As an im portant branch of fiber-shaped energy storage devices, the fiber-shaped supercapacitor has been widely studied recently. However, it remains challenging to simultaneously achieve fast electron transport and e...As an im portant branch of fiber-shaped energy storage devices, the fiber-shaped supercapacitor has been widely studied recently. However, it remains challenging to simultaneously achieve fast electron transport and excellent ion accessibility in one single fiber electrode of the fibershaped supercapacitor. Herein, a novel family of amphiphilic core-sheath structured carbon nanotube composite fibers has been developed and applied to the fiber-shaped supercapacitor to address the above challenge. The polyaniline-modified hydrophilic sheath of the composite fiber electrode effectively enhanced the electrochemical property via advancing ion accessibility, while Au-deposited hydrophobic core demonstrated improved electrical conductivity by fast electron supply. On the basis of a synergistic effect, a remarkable specific capacitance of 324 F cm^-3 at 0.5 A cm^-3 and greatly enhanced rate performance were achieved, i.e” a 79% retention (256 F cm 3) at 50 A cm^-3. The obtained fiber-shaped supercapacitor finally displayed remarkable energy and power densities of 7.2 mW h cm 3 and 10 W cm^-3, respectively. The strategy developed herein also presents a general pathway towards novel fiber electrodes for high-performance wearable devices.展开更多
20151648 Bai Yongbo(School of Earth Sciences,Lanzhou University,Lanzhou 730000,China);Meng Zhen Geology and Geochemical Characteristics of Dongdonggou Gold Deposit in Gansu Province(Gansu Geology,ISSN1004-4116,CN 62-1...20151648 Bai Yongbo(School of Earth Sciences,Lanzhou University,Lanzhou 730000,China);Meng Zhen Geology and Geochemical Characteristics of Dongdonggou Gold Deposit in Gansu Province(Gansu Geology,ISSN1004-4116,CN 62-1191/P,23(3),2014,p.21-25,4illus.,5tables,9refs.)展开更多
A [ReO(Imz)(Hyd)(H2O)2OH] complex was successfully synthesized by the ligand exchange method using oxorhenuim citrate and an imidazole /Hydanton mixed ligand system. Geometry optimization of complex has been carried o...A [ReO(Imz)(Hyd)(H2O)2OH] complex was successfully synthesized by the ligand exchange method using oxorhenuim citrate and an imidazole /Hydanton mixed ligand system. Geometry optimization of complex has been carried out using DFT at the B3LYP/LANL2DZ functional in singlet state. B3LYP predicated infrared spectrum of the geometrically optimized structure using the same level of the theory and the same base set showed good agreement with experimentally observed values. The spin allowed singlet-singlet electronic transition of the [ReO(Imz)(Hyd) (H2O)2OH] complex was calculated with time dependent density function theory (TD-DFT) and the UV-Vis spectra has been discussed on this basis. The complex was characterized using microanalysis and IR, UV-Vis, NMR and mass spectroscopic. The technetium tracer [99mTcO(Imz)(Hyd) (H2O)2OH] has also been synthesized by two methods using 99mTc-gluconate as a precursor or;by direct reduction. The radiochemical purity of the complex was over 95% as measured by thin layer chromatography. In vitro studies showed that the complex possessed good stability under physiological conditions. The partition coefficient indicated that the complex hydrophilic and the electrophoresis results showed that the complex cationic. Biodistrbution in mice showed that the complex accumulated in heart uptake of 9.53±3.87 % ID/gm at 5 min and good retention (6.37±1.21) % ID/gm at 60 min. One hour after the injection, the heart/liver, heart/lung and heart/blood radioactivity ratios were 0.46, 1.04 and 0.56, respectively. These findings indicate that the complex might be suitable for myocardial imaging.展开更多
20112622Bian Jianmin(College of Environment and Resources, Jilin University, Changchun 130026,China);Zha Enshuang Inverse Geochemical Modeling of Arsenic Groundwater at Arseniasis Area in the Western of
