Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experim...Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.展开更多
Clinopyroxene-enriched upper mantle xenoliths classified as wehrlites are common(~20% of all xenoliths) in the central part of the Nograd-G(o| ")m(o|")r Volcanic Field(NGVF),situated in the northern margin o...Clinopyroxene-enriched upper mantle xenoliths classified as wehrlites are common(~20% of all xenoliths) in the central part of the Nograd-G(o| ")m(o|")r Volcanic Field(NGVF),situated in the northern margin of the Pannonian Basin in northern Hungary and southern Slovakia.In this study,we thoroughly investigated 12 wehrlite xenoliths,two from each wehrlite-bearing occurrence,to determine the conditions of their formation.Specific textural features,including clinopyroxene-rich patches in an olivine-rich lithology,orthopyroxene remnants in the cores of newlyformed clinopyroxenes and vermicular spinel forms all suggest that wehrlites were formed as a result of intensive interaction between a metasomatic agent and the peridotite wall rock.Based on the major and trace element geochemistry of the rock-forming minerals,significant enrichment in basaltic(Fe,Mn,Ti) and high field strength elements(Nb,Ta,Hf,Zr) was observed,compared to compositions of common lherzolite xenoliths.The presence of orthopyroxene remnants and geochemical trends in rock-forming minerals suggest that the metasomatic process ceased before complete wehrlitization was achieved.The composition of the metasomatic agent is interpreted to be a mafic silicate melt,which was further confirmed by numerical modelling of trace elements using the plate model.The model results also show that the melt/rock ratio played a key role in the degree of petrographic and geochemical transformation.The lack of equilibrium and the conclusions drawn by using variable lherzolitic precursors in the model both suggest that wehrlitization was the last event that occurred shortly before xenolith entrainment in the host mafic melt.We suggest that the wehrlitization and the Plio-Pleistocene basaltic volcanism are related to the same magmatic event.展开更多
The Dalnyaya kimberlite pipe（Yakutia,Russia） contains mantle peridotite xenoliths（mostly Iherzolites and harzburgites） that show both sheared porphyroclastic（deformed） and coarse granular textures,together with ...The Dalnyaya kimberlite pipe（Yakutia,Russia） contains mantle peridotite xenoliths（mostly Iherzolites and harzburgites） that show both sheared porphyroclastic（deformed） and coarse granular textures,together with ilmenite and clinopyroxene megacrysts.Deformed peridotites contain high-temperature Fe-rich clinopyroxenes,sometimes associated with picroilmenites,which are products of interaction of the lithospheric mantle with protokimberlite related melts.The orthopyroxene-derived geotherm for the lithospheric mantle beneath Dalnyaya is stepped similar to that beneath the Udachnaya pipe.Coarse granular xenoliths fall on a geotherm of 35 mWm-2 whereas deformed varieties yield a 45 mWm-2）geotherm in the 2-7.5 GPa pressure interval.The chemistry of the constituent minerals including garnet,olivine and clinopyroxene shows trends of increasing Fe~#（=Fe/（Fe＋Mg））with decreasing pressure.This may suggest that the interaction with fractionating protokimberlite melts occurred at different levels.Two