Perovskite solar cells(PSCs) have attracted much attention because of their high efficiencies and low costs for production.Although academic research started late in China, compared to that in Europe and Korea, the ma...Perovskite solar cells(PSCs) have attracted much attention because of their high efficiencies and low costs for production.Although academic research started late in China, compared to that in Europe and Korea, the majority of active PSC research is now conducted in China;furthermore, Chinese research groups currently hold the certified highest efficiency record for both an individual PSC and a PSC module. China is also the world’s largest supplier of solar modules, making it a promising country in which to realize the commercialization of PSCs. Herein, we review PSC research activities undertaken in China(both academic and industrial) and discuss significant remaining challenges to overcome for early commercialization of PSCs. We propose that research activities shift away from material and device structure development toward improving PSC stability and developing methods for large-area module fabrication. In addition, we suggest that a recognized certification center is urgently needed in China to further accelerate PSC research.展开更多
Perovskite materials have drawn a lot of interest recently due to their potential to increase solar cell efficiency. This study uses the solar cell capacitance simulator (SCAPS-1D) to develop and simulate a perovskite...Perovskite materials have drawn a lot of interest recently due to their potential to increase solar cell efficiency. This study uses the solar cell capacitance simulator (SCAPS-1D) to develop and simulate a perovskite solar cell made of semiconductor materials. The design that has been suggested is Al:ZnO/ZnO/CdS/CsSnCl<sub>3</sub> and MoS<sub>2</sub>. The analysis focuses on how different characteristics of the material affect the device’s performance. The analysis of the data reveals that the architecture had 26.15% power conversion efficiency (PCE). The solar cell creates an interest in developing a non-toxic solar cell with low manufacturing costs, outstanding conversion efficiency, and stability.展开更多
n-type CZ-Si wafers featuring longer minority carrier lifetime and higher tolerance of certain metal contamination can offer one of the best Si-based solar cells. In this study, Si heterojuction （SHJ） solar cells wh...n-type CZ-Si wafers featuring longer minority carrier lifetime and higher tolerance of certain metal contamination can offer one of the best Si-based solar cells. In this study, Si heterojuction （SHJ） solar cells which was fabricated with different wafers in the top, middle and tail positions of the ingot, exhibited a stable high efficiency of〉 22% in spite of the various profiles of the resistivity and lifetime, which demonstrated the high material utilization of n-type ingot. In addition, for effectively converting the sunlight into electrical power, the pyramid size, pyramid density and roughness of surface of the Cz-Si wafer were investigated by scanning electron microscope （SEM） and transmission electron microscope （TEM）. Furthermore, the dependence of SHJ solar cell open- circuit voltage on the surface topography was discussed, which indicated that the uniformity of surface pyramid helps to improve the open-circuit voltage and conversion efficiency. Moreover, the simulation revealed that the highest efficiency of the SHJ solar cell could be achieved by the wafer with a thickness of 100 μm. Fortunately, over 23% of the conversion efficiency of the SHJ solar cell with a wafer thickness of 100 μm was obtained based on the systematic optimization of cell fabrication process in the pilot production line. Evidently, the large availability of both n-type ingot and thinner wafer strongly supported the lower cost fabrication of high efficiency SHJ solar cell.展开更多
高效性、轻型化是未来单体太阳电池的发展方向。采用金属有机物化学气相沉积(MOCVD)法制备高效Ga In P/Ga As/Ge正向晶格匹配三结砷化镓外延片,先采用机械磨削方式减薄到一定厚度,再通过氢氟酸、双氧水和水的混合液将衬底减薄至120、100...高效性、轻型化是未来单体太阳电池的发展方向。采用金属有机物化学气相沉积(MOCVD)法制备高效Ga In P/Ga As/Ge正向晶格匹配三结砷化镓外延片,先采用机械磨削方式减薄到一定厚度,再通过氢氟酸、双氧水和水的混合液将衬底减薄至120、100、80μm,最薄至50μm。设计新型背电极,解决超薄片翘曲问题。通过以上手段制备成不同厚度和不同面积的砷化镓太阳电池,利用厚度50μm的外延片,制备出最大面积为12.25 cm2的太阳电池,其光电转换效率为29.52%(AM0,25℃)。利用厚度80μm的外延片,制备出最大面积为30.18 cm2的太阳电池,其光电转换效率为29.7%(AM0,25℃)。经过温度冲击、焊点拉力和稳态湿热等可靠性试验考核,均满足要求。展开更多
