{4-[4-p-nitrobenzoyl(thiophenyl) phenyl]} phenyl iodonium hexafluorophosphate(Ⅳ) is synthesized from iodobenzene,p-nitro-benzoic acid and diphenyl sulfide through Friedel-Crafts acylation、substitution reaction and m...{4-[4-p-nitrobenzoyl(thiophenyl) phenyl]} phenyl iodonium hexafluorophosphate(Ⅳ) is synthesized from iodobenzene,p-nitro-benzoic acid and diphenyl sulfide through Friedel-Crafts acylation、substitution reaction and metathesis.It’s structure is identified by UV,1HNMR,MS and IR.The photoinitiability of product is tested.展开更多
4-[4-benzoyl(phenoxy) phenyl] Phenyl Iodonium Hexafluorophosphate(Ⅲ) was synthesized from diphenyl ether and iodobenzene as main crude material through Friedel-Crafts acylation、substitution reaction and metathesis....4-[4-benzoyl(phenoxy) phenyl] Phenyl Iodonium Hexafluorophosphate(Ⅲ) was synthesized from diphenyl ether and iodobenzene as main crude material through Friedel-Crafts acylation、substitution reaction and metathesis.Ⅲ was a novel Free radical-Cationic Hybrid UV photoinitiator and the structure was identified by UV,1HNMR,IR and MS,and discussed the modification of synthetic route.展开更多
Reduction of diaryldiselenides by the system of Cp2TiCl2/Bu'MgBr/THF gave the nucleophilic arylselenium complex. They reacted with diaryl iodonium salts to afford unsymmetrical diaryl selenides in high yields.
A fast and convenient base-free Heck reaction of acrylic acid with hypervalent iodonium salts was achieved under microwave irradiation in water, providing a simple method for the synthesis of trans-cinnanfic acids in ...A fast and convenient base-free Heck reaction of acrylic acid with hypervalent iodonium salts was achieved under microwave irradiation in water, providing a simple method for the synthesis of trans-cinnanfic acids in good yields in short time.展开更多
文摘{4-[4-p-nitrobenzoyl(thiophenyl) phenyl]} phenyl iodonium hexafluorophosphate(Ⅳ) is synthesized from iodobenzene,p-nitro-benzoic acid and diphenyl sulfide through Friedel-Crafts acylation、substitution reaction and metathesis.It’s structure is identified by UV,1HNMR,MS and IR.The photoinitiability of product is tested.
文摘4-[4-benzoyl(phenoxy) phenyl] Phenyl Iodonium Hexafluorophosphate(Ⅲ) was synthesized from diphenyl ether and iodobenzene as main crude material through Friedel-Crafts acylation、substitution reaction and metathesis.Ⅲ was a novel Free radical-Cationic Hybrid UV photoinitiator and the structure was identified by UV,1HNMR,IR and MS,and discussed the modification of synthetic route.
文摘Reduction of diaryldiselenides by the system of Cp2TiCl2/Bu'MgBr/THF gave the nucleophilic arylselenium complex. They reacted with diaryl iodonium salts to afford unsymmetrical diaryl selenides in high yields.
文摘A fast and convenient base-free Heck reaction of acrylic acid with hypervalent iodonium salts was achieved under microwave irradiation in water, providing a simple method for the synthesis of trans-cinnanfic acids in good yields in short time.
基金Project supported by the National Natural Science Foundation of China(21602165)the “Chutian Scholar” Program from Department of Education of Hubei Provincethe “Hundred Talent” Program of Hubei Province~~
