The coexistence theory of slag structure and it's application to calculation of the oxidizing capabilities of slag melts is described. It is shown that the law of mass action can be widely applied to the calculati...The coexistence theory of slag structure and it's application to calculation of the oxidizing capabilities of slag melts is described. It is shown that the law of mass action can be widely applied to the calculation of oxidizing capabilities of slag melts in combination with the coexistence theory of slag structure.For slag melts containing basic oxides FeO and MnO, their oxidizing capabilities can be expressed by N Fe tO =N FeO +6N Fe 2O 3 , while for slag melts containing basic oxides CaO, MgO, etc., in addition to FeO and MnO, their oxidizing capabilities can be given as N Fe tO =N FeO +6N Fe 2O 3 +8N Fe 3O 4 .展开更多
Based on the phase diagrams, measured activities and the annexationprinciple, calculating models of mass action concentrations for In-Bi-Cu and In-Sb-Cu melts havebeen formulated. Calculated results not only agree wel...Based on the phase diagrams, measured activities and the annexationprinciple, calculating models of mass action concentrations for In-Bi-Cu and In-Sb-Cu melts havebeen formulated. Calculated results not only agree well with practical values, but also obey themass action law, showing that the deduced model can reflect the structural reality of given meltasand that the annexation principles is applicable to these tow ternary metallic melts. So long asthere is one from three binary systems constituting the ternary melts, in which the activities ofone component exhibit positive deviation relative to Raoultian behavior, heterogeous meltsinevitably would form, so heterogeneous calculating model should be used to calculate their massaction concentrations. On the contrary, if all the binary melts are homogeneous and their activitiesexhibit negative deviation with respect to the Raoult's law, then the ternary melts formed fromthem will certainly be homogeneous, hence single phase model should be applied.展开更多
Based on the practical basis of measured activities and phase diagrams aswell as in the light of the mass action law. the model of inseparable cations and anions of moltensalts and mattes, and the annexation principle...Based on the practical basis of measured activities and phase diagrams aswell as in the light of the mass action law. the model of inseparable cations and anions of moltensalts and mattes, and the annexation principle of two kinds of solutions in binary melts, thecalculating model of mass action concentrations of molten salts CaCl_2-MgCl_2-NaCl was formulated.The results of calculation not only agree with experimental values, but also obey the mass actionlaw, testifying that the model formulated can embody the structural characteristics of these ternarysalts, and that the model of inseparable cations and anions as well as the annexation principle oftwo kinds of solutions in binary melts are also applicable to these ternary salts.展开更多
The calculating models of mass action concentrations for electrolyte aqueous solutions NaBr-H2O, LiNO3-H2O, HNO3-H2O, and KF-H2O have been developed at 298.15 K and their molalities ranging from 0.1 mol/kg to saturati...The calculating models of mass action concentrations for electrolyte aqueous solutions NaBr-H2O, LiNO3-H2O, HNO3-H2O, and KF-H2O have been developed at 298.15 K and their molalities ranging from 0.1 mol/kg to saturation according to the ion and molecule coexistence theory as well as mass action law. The calculated mass action concentration is based on pure species as the standard state and the mole fraction as the concentration unit, and the reported activities are usually based on infinite dilution as the standard state and molality as the concentration unit. Hence, the calculated mass action concentration must be transformed to the same standard state and concentration unit. The transformation coefficients between calculated mass action concentrations and reported activities of the same component fluctuate in a very narrow range. Thus, the transformed mass action concentrations not only agree well with reported activities, but also strictly obey mass action law. The calculated results show that the new developed models can embody the intrinsic structure of investigated four electrolyte aqueous solutions. The results also indicate that mass action law has its widespread applicability to electrolyte binary aqueous solutions.展开更多
