Lanthanides(Ln(Ⅲ))based compounds as light-emitting materials have emerged as successful agents in high-performance defense and lighting systems,magnets,bio-markers,and circuitry.Therefore,they have recently gained m...Lanthanides(Ln(Ⅲ))based compounds as light-emitting materials have emerged as successful agents in high-performance defense and lighting systems,magnets,bio-markers,and circuitry.Therefore,they have recently gained much attention as energy-saving and cost-effective luminescent materials and their applications in analyte detection.The present review summarizes powerful features and recent developments of organo-lanthanide complexes in lighting applications with a particular focus on visible light emitters,including Eu(Ⅲ),Tb(Ⅲ),Sm(Ⅲ),and Dy(Ⅲ)ions.In addition,this review discusses the most relevant aspects of photosensitization,such as the structure,property,functionalization of primary and secondary ligands,and molecular geometry.In addition,coordination sites of organo-lanthanide complexes and their applications collectively contribute to the improved performance of innovative luminescent materials.Finally,the current challenges and key recommendations for advancing organolanthanides in material science are provided.展开更多
Hydroxyapatite luminescent nanocrystallines doped with 6 mol.%Tb^(3+)(Tb-HA)were prepared via chemical deposition method and calcined at different temperature,and the effects of calcinations temperature on the lumines...Hydroxyapatite luminescent nanocrystallines doped with 6 mol.%Tb^(3+)(Tb-HA)were prepared via chemical deposition method and calcined at different temperature,and the effects of calcinations temperature on the luminescence intensity and fluorescent lifetime were studied.TEM image of Tb-HA revealed that the shape of nanocrystallines changed from needle-like to short rod-like and sphere-like with the increase of calcinations temperature;while the particles sizes decreased from 190 nm to 110 nm.the crystallinity degree increased.the typical emission peaks attributed to Tb^(3+) ions were observed in emission spectra of 6 mol.%Tb-HA under 378 nm excitation.the luminescent intensity of Tb-HA,which showed the fluorescence quenching,firstly enhanced and then decreased at 700℃;while the fluorescent lifetime increased firstly and then decreased after 600℃.Furthermore,the ratio of intensity between 545 nm and 490 nm corresponding to electric-dipole and magnetic-dipole transition(I_(R):I_(O))increases firstly and then decreases,which revealed that the proportion of substitute type and site of Ca^(2+) ions by Tb^(3+) ions were helpful to realize the substitute process and functional structure design.展开更多
A series of barium-tungstate-based phosphors doped with different concentrations of Dy<sup>3+</sup> were synthesized by solid-state reaction method. Photoluminescence properties and decay lifetime of Dy<...A series of barium-tungstate-based phosphors doped with different concentrations of Dy<sup>3+</sup> were synthesized by solid-state reaction method. Photoluminescence properties and decay lifetime of Dy<sup>3+</sup>-doped BaWO<sub>4</sub> samples were studied. The results indicated that luminescent properties of BaWO<sub>4</sub>:Dy<sup>3+</sup> depended on the Dy<sup>3+</sup> concentration, and the inner energy could transfer from to Dy<sup>3+</sup>. The quality of the light was checked by estimating CIE parameters, and the results showed that BaWO<sub>4</sub>:Dy<sup>3+</sup> was a potential candidate as blue-green luminescent materials in white LED because of its excellent emission spectrum excited by UV light.展开更多
Three kinds of PPV-based copolymers were synthesized and characterized. Their luminescent properties were investigated and discussed by PL spectrum, and time-dependence luminescent spectrum in film and solution state....Three kinds of PPV-based copolymers were synthesized and characterized. Their luminescent properties were investigated and discussed by PL spectrum, and time-dependence luminescent spectrum in film and solution state. The results show that in the range of our study, the PL intensity and lifetime of luminescent decay increase with the increasing length of flexible segments and the solution diluting, indicating the tendency of the increase of luminescent efficiency.展开更多
In this work, the photoluminescence（PL） of NaScP2O7：Eu^2＋ and NaScP2O7：Eu^2＋,Mn^2＋ was investigated. Phase purity was checked using X-ray powder diffractometry（XRD）. PL excitation and emission spectra were re...In this work, the photoluminescence（PL） of NaScP2O7：Eu^2＋ and NaScP2O7：Eu^2＋,Mn^2＋ was investigated. Phase purity was checked using X-ray powder diffractometry（XRD）. PL excitation and emission spectra were recorded to elucidate the PL properties of NaScP2O7：Eu^2＋ and NaScP2O7：Eu^2＋,Mn^2＋. Furthermore, fluorescence lifetime measurements were performed. PL and lifetime measurements were carried out from 10 to 525 K. Moreover, the Eu^2＋ site occupation was discussed. It turned out that the incorporated Eu^2＋ ions substituted for Na＋ site and occupied two different sites. Temperature dependent PL measurements indicated the emission intensity decreased with increasing temperature due to temperature quenching in NaScP2O7：Eu^2＋. Fluorescence lifetimes of Eu^2＋ in NaScP2O7：Eu^2＋ almost did not change with a decay constant τ=~0.53 μs in the temperature range of 10–280 K, and then shortened due to temperature quenching. The luminescent lifetime reached ~0.05 μs at T=525 K. Finally, it was found that energy transfer occurred from Eu^2＋ to Mn^2＋ in co-doped NaScP2O7：Eu^2＋,Mn^2＋.展开更多
Lanthanide-doped polymers are very attractive, since they can be used for luminescent optical fiber fabrications.This Letter presents the terbium-ions-doped poly（methyl methacrylate） fiber fabrication and spectrosco...Lanthanide-doped polymers are very attractive, since they can be used for luminescent optical fiber fabrications.This Letter presents the terbium-ions-doped poly（methyl methacrylate） fiber fabrication and spectroscopic characterization. The measured excited state（5D4） lifetime of 0.741 ms confirms that a used organometallic can be used to obtain an intense luminescence in a polymeric fiber. The luminescence spectrum shape modification versus the fiber length is also investigated.展开更多
基金Project supported by the Human Resource Development Group(HRDG)Council of Scientific&Industrial Research(CSIR),New Delhi,India(09/105(0266)-2018-EMR-1)。
文摘Lanthanides(Ln(Ⅲ))based compounds as light-emitting materials have emerged as successful agents in high-performance defense and lighting systems,magnets,bio-markers,and circuitry.Therefore,they have recently gained much attention as energy-saving and cost-effective luminescent materials and their applications in analyte detection.The present review summarizes powerful features and recent developments of organo-lanthanide complexes in lighting applications with a particular focus on visible light emitters,including Eu(Ⅲ),Tb(Ⅲ),Sm(Ⅲ),and Dy(Ⅲ)ions.In addition,this review discusses the most relevant aspects of photosensitization,such as the structure,property,functionalization of primary and secondary ligands,and molecular geometry.In addition,coordination sites of organo-lanthanide complexes and their applications collectively contribute to the improved performance of innovative luminescent materials.Finally,the current challenges and key recommendations for advancing organolanthanides in material science are provided.
