Ti-Ni porous alloy was made from titanium and nickel powder mixture in equiatomic composition by combustion synthesis technique (self-propagation high temperature synthesis). The result analyzed by SEM and XRD shows t...Ti-Ni porous alloy was made from titanium and nickel powder mixture in equiatomic composition by combustion synthesis technique (self-propagation high temperature synthesis). The result analyzed by SEM and XRD shows that the alloy possesses high porosity (50%～70%), and mainly consists of TiNi phase as well as rare Ti_2Ni and TiNi_3 transition phase. Then it was activated, cracked and used as sorbent for hydrogen isotope separation. Through experiment investigation, it was discovered that the alloy is able to absorb hydrogen in very large quantities in the lattice thereof, but deuterium only very slightly or not at all, at temperatures up to 623 K, especially at temperatures from about 323 to 423 K. According to this characteristic, the Ti-Ni porous alloys may replace noble metal palladium(Pd) as used for hydrogen isotope separation and purification. Study illustrated that the technology would have a promising engineering application, such as being used for reprocessing Tokamak exhaust gases and producing high purity deuterium.展开更多
1 Introduction In deeper study of HTSC, it is found that Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub> has an unusualproperty of absorbing hydrogen. The abso...1 Introduction In deeper study of HTSC, it is found that Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub> has an unusualproperty of absorbing hydrogen. The absorption process could be described by a gen-eral equation （x/2） H<sub>2</sub> + Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub>→H<sub>x</sub>Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub>.A structural analysis indicates that absorbed hydrogen is located on the Cu-Osurface and its state change with temperature. As an isotope of hydrogen,deuterium can have simlar effects. Therefore we have experimentally studied展开更多
文摘Ti-Ni porous alloy was made from titanium and nickel powder mixture in equiatomic composition by combustion synthesis technique (self-propagation high temperature synthesis). The result analyzed by SEM and XRD shows that the alloy possesses high porosity (50%～70%), and mainly consists of TiNi phase as well as rare Ti_2Ni and TiNi_3 transition phase. Then it was activated, cracked and used as sorbent for hydrogen isotope separation. Through experiment investigation, it was discovered that the alloy is able to absorb hydrogen in very large quantities in the lattice thereof, but deuterium only very slightly or not at all, at temperatures up to 623 K, especially at temperatures from about 323 to 423 K. According to this characteristic, the Ti-Ni porous alloys may replace noble metal palladium(Pd) as used for hydrogen isotope separation and purification. Study illustrated that the technology would have a promising engineering application, such as being used for reprocessing Tokamak exhaust gases and producing high purity deuterium.
文摘1 Introduction In deeper study of HTSC, it is found that Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub> has an unusualproperty of absorbing hydrogen. The absorption process could be described by a gen-eral equation （x/2） H<sub>2</sub> + Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub>→H<sub>x</sub>Y<sub>1</sub>Ba<sub>2</sub>Cu<sub>3</sub>O<sub>7-δ</sub>.A structural analysis indicates that absorbed hydrogen is located on the Cu-Osurface and its state change with temperature. As an isotope of hydrogen,deuterium can have simlar effects. Therefore we have experimentally studied
