It is shown by the the law of mass action in combination with the coexistence theory of slag structure that KMn n =NMno /(NFeo [%Mn] does not change with basicities and maintains constant at constant temperature; the...It is shown by the the law of mass action in combination with the coexistence theory of slag structure that KMn n =NMno /(NFeo [%Mn] does not change with basicities and maintains constant at constant temperature; the oxidizing capabilities of multicomponent slag systems containing CaO, MgO etc., can be expressed by NFe tO =NFeO + 6NFe2 O3 + 8NFe3O4; the desulfurizing capabilities of various basic oxides for multicomponent slag systems can be calculated by Ls=8(KCaSNCaO+KMgsNMgo +KFeSNFeO)∑n/[%O]; the dephosphorizing capabili- ties of CaO-MgO-FeO-FeO O3-P2 O5 as well as CaO-FeO-Fe2 O3-A12 O3-P2 O5 molten slags expressed respectively by Lpo=(%P2O5)/[P]2 = 141.94[%O]5∑nK00(1 + K5N2Cao + K6N3CaO + K7N4CaO + K8N2MgO + K9N3MgO + K10N3FeO + K11N4Feo); LPO=(%P2O5)/[P]2= 141.94[%O]5∑nK00(1 + K10N2CaO+ K11N3CaO+ K12N4CaO + K13N3FeO + K14N4FeO) have good agreement with practical values.展开更多
This article reports the morphology, size, and distribution evolution of MnS inclusions in non-quenched and tempered steel during heat treatment. The variation of single large-sized MnS inclusions at high temperature ...This article reports the morphology, size, and distribution evolution of MnS inclusions in non-quenched and tempered steel during heat treatment. The variation of single large-sized MnS inclusions at high temperature was observed in situ using a confocal scanning laser microscope (CSLM). The slender MnS inclusions first changed to pearl-like slrings. These small-sized pearls subsequently coalesced and became closer together as the temperature increased. Large-sized MnS inclusions in non-quenched and tempered steel samples with different thermal histories were investigated with respect to the evolution of their morphology, size, and distribution. After 30 min of ovulation at 1573 K, the percentage of MnS inclusions larger than 3 μm decreased from 50.5% to 3.0%. After a 3 h making period, Ostwald ripening occurred. Most MnS inclusions moved from the grain bounda- ries to the interior. The present study demonstrates that heat treatment is an effective method of changing the morphology, size, and distribution of MnS inclusions, especially large-sized ones.展开更多
Phytolacca acinosa Roxb. (P acinosa) is a recently discovered manganese hyperaccumulator plant from southern China. It is a good candidate for phytoremediation of manganese(Mn) polluted soil for its high biomass a...Phytolacca acinosa Roxb. (P acinosa) is a recently discovered manganese hyperaccumulator plant from southern China. It is a good candidate for phytoremediation of manganese(Mn) polluted soil for its high biomass and fast growth. Knowledge of the tissue localization and identification of heavy metals can provide essential information on metal toxicity and bioaccumulation mechanisms. Synchrotron radiation X-ray fluorescence spectroscopy (SRXRF) microprobe was used in this study to investigate the cellular distributions of Mn and other elements in root, stem, leaf, petiole and midrib of P. acinosa. The highest Mn content was found in the vascular tissues of root, stem, petiole and midrib. Cortex in root played a key role in Mn absorption and Mn was limited in the vascular bundle during the process of transportation in stem. Moreover, Mn content in leaf epidermis was higher than that in mesophyll, which suggested that the sequestration of Mn in leaf epidermis might be one of the detoxification mechanisms of P. acinosa. The significance of other elemental (such as P, S, K, Ca, Fe, Zn and Cu) distribution patterns and the correlation with Mn were also discussed.展开更多
文摘It is shown by the the law of mass action in combination with the coexistence theory of slag structure that KMn n =NMno /(NFeo [%Mn] does not change with basicities and maintains constant at constant temperature; the oxidizing capabilities of multicomponent slag systems containing CaO, MgO etc., can be expressed by NFe tO =NFeO + 6NFe2 O3 + 8NFe3O4; the desulfurizing capabilities of various basic oxides for multicomponent slag systems can be calculated by Ls=8(KCaSNCaO+KMgsNMgo +KFeSNFeO)∑n/[%O]; the dephosphorizing capabili- ties of CaO-MgO-FeO-FeO O3-P2 O5 as well as CaO-FeO-Fe2 O3-A12 O3-P2 O5 molten slags expressed respectively by Lpo=(%P2O5)/[P]2 = 141.94[%O]5∑nK00(1 + K5N2Cao + K6N3CaO + K7N4CaO + K8N2MgO + K9N3MgO + K10N3FeO + K11N4Feo); LPO=(%P2O5)/[P]2= 141.94[%O]5∑nK00(1 + K10N2CaO+ K11N3CaO+ K12N4CaO + K13N3FeO + K14N4FeO) have good agreement with practical values.
文摘This article reports the morphology, size, and distribution evolution of MnS inclusions in non-quenched and tempered steel during heat treatment. The variation of single large-sized MnS inclusions at high temperature was observed in situ using a confocal scanning laser microscope (CSLM). The slender MnS inclusions first changed to pearl-like slrings. These small-sized pearls subsequently coalesced and became closer together as the temperature increased. Large-sized MnS inclusions in non-quenched and tempered steel samples with different thermal histories were investigated with respect to the evolution of their morphology, size, and distribution. After 30 min of ovulation at 1573 K, the percentage of MnS inclusions larger than 3 μm decreased from 50.5% to 3.0%. After a 3 h making period, Ostwald ripening occurred. Most MnS inclusions moved from the grain bounda- ries to the interior. The present study demonstrates that heat treatment is an effective method of changing the morphology, size, and distribution of MnS inclusions, especially large-sized ones.
文摘Phytolacca acinosa Roxb. (P acinosa) is a recently discovered manganese hyperaccumulator plant from southern China. It is a good candidate for phytoremediation of manganese(Mn) polluted soil for its high biomass and fast growth. Knowledge of the tissue localization and identification of heavy metals can provide essential information on metal toxicity and bioaccumulation mechanisms. Synchrotron radiation X-ray fluorescence spectroscopy (SRXRF) microprobe was used in this study to investigate the cellular distributions of Mn and other elements in root, stem, leaf, petiole and midrib of P. acinosa. The highest Mn content was found in the vascular tissues of root, stem, petiole and midrib. Cortex in root played a key role in Mn absorption and Mn was limited in the vascular bundle during the process of transportation in stem. Moreover, Mn content in leaf epidermis was higher than that in mesophyll, which suggested that the sequestration of Mn in leaf epidermis might be one of the detoxification mechanisms of P. acinosa. The significance of other elemental (such as P, S, K, Ca, Fe, Zn and Cu) distribution patterns and the correlation with Mn were also discussed.