Ion optics is a critical component of ion thrusters. A two-dimensional axisymmetric model is developed to study the characteristics of three-grid electron cyclotron resonance ion thruster optics. The code is based on ...Ion optics is a critical component of ion thrusters. A two-dimensional axisymmetric model is developed to study the characteristics of three-grid electron cyclotron resonance ion thruster optics. The code is based on a particle-in-cell combined with the Monte Carlo collision method to simulate ion dynamics and charge-exchange processes in the grid region. The simulation results show that the mode can give a reasonable estimate of the physics characteristics of the ion optics. The design of the ion optics satisfies the requirement of preventing electron backstreaming. Charge-exchange ions can cause damage to the grids, especially to the accelerator grid. ＇Barrel＇ erosion can increase the accelerator grid aperture radius at a rate of 1.91~ 10-11 m/s, while the decelerator grid plays an important role in reducing ＇pits-and-grooves＇ erosion.展开更多
Ni-rich cathode materials show great potential of applying in high-energy lithium ion batteries,but their inferior cycling stability hinders this process.Study on the electrode/electrolyte interfacial reaction is indi...Ni-rich cathode materials show great potential of applying in high-energy lithium ion batteries,but their inferior cycling stability hinders this process.Study on the electrode/electrolyte interfacial reaction is indispensable to understand the capacity failure mechanism of Ni-rich cathode materials and further address this issue.This work demonstrates the domain size effects on interfacial side reactions firstly,and further analyzes the inherent mechanism of side reaction induced capacity decay through comparing the interfacial behaviors before and after MgO coating.It has been determined that LiF deposition caused thicker SEI films may not increase the surface film resistance,while HF erosion induced surface phase transition will increase the charge transfer resistance,and the later plays the dominant factor to declined capacity of Ni-rich cathode materials.This work suggests strategies to suppress the capacity decay of layered cathode materials and provides a guidance for the domain size control to match the various applications under different current rates.展开更多
文摘Ion optics is a critical component of ion thrusters. A two-dimensional axisymmetric model is developed to study the characteristics of three-grid electron cyclotron resonance ion thruster optics. The code is based on a particle-in-cell combined with the Monte Carlo collision method to simulate ion dynamics and charge-exchange processes in the grid region. The simulation results show that the mode can give a reasonable estimate of the physics characteristics of the ion optics. The design of the ion optics satisfies the requirement of preventing electron backstreaming. Charge-exchange ions can cause damage to the grids, especially to the accelerator grid. ＇Barrel＇ erosion can increase the accelerator grid aperture radius at a rate of 1.91~ 10-11 m/s, while the decelerator grid plays an important role in reducing ＇pits-and-grooves＇ erosion.
基金supported by the National Key R&D Program of China(2016YFB0100301)the National Natural Science Foundation of China(21875022,51802020,U1664255)+2 种基金the Science and Technology Innovation Foundation of Beijing Institute of Technology Chongqing Innovation Center(2020CX5100006)the Young Elite Scientists Sponsorship Program by CAST(2018QNRC001)the support from the Beijing Institute of Technology Research Fund Program for Young Scholars。
文摘Ni-rich cathode materials show great potential of applying in high-energy lithium ion batteries,but their inferior cycling stability hinders this process.Study on the electrode/electrolyte interfacial reaction is indispensable to understand the capacity failure mechanism of Ni-rich cathode materials and further address this issue.This work demonstrates the domain size effects on interfacial side reactions firstly,and further analyzes the inherent mechanism of side reaction induced capacity decay through comparing the interfacial behaviors before and after MgO coating.It has been determined that LiF deposition caused thicker SEI films may not increase the surface film resistance,while HF erosion induced surface phase transition will increase the charge transfer resistance,and the later plays the dominant factor to declined capacity of Ni-rich cathode materials.This work suggests strategies to suppress the capacity decay of layered cathode materials and provides a guidance for the domain size control to match the various applications under different current rates.