According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2O_3-SiO_2,CaO-MgO-MnO-FeO-Fe_2O_3-P_2O_5-SiO_2 and CaO-MgO-MnO-FeO-...According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2O_3-SiO_2,CaO-MgO-MnO-FeO-Fe_2O_3-P_2O_5-SiO_2 and CaO-MgO-MnO-FeO-Fe_2O_3-Al_2O_3-P_2O_5-SiO_2 slag melts areformulated and sulphur distribution between the slag melts and liquid iron is treated. It is foundthat CaO, MnO and FeO promote desulphurization, while MgO is detrimental to desulphurization. Inaddition, the sulphur distribution coefficients between the slag melts and liquid iron andpresented.展开更多
Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent researc...Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent research work, Showing that the model formulatedcan reflect the structural characteristics of these melts. In thismodel, without the help Of any empirical parameters, only threeequilibrium constants are used, hence it is simple, lear, andfavorable to the sim- Plification of calculation.展开更多
A universal thermodynamic model of calculating the mass action concentrations of components in a ternary strong electrolyte aqueous solution has been developed based on the ion and molecule coexistence theory,and veri...A universal thermodynamic model of calculating the mass action concentrations of components in a ternary strong electrolyte aqueous solution has been developed based on the ion and molecule coexistence theory,and verified in the NaCl-KCl-H2O ternary system at 298.15 K. To compare the difference of the thermodynamic model in binary and ternary strong electrolyte aqueous solutions,the mass action concentrations of components in the NaCl-H2O binary strong electrolyte aqueous solution were also computed at 298.15K. A transformation coefficient was required to compare the calculated mass action concentration and reported activity because they were obtained at different standard states and concentration units. The results show that the transformation coefficients between calculated mass action concentrations and reported activities of the same components change in a very narrow range. The calculated mass action concentrations of components in the NaCl-H2O and NaCl-KCl-H2O systems are in good agreement with the reported activities. This indicates that the developed thermodynamic model can reflect the structural characteristics of solutions,and the mass action concentration also strictly follows the mass action law.展开更多
Mass action concentration （activity） calculation model was used to analyze the variation rule of mass action concentrations of slag compositions with basicity changing, and the effect of basicity on deoxidation capa...Mass action concentration （activity） calculation model was used to analyze the variation rule of mass action concentrations of slag compositions with basicity changing, and the effect of basicity on deoxidation capability and control of spinel and globular inclusions was investigated theoretically. From the calculation and experimental results, it was found that with the increase of basicity, the mass action concentration of Al2O3 and SiO2 decreases, while the mass action concentration of FeO and MgO increases at first and then decreases.Slag basicity below 3 to 4 would help to control spinel inclusions formation, and higher basicity improves formation of globular inclusions. Slag with basicity under 2 can effectively control the formation of globular inclusions. Deoxidation capability of slag increases with the increase of basicity, and slag with basicity about 4 could almost reach the maximum deoxidation capability. In order to smelt low oxygen steel with globular inclusions controlled, refining slag basicity should be controlled at about 4.展开更多
According to the law of mass action and the coexistence theory of slag structure, the distribution of manganese between MnO FeO SiO 2 and MgO MnO FeO SiO 2 slag melts as well as liquid iron was analyzed. It is shown t...According to the law of mass action and the coexistence theory of slag structure, the distribution of manganese between MnO FeO SiO 2 and MgO MnO FeO SiO 2 slag melts as well as liquid iron was analyzed. It is shown that K ′ Mn and K MnO are only dependent on temperature and don’t change with basicities and compositions of slag melts. So the distribution of manganese between the above mentioned slag melts and molten iron obeys the law of mass action. But analysis of experimental results from other sources shows that K ′ Mn and K MnO really change with basicities of slag, which is probably arisen from not approaching equilibrium under low basicity slag melts.展开更多