major mantle lithologies are distinguished by the trace element patterns of their constituent minerals,determined by LA-ICP-MS.Orthopyroxenes,some clinopyroxenes and rare garnets are depleted in Ba,Sr,HFSE and MREE and represent relic lithospheric mantle.Re-fertilized garnet and clinopyroxene are more enriched.The distribution of trace elements between garnet and clinopyroxene shows that the garnets dissolved primary orthopyroxene and clinopyroxene.Later high temperature clinopyroxenes related to the protokimberlite melts partially dissolved these garnets.Olivines show decreases in Ni and increases in Al,Ca and Ti from Mg-rich varieties to the more Fe-rich,deformed and refertilized ones.Minerals showing higher Fe~#（0.11-0.15） are found within intergrowths of low-Cr ilmenite-clinopyroxene-garnet related to the crystallization of protokimberlite melts in feeder channels.In P-f（O_2） diagrams,garnets and Cr-rich clinopyroxenes indicate reduced conditions at the base of the lithosphere at-5 log units below展开更多
文摘针对穿管铜导线过电流故障熔化痕迹难以识别的问题,利用电气故障模拟及痕迹制备实验装置,实验模拟了4~7倍额定电流I e下穿管铜导线过电流故障,划分了过电流故障传热特征阶段,分析了电流对碳烟析出、熔断时间、熔痕体积和熔痕数量的影响,探究了过电流故障熔痕金相组织特征。研究发现:“累积期”电流增大碳烟析出增加,熔断时间减小。穿管铜导线发生熔断电流至少5.5 I e,在5.5~7I e时产生了电弧熔痕、迸溅熔珠及结痂痕;随着电流增大,电弧熔痕和迸溅熔珠的体积逐渐增大,结痂痕的体积逐渐减小;迸溅熔珠和结痂痕数量逐渐增加。电弧熔痕的金相组织为树枝晶和胞状晶,迸溅熔珠和结痂痕金相组织只有胞状晶,熔痕与本体之间无明显过渡区,熔痕内部存在孔洞。实验结果表明穿管铜导线过电流故障与未穿管铜导线过电流故障痕迹特征存在差别。研究结论为火灾事故调查中识别与鉴定穿管铜导线过电流故障痕迹提供参考依据。
基金Natural Science Foundations of China(Grant Nos.41502057 and 41472065)Foundations of Suzhou University(Nos.2019ZD46,2015jb01 and 2015jb07).
文摘Interactions between basaltic melt and orthopyroxenite(Opx)were investigated to gain a better understanding of the consequences of the residence and transport of ocean island basalts(OIBs)within the mantle.The experiments were conducted using a DS-3600 six-anvil apparatus at 3.0–4.5 GPa and 1300–1450℃.The basaltic melt and Opx coexisted at local equilibrium at these pressures and temperatures;the initial melts dissolved Opx,which modified their chemical composition,and clinopyroxene(Cpx)precipitated with or without garnet(Grt).The trace-element contents of Grt,Cpx,and melt were measured and the mineral–melt distribution coefficients(D)of Cpx–melt and Grt–melt were calculated,which can be used to assess the distribution of trace elements between basalt and minerals in the mantle.Two types of reaction rim were found in the experimental products,Cpx,and Cpx+Grt;this result indicates that residual rocks within the mantle should be pyroxenite or garnet pyroxenite.Both rock types are found in mantle xenoliths from Hawaii,and the rare-earth-element(REE)pattern of Cpx in these mantle pyroxenites matches those of Cpx in the experimental reaction rims.Furthermore,residual melts in the experimental products plot in similar positions to Hawaiian high-SiO_(2)OIBs on major-element Harker diagrams,and their trace-element patterns show the signature of residual Grt,particularly in runs at1350℃ and 4.0–4.5 GPa.Trace-element concentrations of the experimental residual melts plot in similar positions to the Hawaiian OIBs on commonly used discrimination diagrams(Ti vs.Zr,Cr vs.Y,Cr vs.V,Zr/Y vs.Zr,and Ti/Y vs.Nb/Y).These results indicate that reaction between basaltic melt and pyroxenite might contribute to the generation of Hawaiian high-SiO2 OIBs and account for their chemical variability.