基金The authors gratefully acknowledge the financial support of International S&T Cooperation Program of China(No.2009DFR50520)Natural Science Foundation of China(NO.51472151).
文摘Hydroxyapatite luminescent nanocrystallines doped with 6 mol.%Tb^(3+)(Tb-HA)were prepared via chemical deposition method and calcined at different temperature,and the effects of calcinations temperature on the luminescence intensity and fluorescent lifetime were studied.TEM image of Tb-HA revealed that the shape of nanocrystallines changed from needle-like to short rod-like and sphere-like with the increase of calcinations temperature;while the particles sizes decreased from 190 nm to 110 nm.the crystallinity degree increased.the typical emission peaks attributed to Tb^(3+) ions were observed in emission spectra of 6 mol.%Tb-HA under 378 nm excitation.the luminescent intensity of Tb-HA,which showed the fluorescence quenching,firstly enhanced and then decreased at 700℃;while the fluorescent lifetime increased firstly and then decreased after 600℃.Furthermore,the ratio of intensity between 545 nm and 490 nm corresponding to electric-dipole and magnetic-dipole transition(I_(R):I_(O))increases firstly and then decreases,which revealed that the proportion of substitute type and site of Ca^(2+) ions by Tb^(3+) ions were helpful to realize the substitute process and functional structure design.
文摘A series of barium-tungstate-based phosphors doped with different concentrations of Dy<sup>3+</sup> were synthesized by solid-state reaction method. Photoluminescence properties and decay lifetime of Dy<sup>3+</sup>-doped BaWO<sub>4</sub> samples were studied. The results indicated that luminescent properties of BaWO<sub>4</sub>:Dy<sup>3+</sup> depended on the Dy<sup>3+</sup> concentration, and the inner energy could transfer from to Dy<sup>3+</sup>. The quality of the light was checked by estimating CIE parameters, and the results showed that BaWO<sub>4</sub>:Dy<sup>3+</sup> was a potential candidate as blue-green luminescent materials in white LED because of its excellent emission spectrum excited by UV light.
文摘Three kinds of PPV-based copolymers were synthesized and characterized. Their luminescent properties were investigated and discussed by PL spectrum, and time-dependence luminescent spectrum in film and solution state. The results show that in the range of our study, the PL intensity and lifetime of luminescent decay increase with the increasing length of flexible segments and the solution diluting, indicating the tendency of the increase of luminescent efficiency.
基金Project supported by the Science and Technology Program of Hunan Province(2010FJ3092)
文摘In this work, the photoluminescence（PL） of NaScP2O7：Eu^2＋ and NaScP2O7：Eu^2＋,Mn^2＋ was investigated. Phase purity was checked using X-ray powder diffractometry（XRD）. PL excitation and emission spectra were recorded to elucidate the PL properties of NaScP2O7：Eu^2＋ and NaScP2O7：Eu^2＋,Mn^2＋. Furthermore, fluorescence lifetime measurements were performed. PL and lifetime measurements were carried out from 10 to 525 K. Moreover, the Eu^2＋ site occupation was discussed. It turned out that the incorporated Eu^2＋ ions substituted for Na＋ site and occupied two different sites. Temperature dependent PL measurements indicated the emission intensity decreased with increasing temperature due to temperature quenching in NaScP2O7：Eu^2＋. Fluorescence lifetimes of Eu^2＋ in NaScP2O7：Eu^2＋ almost did not change with a decay constant τ=~0.53 μs in the temperature range of 10–280 K, and then shortened due to temperature quenching. The luminescent lifetime reached ~0.05 μs at T=525 K. Finally, it was found that energy transfer occurred from Eu^2＋ to Mn^2＋ in co-doped NaScP2O7：Eu^2＋,Mn^2＋.
基金supported by the Bialystok University of Technology project No.S/WE/4/2013,Polandunder EU COST Action MP1401 "Advanced fibre laser and coherent source as tools for society,manufacturing and life science."
文摘Lanthanide-doped polymers are very attractive, since they can be used for luminescent optical fiber fabrications.This Letter presents the terbium-ions-doped poly（methyl methacrylate） fiber fabrication and spectroscopic characterization. The measured excited state（5D4） lifetime of 0.741 ms confirms that a used organometallic can be used to obtain an intense luminescence in a polymeric fiber. The luminescence spectrum shape modification versus the fiber length is also investigated.