Based on the calculating model of metallic melts involving eutectic, the calculating equations of mixing thermodynamic parameters for two phase metallic melts have been formulated in the light of those equations of ho...Based on the calculating model of metallic melts involving eutectic, the calculating equations of mixing thermodynamic parameters for two phase metallic melts have been formulated in the light of those equations of homogeneous solutions. Irrespective as to whether the activity deviation relative to Raoultian behavior is positive or negative, or the deviation is symmetrical or unsym-metrical, the evaluated results not only agree well with experimental values, but also strictly obey the mass action law. This testifies that these equations can authentically reflect the structural reality and mixing thermodynamic characteristics of two-phase metallic melts. The calculating equations of mixing thermodynamic parameters for the model of two phase metallic melts offer two practical criteria (activity and mixing thermodynamic parameters) and one theoretical criterion (the mass action law).展开更多
文摘The coexistence theory of slag structure and it's application to calculation of the oxidizing capabilities of slag melts is described. It is shown that the law of mass action can be widely applied to the calculation of oxidizing capabilities of slag melts in combination with the coexistence theory of slag structure.For slag melts containing basic oxides FeO and MnO, their oxidizing capabilities can be expressed by N Fe tO =N FeO +6N Fe 2O 3 , while for slag melts containing basic oxides CaO, MgO, etc., in addition to FeO and MnO, their oxidizing capabilities can be given as N Fe tO =N FeO +6N Fe 2O 3 +8N Fe 3O 4 .
文摘Based on the phase diagrams, measured activities and the annexationprinciple, calculating models of mass action concentrations for In-Bi-Cu and In-Sb-Cu melts havebeen formulated. Calculated results not only agree well with practical values, but also obey themass action law, showing that the deduced model can reflect the structural reality of given meltasand that the annexation principles is applicable to these tow ternary metallic melts. So long asthere is one from three binary systems constituting the ternary melts, in which the activities ofone component exhibit positive deviation relative to Raoultian behavior, heterogeous meltsinevitably would form, so heterogeneous calculating model should be used to calculate their massaction concentrations. On the contrary, if all the binary melts are homogeneous and their activitiesexhibit negative deviation with respect to the Raoult's law, then the ternary melts formed fromthem will certainly be homogeneous, hence single phase model should be applied.
文摘Based on the practical basis of measured activities and phase diagrams aswell as in the light of the mass action law. the model of inseparable cations and anions of moltensalts and mattes, and the annexation principle of two kinds of solutions in binary melts, thecalculating model of mass action concentrations of molten salts CaCl_2-MgCl_2-NaCl was formulated.The results of calculation not only agree with experimental values, but also obey the mass actionlaw, testifying that the model formulated can embody the structural characteristics of these ternarysalts, and that the model of inseparable cations and anions as well as the annexation principle oftwo kinds of solutions in binary melts are also applicable to these ternary salts.
文摘The calculating models of mass action concentrations for electrolyte aqueous solutions NaBr-H2O, LiNO3-H2O, HNO3-H2O, and KF-H2O have been developed at 298.15 K and their molalities ranging from 0.1 mol/kg to saturation according to the ion and molecule coexistence theory as well as mass action law. The calculated mass action concentration is based on pure species as the standard state and the mole fraction as the concentration unit, and the reported activities are usually based on infinite dilution as the standard state and molality as the concentration unit. Hence, the calculated mass action concentration must be transformed to the same standard state and concentration unit. The transformation coefficients between calculated mass action concentrations and reported activities of the same component fluctuate in a very narrow range. Thus, the transformed mass action concentrations not only agree well with reported activities, but also strictly obey mass action law. The calculated results show that the new developed models can embody the intrinsic structure of investigated four electrolyte aqueous solutions. The results also indicate that mass action law has its widespread applicability to electrolyte binary aqueous solutions.
