A hybrid system containing a pillar[5]arene unit and ten crown ether moieties was developed.The LCST behavior and thermo-responsive ness were successfully introduced into this pillar[5]arene-crown ether system.Both ho...A hybrid system containing a pillar[5]arene unit and ten crown ether moieties was developed.The LCST behavior and thermo-responsive ness were successfully introduced into this pillar[5]arene-crown ether system.Both host-guest interactions and salting-out effect displayed great effects in realizing the supramolecular control over LCST properties and the rmo-re sponsiveness.Compa red with the individual macrocycles,this hybrid macrocycle system dramatically amplified the supramolecular control effect over LCST behavior.展开更多
基金the National Natural Science Foundation of China(No.21704024)the Huxiang Young Talent Program from Hunan Province(No.2018RS3036)+1 种基金the Fundamental Research Funds for the Central Universities from Hunan UniversityNational Natural Science Foundation of Shandong Province(No.ZR2019QB024)。
文摘A hybrid system containing a pillar[5]arene unit and ten crown ether moieties was developed.The LCST behavior and thermo-responsive ness were successfully introduced into this pillar[5]arene-crown ether system.Both host-guest interactions and salting-out effect displayed great effects in realizing the supramolecular control over LCST properties and the rmo-re sponsiveness.Compa red with the individual macrocycles,this hybrid macrocycle system dramatically amplified the supramolecular control effect over LCST behavior.