With sustained demand growth in downstreamsectors,both DMAC(N,N-dimethy-lacetamide)capacity and output have increasedrapidly in China with an average annual growthof 82.5% and 80.6% respectively from 2003to 2008.DMAC ...With sustained demand growth in downstreamsectors,both DMAC(N,N-dimethy-lacetamide)capacity and output have increasedrapidly in China with an average annual growthof 82.5% and 80.6% respectively from 2003to 2008.DMAC capacity in China reachedaround 80 000 t/a in 2008.Major producersinclude Zhejiang Jiangshan Chemical Co.,Ltd.,展开更多
To investigate the cold preservation effect of rat livers by modified storage method with self made HYD solution. Methods. The modified method was that the vascular bed of rat livers was expanded with an additional 20...To investigate the cold preservation effect of rat livers by modified storage method with self made HYD solution. Methods. The modified method was that the vascular bed of rat livers was expanded with an additional 20 to 40ml self made HYD solution/100g liver. After removing the liver, the extra HYD solution expressed as % liver weight was entrapped via portal infusion by tying off the supra and infra hepatic inferior vena cava. According to the amount of extra HYD solution, 40 rats were randomly divided into four groups including: control group with conventional storage method, 20% group, 30% group and 40% group. The preservation effect of modified storage method with that of conventional storage method by using isolated perfused rat liver model was compared. [WT5”BX] Results.[WT5”BZ] Bile production and all the indices of hepatic microcirculation including portal perfusion pressure, endothelin 1 in the effluent, trypan blue distribution time and histology in modified method groups were significantly superior to those in control group (P<0.05). The liver enzymes in 30% group were markedly lower than those in control group (P<0.05). The preservation effect of rat liver in 30% group was the best among the modified method groups. Conclusion. The modified cold storage method is effective and may have potential for clinical application for liver preservation.展开更多
20141470 Chai Lu(Shenyang Institute of Geology and Mineral Resources,CGS,Shenyang110034,China);Zhu Qun Distribution of Significant Metal Mineral Resources the in Adjacent Areas of China,Russia and Mongolia(Geology and...20141470 Chai Lu(Shenyang Institute of Geology and Mineral Resources,CGS,Shenyang110034,China);Zhu Qun Distribution of Significant Metal Mineral Resources the in Adjacent Areas of China,Russia and Mongolia(Geology and Resources,ISSN1671-1947,CN21-1458/P,22(5),2013,p.397-402,2 illus.,3 tables,20 refs.)Key words:metal ores,China,Russia。展开更多
基金supported by the Ministry of Science and Technology (2016YFA0203302)the National Natural Science Foundation of China (21634003, 51573027, 51673043, 21604012, 21805044 and 21875042)+1 种基金Shanghai Science and Technology Committee (16JC1400702, 17QA1400400, 18QA1400700 and 18QA1400800)SHMEC (2017-01-07-00-07-E00062)
文摘As an im portant branch of fiber-shaped energy storage devices, the fiber-shaped supercapacitor has been widely studied recently. However, it remains challenging to simultaneously achieve fast electron transport and excellent ion accessibility in one single fiber electrode of the fibershaped supercapacitor. Herein, a novel family of amphiphilic core-sheath structured carbon nanotube composite fibers has been developed and applied to the fiber-shaped supercapacitor to address the above challenge. The polyaniline-modified hydrophilic sheath of the composite fiber electrode effectively enhanced the electrochemical property via advancing ion accessibility, while Au-deposited hydrophobic core demonstrated improved electrical conductivity by fast electron supply. On the basis of a synergistic effect, a remarkable specific capacitance of 324 F cm^-3 at 0.5 A cm^-3 and greatly enhanced rate performance were achieved, i.e” a 79% retention (256 F cm 3) at 50 A cm^-3. The obtained fiber-shaped supercapacitor finally displayed remarkable energy and power densities of 7.2 mW h cm 3 and 10 W cm^-3, respectively. The strategy developed herein also presents a general pathway towards novel fiber electrodes for high-performance wearable devices.