文摘According to the mass action law and the coexistence theory of slagstructure, the calculating models of mass action concentration for CaO-MgO-FeO-Fe_2O_3-SiO_2,CaO-MgO-MnO-FeO-Fe_2O_3-P_2O_5-SiO_2 and CaO-MgO-MnO-FeO-Fe_2O_3-Al_2O_3-P_2O_5-SiO_2 slag melts areformulated and sulphur distribution between the slag melts and liquid iron is treated. It is foundthat CaO, MnO and FeO promote desulphurization, while MgO is detrimental to desulphurization. Inaddition, the sulphur distribution coefficients between the slag melts and liquid iron andpresented.
文摘Based on phase diagrams and measured activities, the calculatingmodel of mass action concentrations for het- erogeneous meltsAg-Au-Cu was formulated. Calculated results agree with the improvedresults of recent research work, Showing that the model formulatedcan reflect the structural characteristics of these melts. In thismodel, without the help Of any empirical parameters, only threeequilibrium constants are used, hence it is simple, lear, andfavorable to the sim- Plification of calculation.
文摘A universal thermodynamic model of calculating the mass action concentrations of components in a ternary strong electrolyte aqueous solution has been developed based on the ion and molecule coexistence theory,and verified in the NaCl-KCl-H2O ternary system at 298.15 K. To compare the difference of the thermodynamic model in binary and ternary strong electrolyte aqueous solutions,the mass action concentrations of components in the NaCl-H2O binary strong electrolyte aqueous solution were also computed at 298.15K. A transformation coefficient was required to compare the calculated mass action concentration and reported activity because they were obtained at different standard states and concentration units. The results show that the transformation coefficients between calculated mass action concentrations and reported activities of the same components change in a very narrow range. The calculated mass action concentrations of components in the NaCl-H2O and NaCl-KCl-H2O systems are in good agreement with the reported activities. This indicates that the developed thermodynamic model can reflect the structural characteristics of solutions,and the mass action concentration also strictly follows the mass action law.
基金Item Sponsored by National Natural Science Foundation of China(51134009)Fundamental Research Funds for Central Universities of China(N100102001)
文摘Mass action concentration （activity） calculation model was used to analyze the variation rule of mass action concentrations of slag compositions with basicity changing, and the effect of basicity on deoxidation capability and control of spinel and globular inclusions was investigated theoretically. From the calculation and experimental results, it was found that with the increase of basicity, the mass action concentration of Al2O3 and SiO2 decreases, while the mass action concentration of FeO and MgO increases at first and then decreases.Slag basicity below 3 to 4 would help to control spinel inclusions formation, and higher basicity improves formation of globular inclusions. Slag with basicity under 2 can effectively control the formation of globular inclusions. Deoxidation capability of slag increases with the increase of basicity, and slag with basicity about 4 could almost reach the maximum deoxidation capability. In order to smelt low oxygen steel with globular inclusions controlled, refining slag basicity should be controlled at about 4.
文摘According to the law of mass action and the coexistence theory of slag structure, the distribution of manganese between MnO FeO SiO 2 and MgO MnO FeO SiO 2 slag melts as well as liquid iron was analyzed. It is shown that K ′ Mn and K MnO are only dependent on temperature and don’t change with basicities and compositions of slag melts. So the distribution of manganese between the above mentioned slag melts and molten iron obeys the law of mass action. But analysis of experimental results from other sources shows that K ′ Mn and K MnO really change with basicities of slag, which is probably arisen from not approaching equilibrium under low basicity slag melts.
文摘Based on the calculating model of metallic melts involving eutectic, the calculating equations of mixing thermodynamic parameters for two phase metallic melts have been formulated in the light of those equations of homogeneous solutions. Irrespective as to whether the activity deviation relative to Raoultian behavior is positive or negative, or the deviation is symmetrical or unsym-metrical, the evaluated results not only agree well with experimental values, but also strictly obey the mass action law. This testifies that these equations can authentically reflect the structural reality and mixing thermodynamic characteristics of two-phase metallic melts. The calculating equations of mixing thermodynamic parameters for the model of two phase metallic melts offer two practical criteria (activity and mixing thermodynamic parameters) and one theoretical criterion (the mass action law).
