The varied altitudinal gradient of climate and vegetation is further complicated by mass elevation effect(MEE), especially in high and extensive mountain regions. However, this effect and its implications for mountain...The varied altitudinal gradient of climate and vegetation is further complicated by mass elevation effect(MEE), especially in high and extensive mountain regions. However, this effect and its implications for mountain altitudinal belts have not been well studied until recently. This paper provides an overview of the research carried out in the past 5 years. MEE is virtually the heating effect of mountain massifs and can be defined as the temperature difference on a given elevation between inside and outside of a mountain mass. It can be digitally modelled with three factors of intra-mountain base elevation(MBE), latitude and hygrometric continentality; MBE usually acts as the primary factor for the magnitude of MEE and, to a great extent, could represent MEE. MEE leads to higher treelines in the interior than in the outside of mountain masses. It makes montane forests to grow at 4800–4900 m and snowlines to develop at about 6000 m in the southern Tibetan Plateau and the central Andes, and large areas of forests to live above 3500 m in a lot of high mountains of the world. The altitudinal distribution of global treelines can be modelled with high precision when taking into account MEE and the result shows that MEE contributes the most to treeline distribution pattern. Without MEE, forests could only develop upmost to about 3500 m above sea level and the world ecological pattern would be much simpler. The quantification of MEE should be further improved with higher resolution data and its global implications are to be further revealed.展开更多
Vertical mass isolation(VMI)is one of the novel methods for the seismic control of structures.In this method,the entire structure is assumed to consist of two mass and stiffness subsystems,and an isolated layer is loc...Vertical mass isolation(VMI)is one of the novel methods for the seismic control of structures.In this method,the entire structure is assumed to consist of two mass and stiffness subsystems,and an isolated layer is located among them.In this study,the magnetorheological damper in three modes:passive-off,passive-on,and semi-active mode with variable voltage between zero and 9 volts was used as an isolated layer between two subsystems.Multi-degrees-of-freedom structures with 5,10,and 15 floors in two dimensions were examined under 11 pairs of near field earthquakes.On each level,the displacement of MR dampers was taken into account.The responses of maximum displacement,maximum inter-story drift,and maximum base shear in controlled and uncontrolled buildings were compared to assess the suggested approach for seismic control of the structures.According to the results,the semi-active control method can reduce the response by more than 12%compared to the uncontrolled mode in terms of maximum displacement of the mass subsystem of the structures.This method can reduce more than 16%and 20%of the responses compared to the uncontrolled mode in terms of maximum inter-story drift and base shear of the structure,respectively.展开更多
Mass elevation effect (MEE) refers to the thermal effect of huge mountains or plateaus, which causes the tendency for tem- perature-related montane landscape limits to occur at higher elevations in the inner massifs...Mass elevation effect (MEE) refers to the thermal effect of huge mountains or plateaus, which causes the tendency for tem- perature-related montane landscape limits to occur at higher elevations in the inner massifs than on their outer margins. MEE has been widely identified in all large mountains, but how it could be measured and what its main forming-factors are still remain open. This paper, supposing that the local mountain base elevation (MBE) is the main factor of MEE, takes the Qinghai-Tibet Plateau (QTP) as the study area, defines MEE as the temperature difference (AT) between the inner and outer parts of mountain massifs, identifies the main forming factors, and analyzes their contributions to MEE. A total of 73 mountain bases were identified, ranging from 708 m to 5081 m and increasing from the edges to the central parts of the plateau. Climate data (1981-2010) from 134 meteorological stations were used to acquire ATby comparing near-surface air temperature on the main plateau with the free-air temperature at the same altitude and simi- lar latitude outside of the plateau. The AT for the warmest month is averagely 6.15 ~C, over 12~C at Lhatse and Baxoi. A multivariate linear regression model was developed to simulate MEE based on three variables (latitude, annual mean precipitation and MBE), which are all significantly correlated to AT. The model could explain 67.3% of MEE variation, and the contribution rates of three independent variables to MEE are 35.29%, 22.69% and 42.02%, respectively. This confirms that MBE is the main factor of MEE. The intensive MEE of the QTP pushes the 10~C isotherm of the warmest month mean temperature 1300-2000 m higher in the main plateau than in the outer regions, leading the occurrence of the highest timberline (4900 m) and the highest snowline (6200 m) of the Northern Hemisphere in the southeast and southwest of the plateau, respectively.展开更多
The vanadium(V) peroxo complexes containing Mannich base ligands having composition Na[VO(O2)2(L-L)]·H2O [where L-L=morpholinobenzyl acetamide (MBA), piperidinobenzyl acetamide (PBA), morpholinobenzyl b...The vanadium(V) peroxo complexes containing Mannich base ligands having composition Na[VO(O2)2(L-L)]·H2O [where L-L=morpholinobenzyl acetamide (MBA), piperidinobenzyl acetamide (PBA), morpholinobenzyl benzamide (MBB), piperidinobenzyl benzamide (PBB), morpholinomethyl benzamide (MMB), piperidinomethyl benzamide (PMB), morpholinobenzyl formamide (MBF), piperdinobenzyl formamide (PBF)] have been reported. The complexes have been prepared by stirring vanadium pentoxide with excess of 30% aque- ous-H202 followed by treatment with ethanolic solution of the ligand and finally maintained the pH of the reaction mixture by adding dilute solution of sodium hydroxide. The synthesized complexes have been characterized by various physico-chemical techniques, via elemental analysis, molar conductivity, magnetic susceptibility measure- ments, infra red, electronic, mass, ~H NMR spectral and TGA/DTA studies. These studies revealed that the synthesized complexes are uni-univalent electrolytes and diamagnetic in nature. The ligands are bound to metal in a bi- dentate mode through carbonyl oxygen and the ring nitrogen. Thermal analysis result provides conclusive evidence for the presence of one molecule of lattice water in the complexes. Mass spectra confirm the molecular mass of the complexes.展开更多
基金National Natural Science Foundation of China,No.41421001,No.41571099,No.41030528
文摘The varied altitudinal gradient of climate and vegetation is further complicated by mass elevation effect(MEE), especially in high and extensive mountain regions. However, this effect and its implications for mountain altitudinal belts have not been well studied until recently. This paper provides an overview of the research carried out in the past 5 years. MEE is virtually the heating effect of mountain massifs and can be defined as the temperature difference on a given elevation between inside and outside of a mountain mass. It can be digitally modelled with three factors of intra-mountain base elevation(MBE), latitude and hygrometric continentality; MBE usually acts as the primary factor for the magnitude of MEE and, to a great extent, could represent MEE. MEE leads to higher treelines in the interior than in the outside of mountain masses. It makes montane forests to grow at 4800–4900 m and snowlines to develop at about 6000 m in the southern Tibetan Plateau and the central Andes, and large areas of forests to live above 3500 m in a lot of high mountains of the world. The altitudinal distribution of global treelines can be modelled with high precision when taking into account MEE and the result shows that MEE contributes the most to treeline distribution pattern. Without MEE, forests could only develop upmost to about 3500 m above sea level and the world ecological pattern would be much simpler. The quantification of MEE should be further improved with higher resolution data and its global implications are to be further revealed.
