In the troposphere, ozone is a harmful gas compound to both human health and vegetation. Ozone is produced from the reaction of NO_x(@NO + NO_2) and VOCs(volatile organic compounds) with light. Due to the highly nonli...In the troposphere, ozone is a harmful gas compound to both human health and vegetation. Ozone is produced from the reaction of NO_x(@NO + NO_2) and VOCs(volatile organic compounds) with light. Due to the highly nonlinear relationships between ozone and its precursors, proper ozone mitigation relies on the knowledge of chemical mechanisms. In this study, an observation-based method is used to simulate ozone formation and elucidate its controlling factors for a rural site on the North China Plain. The instantaneous ozone production rate is calculated utilizing a box model using the dataset obtained from the Wangdu campaign. First, the model was operated in a time-dependent mode to calculate the ozone production rate at each time stamp. The calculated ozone formation rate showed a diurnal average maximum value of 17 ppbv/h(1-h diurnal averaged). The contribution of individual peroxy radicals to ozone production was analyzed. In addition, the functional dependence of calculated P(O_3) reveals that ozone production was in a NO_x-limited regime during the campaign. Furthermore, the missing peroxy radical source will further extend NO_x-limited conditions to earlier in the day, making NO_xlimitation dominate more of a day than the current chemical model predicts. Finally, a multiple scenarios mode,also known as EKMA(empirical kinetic modeling approach), was used to simulate the response of P(O_3) to the imaginary change in precursor concentrations. We found that ozone production was in the NO_x-limited region. However, the use of NO_2 measured by the molybdenum converter and/or the absence of a peroxy radical source in the current chemical model could over-emphasize the VOC-limited effect on ozone production.展开更多
Study on seasonal responses of terrestrial net primary production (NPP) to climate changes is to help understand feedback between climate systems and terrestrial ecosystems and mechanisms of increased NPP in the north...Study on seasonal responses of terrestrial net primary production (NPP) to climate changes is to help understand feedback between climate systems and terrestrial ecosystems and mechanisms of increased NPP in the northern middle and high latitudes. In this study, time series dataset of normalized difference vegetation index (NDVI) and corresponding ground-based information on vegetation, climate, soil, and solar radiation, together with an ecological process model, were used to explore the seasonal trends of terrestrial NPP and their geographical differences in China from 1982 to 1999. As the results,. seasonal total NPP in China showed a significant increase for all four seasons (spring, summer, autumn and winter) during the past 18 years. The spring NPP indicated the largest increase rate, while the summer NPP was with the largest increase in magnitude. The response of NPP to climate changes varied with different vegetation types. The increased NPP was primarily led by an advanced growing season for broadleaf evergreen forest, needle-leaf evergreen forest, and needle-leaf deciduous forest, whilst that was mainly due to enhanced vegetation activity (amplitude of growth cycle) during growing season for broadleaf deciduous forest, broadleaf and needle-leaf mixed forest, broadleaf trees with groundcover, perennial grasslands, broadleaf shrubs with grasslands, tundra, desert, and cultivation. The regions with the largest increase in spring NPP appeared mainly in eastern China, while the areas with the largest increase in summer NPP occurred in most parts of Northwestern China, Qinghai-Xizang Plateau, Mts. Xiaoxinganling-Changbaishan, Sanjiang Plain, Songliao Plain, Sichuan Basin, Leizhou Peninsula, part of the middle and lower Yangtze River, and southeastern mountainous areas of China. In autumn, the largest NPP increase appeared in Yunnan Plateau-Eastern Xizang and the areas around Hulun Lake. Such different ways of the NPP responses depended on regional climate attributes and their changes.展开更多
基金supported from the research projects of the Environmental Public Welfare Industry in China (201509001,201409005)the National Science and Technology Support Program of China (2014BAC21B01)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB05010500)the Special Fund of State Key Joint Laboratory of Environment Simulation and Pollution Control (18K03ESPCP)the EU-project AMIS (Fate and Impact of Atmospheric Pollutants,PIRSES-GA-2011295132)
文摘In the troposphere, ozone is a harmful gas compound to both human health and vegetation. Ozone is produced from the reaction of NO_x(@NO + NO_2) and VOCs(volatile organic compounds) with light. Due to the highly nonlinear relationships between ozone and its precursors, proper ozone mitigation relies on the knowledge of chemical mechanisms. In this study, an observation-based method is used to simulate ozone formation and elucidate its controlling factors for a rural site on the North China Plain. The instantaneous ozone production rate is calculated utilizing a box model using the dataset obtained from the Wangdu campaign. First, the model was operated in a time-dependent mode to calculate the ozone production rate at each time stamp. The calculated ozone formation rate showed a diurnal average maximum value of 17 ppbv/h(1-h diurnal averaged). The contribution of individual peroxy radicals to ozone production was analyzed. In addition, the functional dependence of calculated P(O_3) reveals that ozone production was in a NO_x-limited regime during the campaign. Furthermore, the missing peroxy radical source will further extend NO_x-limited conditions to earlier in the day, making NO_xlimitation dominate more of a day than the current chemical model predicts. Finally, a multiple scenarios mode,also known as EKMA(empirical kinetic modeling approach), was used to simulate the response of P(O_3) to the imaginary change in precursor concentrations. We found that ozone production was in the NO_x-limited region. However, the use of NO_2 measured by the molybdenum converter and/or the absence of a peroxy radical source in the current chemical model could over-emphasize the VOC-limited effect on ozone production.
文摘Study on seasonal responses of terrestrial net primary production (NPP) to climate changes is to help understand feedback between climate systems and terrestrial ecosystems and mechanisms of increased NPP in the northern middle and high latitudes. In this study, time series dataset of normalized difference vegetation index (NDVI) and corresponding ground-based information on vegetation, climate, soil, and solar radiation, together with an ecological process model, were used to explore the seasonal trends of terrestrial NPP and their geographical differences in China from 1982 to 1999. As the results,. seasonal total NPP in China showed a significant increase for all four seasons (spring, summer, autumn and winter) during the past 18 years. The spring NPP indicated the largest increase rate, while the summer NPP was with the largest increase in magnitude. The response of NPP to climate changes varied with different vegetation types. The increased NPP was primarily led by an advanced growing season for broadleaf evergreen forest, needle-leaf evergreen forest, and needle-leaf deciduous forest, whilst that was mainly due to enhanced vegetation activity (amplitude of growth cycle) during growing season for broadleaf deciduous forest, broadleaf and needle-leaf mixed forest, broadleaf trees with groundcover, perennial grasslands, broadleaf shrubs with grasslands, tundra, desert, and cultivation. The regions with the largest increase in spring NPP appeared mainly in eastern China, while the areas with the largest increase in summer NPP occurred in most parts of Northwestern China, Qinghai-Xizang Plateau, Mts. Xiaoxinganling-Changbaishan, Sanjiang Plain, Songliao Plain, Sichuan Basin, Leizhou Peninsula, part of the middle and lower Yangtze River, and southeastern mountainous areas of China. In autumn, the largest NPP increase appeared in Yunnan Plateau-Eastern Xizang and the areas around Hulun Lake. Such different ways of the NPP responses depended on regional climate attributes and their changes.
