We investigated the structural and optical properties of ZnO thin films as an n-type semiconductor. The films were deposited at different precursor molarities using an ultrasonic spray method. In this paper we focused...We investigated the structural and optical properties of ZnO thin films as an n-type semiconductor. The films were deposited at different precursor molarities using an ultrasonic spray method. In this paper we focused our attention on a new approach describing a correlation between the crystallite size and optical gap energy with the precursor molarity of ZnO thin films. The results show that the X-ray diffraction （XRD） spectra revealed a preferred orientation of the crystallites along the c-axis. The maximum value of the crystallite size of the films is 63.99 nm obtained at 0.1 M. The films deposited with 0.1 M show lower absorption within the visible wavelength region. The optical gap energy increased from 3.08 to 3.37 eV with increasing precursor molarity of 0.05 to 0.1 M. The correlation between the structural and optical properties with the precursor molarity suggests that the crystallite size of the films is predominantly influenced by the band gap energy and the precursor molarity. The measurement of the crystallite size by the model proposed is equal to the experimental data. The minimum error value was estimated by Eq. （4） in the higher crystallinity.展开更多
This study aims to develop the alkali activated slag-fly ash concrete(AASFC) using precious slag(PS) ball as the fine aggregate. The slag-fly ash proportion, sodium silicate/sodium hydroxide(SS/SH) ratio and sodium hy...This study aims to develop the alkali activated slag-fly ash concrete(AASFC) using precious slag(PS) ball as the fine aggregate. The slag-fly ash proportion, sodium silicate/sodium hydroxide(SS/SH) ratio and sodium hydroxide concentration are the prime variables. The fresh concrete properties like workability, setting time and the hardened concrete properties of AASFC developed under ambient curing were analyzed and similar way by replacing with fly ash(FA). The sodium hydroxide concentration of 8 M, 10 M and 12 M, SS/SH ratio of 1.0, 1.5 and 2.0, alkaline liquid to binder ratio of 0.35 and variation in slag-fly ash proportion as major inputs for mix design. The test results showed that, the fresh state of AASFC blend has a shorter setting time of 12-16 min, because of calcium mineral from the FA, the workability and setting time of AASFC mix was enhanced by the addition of the trisodium phosphate as a retarder. At the higher SS/SH extent, the workability and setting time exaggerated, whereas the increased FA content and sodium hydroxide concentration had a greater influence on the fresh state of concrete. Also, the sodium hydroxide concentration, SS/SH ratio and slag-fly ash proportion are the most inducing parameters on the workability, setting time and strength parameters of AASFC.展开更多
The fly ash based geopolymer has emerged as a capable and sustainable binder material in construction industry.Ultrasonic pulse velocity(UPV)method is a non-destructive technique for investigating the mechanical perfo...The fly ash based geopolymer has emerged as a capable and sustainable binder material in construction industry.Ultrasonic pulse velocity(UPV)method is a non-destructive technique for investigating the mechanical performance of concrete.Experimental investigation was performed for studying the effect of NaOH Molarity,Na2SiO3/NaOH and curing temperature on the ultrasonic pulse velocity of geopolymer mortar.Experiments were designed based on central composite design(CCD)technique of response surface methodology(RSM).Statistical model was developed and statistically validated and found significant as the difference between adjustable R-squared and predicted R-squared less than 0.2.Finally,the optimized mix proportion was assessed for maximized value of UPV.Experimental validation on the optimized mix reveals the close agreement between experimental and predicted values of UPV with significance level of more than 95%.The proposed technique improves the yield,the reliability of the product and the processes.展开更多
文摘We investigated the structural and optical properties of ZnO thin films as an n-type semiconductor. The films were deposited at different precursor molarities using an ultrasonic spray method. In this paper we focused our attention on a new approach describing a correlation between the crystallite size and optical gap energy with the precursor molarity of ZnO thin films. The results show that the X-ray diffraction （XRD） spectra revealed a preferred orientation of the crystallites along the c-axis. The maximum value of the crystallite size of the films is 63.99 nm obtained at 0.1 M. The films deposited with 0.1 M show lower absorption within the visible wavelength region. The optical gap energy increased from 3.08 to 3.37 eV with increasing precursor molarity of 0.05 to 0.1 M. The correlation between the structural and optical properties with the precursor molarity suggests that the crystallite size of the films is predominantly influenced by the band gap energy and the precursor molarity. The measurement of the crystallite size by the model proposed is equal to the experimental data. The minimum error value was estimated by Eq. （4） in the higher crystallinity.
文摘This study aims to develop the alkali activated slag-fly ash concrete(AASFC) using precious slag(PS) ball as the fine aggregate. The slag-fly ash proportion, sodium silicate/sodium hydroxide(SS/SH) ratio and sodium hydroxide concentration are the prime variables. The fresh concrete properties like workability, setting time and the hardened concrete properties of AASFC developed under ambient curing were analyzed and similar way by replacing with fly ash(FA). The sodium hydroxide concentration of 8 M, 10 M and 12 M, SS/SH ratio of 1.0, 1.5 and 2.0, alkaline liquid to binder ratio of 0.35 and variation in slag-fly ash proportion as major inputs for mix design. The test results showed that, the fresh state of AASFC blend has a shorter setting time of 12-16 min, because of calcium mineral from the FA, the workability and setting time of AASFC mix was enhanced by the addition of the trisodium phosphate as a retarder. At the higher SS/SH extent, the workability and setting time exaggerated, whereas the increased FA content and sodium hydroxide concentration had a greater influence on the fresh state of concrete. Also, the sodium hydroxide concentration, SS/SH ratio and slag-fly ash proportion are the most inducing parameters on the workability, setting time and strength parameters of AASFC.
文摘The fly ash based geopolymer has emerged as a capable and sustainable binder material in construction industry.Ultrasonic pulse velocity(UPV)method is a non-destructive technique for investigating the mechanical performance of concrete.Experimental investigation was performed for studying the effect of NaOH Molarity,Na2SiO3/NaOH and curing temperature on the ultrasonic pulse velocity of geopolymer mortar.Experiments were designed based on central composite design(CCD)technique of response surface methodology(RSM).Statistical model was developed and statistically validated and found significant as the difference between adjustable R-squared and predicted R-squared less than 0.2.Finally,the optimized mix proportion was assessed for maximized value of UPV.Experimental validation on the optimized mix reveals the close agreement between experimental and predicted values of UPV with significance level of more than 95%.The proposed technique improves the yield,the reliability of the product and the processes.