文摘Vertical mass isolation(VMI)is one of the novel methods for the seismic control of structures.In this method,the entire structure is assumed to consist of two mass and stiffness subsystems,and an isolated layer is located among them.In this study,the magnetorheological damper in three modes:passive-off,passive-on,and semi-active mode with variable voltage between zero and 9 volts was used as an isolated layer between two subsystems.Multi-degrees-of-freedom structures with 5,10,and 15 floors in two dimensions were examined under 11 pairs of near field earthquakes.On each level,the displacement of MR dampers was taken into account.The responses of maximum displacement,maximum inter-story drift,and maximum base shear in controlled and uncontrolled buildings were compared to assess the suggested approach for seismic control of the structures.According to the results,the semi-active control method can reduce the response by more than 12%compared to the uncontrolled mode in terms of maximum displacement of the mass subsystem of the structures.This method can reduce more than 16%and 20%of the responses compared to the uncontrolled mode in terms of maximum inter-story drift and base shear of the structure,respectively.
基金National Natural Science Foundation of China(No.41571099,41030528)
文摘Mass elevation effect (MEE) refers to the thermal effect of huge mountains or plateaus, which causes the tendency for tem- perature-related montane landscape limits to occur at higher elevations in the inner massifs than on their outer margins. MEE has been widely identified in all large mountains, but how it could be measured and what its main forming-factors are still remain open. This paper, supposing that the local mountain base elevation (MBE) is the main factor of MEE, takes the Qinghai-Tibet Plateau (QTP) as the study area, defines MEE as the temperature difference (AT) between the inner and outer parts of mountain massifs, identifies the main forming factors, and analyzes their contributions to MEE. A total of 73 mountain bases were identified, ranging from 708 m to 5081 m and increasing from the edges to the central parts of the plateau. Climate data (1981-2010) from 134 meteorological stations were used to acquire ATby comparing near-surface air temperature on the main plateau with the free-air temperature at the same altitude and simi- lar latitude outside of the plateau. The AT for the warmest month is averagely 6.15 ~C, over 12~C at Lhatse and Baxoi. A multivariate linear regression model was developed to simulate MEE based on three variables (latitude, annual mean precipitation and MBE), which are all significantly correlated to AT. The model could explain 67.3% of MEE variation, and the contribution rates of three independent variables to MEE are 35.29%, 22.69% and 42.02%, respectively. This confirms that MBE is the main factor of MEE. The intensive MEE of the QTP pushes the 10~C isotherm of the warmest month mean temperature 1300-2000 m higher in the main plateau than in the outer regions, leading the occurrence of the highest timberline (4900 m) and the highest snowline (6200 m) of the Northern Hemisphere in the southeast and southwest of the plateau, respectively.
文摘The vanadium(V) peroxo complexes containing Mannich base ligands having composition Na[VO(O2)2(L-L)]·H2O [where L-L=morpholinobenzyl acetamide (MBA), piperidinobenzyl acetamide (PBA), morpholinobenzyl benzamide (MBB), piperidinobenzyl benzamide (PBB), morpholinomethyl benzamide (MMB), piperidinomethyl benzamide (PMB), morpholinobenzyl formamide (MBF), piperdinobenzyl formamide (PBF)] have been reported. The complexes have been prepared by stirring vanadium pentoxide with excess of 30% aque- ous-H202 followed by treatment with ethanolic solution of the ligand and finally maintained the pH of the reaction mixture by adding dilute solution of sodium hydroxide. The synthesized complexes have been characterized by various physico-chemical techniques, via elemental analysis, molar conductivity, magnetic susceptibility measure- ments, infra red, electronic, mass, ~H NMR spectral and TGA/DTA studies. These studies revealed that the synthesized complexes are uni-univalent electrolytes and diamagnetic in nature. The ligands are bound to metal in a bi- dentate mode through carbonyl oxygen and the ring nitrogen. Thermal analysis result provides conclusive evidence for the presence of one molecule of lattice water in the complexes. Mass spectra confirm the molecular mass of the complexes.