Compared with monometallic metal-organic frameworks(MOFs)that are synthesized by reacting inorganic metal ions or clusters with bidentate or multidentate ligands via hydrothermal or solvothermal methods,the constructi...Compared with monometallic metal-organic frameworks(MOFs)that are synthesized by reacting inorganic metal ions or clusters with bidentate or multidentate ligands via hydrothermal or solvothermal methods,the construction of heterogeneous frameworks like at least two kinds of metal sites in the individual nodes is proved to be an effective way to modulate their properties for advanced catalysis,especially for selective catalysis and multifunctional catalysis.However,it is still very challenging to precisely characterize their microstructures and reveal the relationship among the composition,structure,and their performances.Therefore,it is necessary to summarize the recent progress on bimetallic MOFs for thermal catalysis.First,we summarize the synthesis strategies and characterization methods of bimetallic MOFs and their derivatives.Second,the application of bimetallic MOFs and their derivatives as catalysts in thermal catalysis is discussed,and the relationship among the active components,structures,and their properties is elucidated.Third,the potential challenges and prospects of bimetallic MOF based nanocatalysts are proposed.This review will bring some insights into the design and preparation of bimetallic MOFs based nanocatalysts in the future.展开更多
This paper reviewed the recent research progress of organic reactions catalyzed by four typical earthabundant and 3d metal catalysts:Mn,Fe,Co,and Ni complexes and mainly focused on the reactions in which these 3d meta...This paper reviewed the recent research progress of organic reactions catalyzed by four typical earthabundant and 3d metal catalysts:Mn,Fe,Co,and Ni complexes and mainly focused on the reactions in which these 3d metal catalysts exhibited obvious advantages over other catalysts.The mechanism that makes these 3d metal catalysts show unusual properties is another focus of this paper.An outlook on 3d metal complexes-catalyzed organic reactions was also considered.展开更多
基金support from the National Key Research and Development Program of China(No.2021YFA1500403)Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB36000000)+1 种基金the National Natural Science Foundation of China(Nos.22173024 and 21722102)Youth Innovation Promotion Association CAS(G.D.L.).
文摘Compared with monometallic metal-organic frameworks(MOFs)that are synthesized by reacting inorganic metal ions or clusters with bidentate or multidentate ligands via hydrothermal or solvothermal methods,the construction of heterogeneous frameworks like at least two kinds of metal sites in the individual nodes is proved to be an effective way to modulate their properties for advanced catalysis,especially for selective catalysis and multifunctional catalysis.However,it is still very challenging to precisely characterize their microstructures and reveal the relationship among the composition,structure,and their performances.Therefore,it is necessary to summarize the recent progress on bimetallic MOFs for thermal catalysis.First,we summarize the synthesis strategies and characterization methods of bimetallic MOFs and their derivatives.Second,the application of bimetallic MOFs and their derivatives as catalysts in thermal catalysis is discussed,and the relationship among the active components,structures,and their properties is elucidated.Third,the potential challenges and prospects of bimetallic MOF based nanocatalysts are proposed.This review will bring some insights into the design and preparation of bimetallic MOFs based nanocatalysts in the future.
基金the National Key R&D Program of China(grant no.2021YFA1500200)the National Natural Science Foundation of China(grant nos.92256301,22221002,22025109,21831008,22101286,and 22271249)the Fundamental Research Funds for the Central Universities(grant nos.226-2022-00224 and 226-2023-00115)for financial support.
文摘This paper reviewed the recent research progress of organic reactions catalyzed by four typical earthabundant and 3d metal catalysts:Mn,Fe,Co,and Ni complexes and mainly focused on the reactions in which these 3d metal catalysts exhibited obvious advantages over other catalysts.The mechanism that makes these 3d metal catalysts show unusual properties is another focus of this paper.An outlook on 3d metal complexes-catalyzed organic reactions was also considered.