基金This research was financially facilitated by Orlando Vasellisupported by the Bolyai Postdoctoral Fellowship Program,a Marie Curie International Reintegration Grant(Grant No.NAMS-230937)+3 种基金a postdoctoral grant(Grant No.PD101683)of the Hungarian Scientific Research Found(OTKA)to I.J.K.as well as a grant of the Hungarian Scientific Research Found(Grant No.78425)to Cs.supported by a grant from the U.S.National Science Foundation(EAR1624589)to R.J.supported by the GINOP-2.3.2-152016-00009 research program。
文摘Clinopyroxene-enriched upper mantle xenoliths classified as wehrlites are common(~20% of all xenoliths) in the central part of the Nograd-G(o| ")m(o|")r Volcanic Field(NGVF),situated in the northern margin of the Pannonian Basin in northern Hungary and southern Slovakia.In this study,we thoroughly investigated 12 wehrlite xenoliths,two from each wehrlite-bearing occurrence,to determine the conditions of their formation.Specific textural features,including clinopyroxene-rich patches in an olivine-rich lithology,orthopyroxene remnants in the cores of newlyformed clinopyroxenes and vermicular spinel forms all suggest that wehrlites were formed as a result of intensive interaction between a metasomatic agent and the peridotite wall rock.Based on the major and trace element geochemistry of the rock-forming minerals,significant enrichment in basaltic(Fe,Mn,Ti) and high field strength elements(Nb,Ta,Hf,Zr) was observed,compared to compositions of common lherzolite xenoliths.The presence of orthopyroxene remnants and geochemical trends in rock-forming minerals suggest that the metasomatic process ceased before complete wehrlitization was achieved.The composition of the metasomatic agent is interpreted to be a mafic silicate melt,which was further confirmed by numerical modelling of trace elements using the plate model.The model results also show that the melt/rock ratio played a key role in the degree of petrographic and geochemical transformation.The lack of equilibrium and the conclusions drawn by using variable lherzolitic precursors in the model both suggest that wehrlitization was the last event that occurred shortly before xenolith entrainment in the host mafic melt.We suggest that the wehrlitization and the Plio-Pleistocene basaltic volcanism are related to the same magmatic event.
基金supported by RBRF grants:05-05-64718,11-0500060,11-05-91060-PICS,16-05-00860the projects 77-2,65-03,02-05 UIGGM SD RAS and ALROSA Stock Company
文摘The Dalnyaya kimberlite pipe（Yakutia,Russia） contains mantle peridotite xenoliths（mostly Iherzolites and harzburgites） that show both sheared porphyroclastic（deformed） and coarse granular textures,together with ilmenite and clinopyroxene megacrysts.Deformed peridotites contain high-temperature Fe-rich clinopyroxenes,sometimes associated with picroilmenites,which are products of interaction of the lithospheric mantle with protokimberlite related melts.The orthopyroxene-derived geotherm for the lithospheric mantle beneath Dalnyaya is stepped similar to that beneath the Udachnaya pipe.Coarse granular xenoliths fall on a geotherm of 35 mWm-2 whereas deformed varieties yield a 45 mWm-2）geotherm in the 2-7.5 GPa pressure interval.The chemistry of the constituent minerals including garnet,olivine and clinopyroxene shows trends of increasing Fe~#（=Fe/（Fe＋Mg））with decreasing pressure.This may suggest that the interaction with fractionating protokimberlite melts occurred at different levels.Two major mantle lithologies are distinguished by the trace element patterns of their constituent minerals,determined by LA-ICP-MS.Orthopyroxenes,some clinopyroxenes and rare garnets are depleted in Ba,Sr,HFSE and MREE and represent relic lithospheric mantle.Re-fertilized garnet and clinopyroxene are more enriched.The distribution of trace elements between garnet and clinopyroxene shows that the garnets dissolved primary orthopyroxene and clinopyroxene.Later high temperature clinopyroxenes related to the protokimberlite melts partially dissolved these garnets.Olivines show decreases in Ni and increases in Al,Ca and Ti from Mg-rich varieties to the more Fe-rich,deformed and refertilized ones.Minerals showing higher Fe~#（0.11-0.15） are found within intergrowths of low-Cr ilmenite-clinopyroxene-garnet related to the crystallization of protokimberlite melts in feeder channels.In P-f（O_2） diagrams,garnets and Cr-rich clinopyroxenes indicate reduced conditions at the base of the lithosphere at-5 log units below
