Kinetics of the decomposition of racemic ibuprofen crystals were studied by non-isothermal analysis. Thermogravimetric analysis revealed that ibuprofen is thermally stable up to 152.6°C and the initial loss of ma...Kinetics of the decomposition of racemic ibuprofen crystals were studied by non-isothermal analysis. Thermogravimetric analysis revealed that ibuprofen is thermally stable up to 152.6°C and the initial loss of mass was due to evaporation only. Activation energy, pre-exponential factor, activation entropy and Gibbs free energy for the decomposition of ibuprofen were determined using the integral method of Coats-Redfern (CR). Geometrical contraction models were found to be the best fits. The Arrheinus equation for the thermal decomposition of ibuprofen is k = (1.1 × 107) e–79125/RT sec–1.展开更多
利用随机样法构建种-面积曲线,对每一取样面积下的物种数进行999次随机抽样后计算均值,得到不同取样面积下的植物物种数,由此绘制实际种-面积曲线,并采用8种曲线模型拟合桂林岩溶石山常绿落叶阔叶混交林的种-面积关系,结合赤池信息量准...利用随机样法构建种-面积曲线,对每一取样面积下的物种数进行999次随机抽样后计算均值,得到不同取样面积下的植物物种数,由此绘制实际种-面积曲线,并采用8种曲线模型拟合桂林岩溶石山常绿落叶阔叶混交林的种-面积关系,结合赤池信息量准则AIC值及生物学意义确定最优拟合模型,通过对比群落总种数比例法、二阶导数法与实际种-面积曲线结果,最终确定桂林岩溶石山常绿落叶阔叶混交林的最小面积。结果表明,桂林岩溶石山常绿落叶阔叶混交林种-面积关系的最优拟合模型为累积韦伯分布模型(cumulative Weibull),拟合方程为S=73.8017(1-exp(-0.0138A ^(0.6685)))。二阶导数法比群落总种数比例法更具科学性和准确性,最终确定桂林岩溶石山常绿落叶阔叶混交林的最小面积为2500 m ^(2)。所以,最小面积的确定应根据实际区域的物种特征来确定。展开更多
基金National Natural Science Foundation of China under Grants 51076148 R&D Special Fund for Public Welfare Industry (forestry， 200704027)+1 种基金 Naian Liu was supported by the Fok Ying Tung Education FoundationHaixiang Chen was supported by National Natura1 Science Foundation of China under Grant 50806070
文摘Kinetics of the decomposition of racemic ibuprofen crystals were studied by non-isothermal analysis. Thermogravimetric analysis revealed that ibuprofen is thermally stable up to 152.6°C and the initial loss of mass was due to evaporation only. Activation energy, pre-exponential factor, activation entropy and Gibbs free energy for the decomposition of ibuprofen were determined using the integral method of Coats-Redfern (CR). Geometrical contraction models were found to be the best fits. The Arrheinus equation for the thermal decomposition of ibuprofen is k = (1.1 × 107) e–79125/RT sec–1.
文摘利用随机样法构建种-面积曲线,对每一取样面积下的物种数进行999次随机抽样后计算均值,得到不同取样面积下的植物物种数,由此绘制实际种-面积曲线,并采用8种曲线模型拟合桂林岩溶石山常绿落叶阔叶混交林的种-面积关系,结合赤池信息量准则AIC值及生物学意义确定最优拟合模型,通过对比群落总种数比例法、二阶导数法与实际种-面积曲线结果,最终确定桂林岩溶石山常绿落叶阔叶混交林的最小面积。结果表明,桂林岩溶石山常绿落叶阔叶混交林种-面积关系的最优拟合模型为累积韦伯分布模型(cumulative Weibull),拟合方程为S=73.8017(1-exp(-0.0138A ^(0.6685)))。二阶导数法比群落总种数比例法更具科学性和准确性,最终确定桂林岩溶石山常绿落叶阔叶混交林的最小面积为2500 m ^(2)。所以,最小面积的确定应根据实际区域的物种特征来确定。
