water separation materials.In this work,a water-assisted thermally induced phase separation method for the preparation of superhydrophobic PLA oil-water separation material with honeycomb-like structures is reported.The PLA material shows great ability in application and could adsorb 27.3 times oil to its own weight.In addition,it could also be applicated as a filter with excellent efficiency(50.9 m^3 m^(-2) h^(-1)).
