A novel all solid-state composite polymer elec-trolyte, PEO-LiClO4-LiZSM5, by using 搒hape-selective?molecular sieves ZSM-5 as filler was obtained by the solvent casting method. The experimental results showed that th...A novel all solid-state composite polymer elec-trolyte, PEO-LiClO4-LiZSM5, by using 搒hape-selective?molecular sieves ZSM-5 as filler was obtained by the solvent casting method. The experimental results showed that the addition of LiZSM5 could enhance the ionic conductivity of the pristine PEO-LiClO4 electrolyte, the ionic conductivity of PEO10-LiClO4-10%LiZSM5 achieved 1.4×10-5 S cm-1 at 25℃. Lithium ion transference number was tested by AC impedance combined with the steady-state current method, the results showed that LiZSM5 could improve the Li+ transference number of the CPE effectively. The broad elec-trochemical stability window ensured the use of PEO-Li- ClO4-LiZSM5 as electrolyte materials for all solid-state re-chargeable lithium ion batteries.展开更多
A novel PEO-based composite polymer electro-lyte by using organic-inorganic hybrid EO20PO70EO20-em- mesoporous silica (P123-em-SBA15) as the filler has been developed. The experiment results show that P123-em- SBA15 c...A novel PEO-based composite polymer electro-lyte by using organic-inorganic hybrid EO20PO70EO20-em- mesoporous silica (P123-em-SBA15) as the filler has been developed. The experiment results show that P123-em- SBA15 can enhance the lithium-ion transference number of the composite polymer electrolyte, which is induced by the special topology structure of P123 in P123-em-SBA15 hybrid. In addition, room temperature ionic conductivity of the composite polymer electrolyte can also be increased by about two orders of magnitude. The excellent lithium transport properties suggest that PEO-LiClO4-P123-em-SBA15 com-posite polymer electrolyte can be used as electrolyte materi-als for all solid-state rechargeable lithium polymer batteries.展开更多
文摘A novel all solid-state composite polymer elec-trolyte, PEO-LiClO4-LiZSM5, by using 搒hape-selective?molecular sieves ZSM-5 as filler was obtained by the solvent casting method. The experimental results showed that the addition of LiZSM5 could enhance the ionic conductivity of the pristine PEO-LiClO4 electrolyte, the ionic conductivity of PEO10-LiClO4-10%LiZSM5 achieved 1.4×10-5 S cm-1 at 25℃. Lithium ion transference number was tested by AC impedance combined with the steady-state current method, the results showed that LiZSM5 could improve the Li+ transference number of the CPE effectively. The broad elec-trochemical stability window ensured the use of PEO-Li- ClO4-LiZSM5 as electrolyte materials for all solid-state re-chargeable lithium ion batteries.
文摘A novel PEO-based composite polymer electro-lyte by using organic-inorganic hybrid EO20PO70EO20-em- mesoporous silica (P123-em-SBA15) as the filler has been developed. The experiment results show that P123-em- SBA15 can enhance the lithium-ion transference number of the composite polymer electrolyte, which is induced by the special topology structure of P123 in P123-em-SBA15 hybrid. In addition, room temperature ionic conductivity of the composite polymer electrolyte can also be increased by about two orders of magnitude. The excellent lithium transport properties suggest that PEO-LiClO4-P123-em-SBA15 com-posite polymer electrolyte can be used as electrolyte materi-als for all solid-state rechargeable lithium polymer batteries.