文摘20151648 Bai Yongbo(School of Earth Sciences,Lanzhou University,Lanzhou 730000,China);Meng Zhen Geology and Geochemical Characteristics of Dongdonggou Gold Deposit in Gansu Province(Gansu Geology,ISSN1004-4116,CN 62-1191/P,23(3),2014,p.21-25,4illus.,5tables,9refs.)
文摘A [ReO(Imz)(Hyd)(H2O)2OH] complex was successfully synthesized by the ligand exchange method using oxorhenuim citrate and an imidazole /Hydanton mixed ligand system. Geometry optimization of complex has been carried out using DFT at the B3LYP/LANL2DZ functional in singlet state. B3LYP predicated infrared spectrum of the geometrically optimized structure using the same level of the theory and the same base set showed good agreement with experimentally observed values. The spin allowed singlet-singlet electronic transition of the [ReO(Imz)(Hyd) (H2O)2OH] complex was calculated with time dependent density function theory (TD-DFT) and the UV-Vis spectra has been discussed on this basis. The complex was characterized using microanalysis and IR, UV-Vis, NMR and mass spectroscopic. The technetium tracer [99mTcO(Imz)(Hyd) (H2O)2OH] has also been synthesized by two methods using 99mTc-gluconate as a precursor or;by direct reduction. The radiochemical purity of the complex was over 95% as measured by thin layer chromatography. In vitro studies showed that the complex possessed good stability under physiological conditions. The partition coefficient indicated that the complex hydrophilic and the electrophoresis results showed that the complex cationic. Biodistrbution in mice showed that the complex accumulated in heart uptake of 9.53±3.87 % ID/gm at 5 min and good retention (6.37±1.21) % ID/gm at 60 min. One hour after the injection, the heart/liver, heart/lung and heart/blood radioactivity ratios were 0.46, 1.04 and 0.56, respectively. These findings indicate that the complex might be suitable for myocardial imaging.
文摘20112622Bian Jianmin(College of Environment and Resources, Jilin University, Changchun 130026,China);Zha Enshuang Inverse Geochemical Modeling of Arsenic Groundwater at Arseniasis Area in the Western of
文摘With sustained demand growth in downstreamsectors,both DMAC(N,N-dimethy-lacetamide)capacity and output have increasedrapidly in China with an average annual growthof 82.5% and 80.6% respectively from 2003to 2008.DMAC capacity in China reachedaround 80 000 t/a in 2008.Major producersinclude Zhejiang Jiangshan Chemical Co.,Ltd.,
文摘To investigate the cold preservation effect of rat livers by modified storage method with self made HYD solution. Methods. The modified method was that the vascular bed of rat livers was expanded with an additional 20 to 40ml self made HYD solution/100g liver. After removing the liver, the extra HYD solution expressed as % liver weight was entrapped via portal infusion by tying off the supra and infra hepatic inferior vena cava. According to the amount of extra HYD solution, 40 rats were randomly divided into four groups including: control group with conventional storage method, 20% group, 30% group and 40% group. The preservation effect of modified storage method with that of conventional storage method by using isolated perfused rat liver model was compared. [WT5”BX] Results.[WT5”BZ] Bile production and all the indices of hepatic microcirculation including portal perfusion pressure, endothelin 1 in the effluent, trypan blue distribution time and histology in modified method groups were significantly superior to those in control group (P<0.05). The liver enzymes in 30% group were markedly lower than those in control group (P<0.05). The preservation effect of rat liver in 30% group was the best among the modified method groups. Conclusion. The modified cold storage method is effective and may have potential for clinical application for liver preservation.
文摘20141470 Chai Lu(Shenyang Institute of Geology and Mineral Resources,CGS,Shenyang110034,China);Zhu Qun Distribution of Significant Metal Mineral Resources the in Adjacent Areas of China,Russia and Mongolia(Geology and Resources,ISSN1671-1947,CN21-1458/P,22(5),2013,p.397-402,2 illus.,3 tables,20 refs.)Key words:metal ores,China,Russia。