A metamorphic GaInP/GaAs/GaInAs/Ge multi-junction solar cell with InAs quantum dots is investigated, and the analytical expression of the energy conversion efficiency on the multi-junction tandem solar cell is derived...A metamorphic GaInP/GaAs/GaInAs/Ge multi-junction solar cell with InAs quantum dots is investigated, and the analytical expression of the energy conversion efficiency on the multi-junction tandem solar cell is derived using the detailed balance principle and the Kronig-Penney model.The influences of interdot distance, quantum-dot size and the intermediate band location on the energy conversion efficiency are studied.This shows that the maximum efficiency,as a function of quantum-dot size and distance,is about 60.15%under the maximum concentration for only one InAs/GaAs subcell,and is even up to 39.69%for the overall cell.In addition,other efficiency factors such as current mismatch,the formation of a quasicontinuum conduction band and concentrated light are examined.展开更多
Development of highly-efficient photovoltaic (PV) modules and expanding its application fields are significant for the further development of PV technologies and realization of innovative green energy infrastructure b...Development of highly-efficient photovoltaic (PV) modules and expanding its application fields are significant for the further development of PV technologies and realization of innovative green energy infrastructure based on PV. Especially, development of solar-powered vehicles as a new application is highly desired and very important for this end. This paper presents the impact of PV cell/module conversion efficiency on reduction in CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> emission and increase in driving range of the electric based vehicles. Our studies show that the utilization of a highly-efficient (higher than 30%) PV module enables the solar-powered vehicle to drive 30 km/day without charging in the case of light weig</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">h</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">t cars with elec</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">t</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ric mileage of 17</span></span></span><span><span><span style="font-family:""> </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">km/kWh under solar irrad</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">i</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">a</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">t</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"展开更多
基金supported by the National Natural Science Foundation of China(11574199,11674219)
文摘Perovskite solar cells(PSCs) have attracted much attention because of their high efficiencies and low costs for production.Although academic research started late in China, compared to that in Europe and Korea, the majority of active PSC research is now conducted in China;furthermore, Chinese research groups currently hold the certified highest efficiency record for both an individual PSC and a PSC module. China is also the world’s largest supplier of solar modules, making it a promising country in which to realize the commercialization of PSCs. Herein, we review PSC research activities undertaken in China(both academic and industrial) and discuss significant remaining challenges to overcome for early commercialization of PSCs. We propose that research activities shift away from material and device structure development toward improving PSC stability and developing methods for large-area module fabrication. In addition, we suggest that a recognized certification center is urgently needed in China to further accelerate PSC research.
文摘Perovskite materials have drawn a lot of interest recently due to their potential to increase solar cell efficiency. This study uses the solar cell capacitance simulator (SCAPS-1D) to develop and simulate a perovskite solar cell made of semiconductor materials. The design that has been suggested is Al:ZnO/ZnO/CdS/CsSnCl<sub>3</sub> and MoS<sub>2</sub>. The analysis focuses on how different characteristics of the material affect the device’s performance. The analysis of the data reveals that the architecture had 26.15% power conversion efficiency (PCE). The solar cell creates an interest in developing a non-toxic solar cell with low manufacturing costs, outstanding conversion efficiency, and stability.
文摘n-type CZ-Si wafers featuring longer minority carrier lifetime and higher tolerance of certain metal contamination can offer one of the best Si-based solar cells. In this study, Si heterojuction （SHJ） solar cells which was fabricated with different wafers in the top, middle and tail positions of the ingot, exhibited a stable high efficiency of〉 22% in spite of the various profiles of the resistivity and lifetime, which demonstrated the high material utilization of n-type ingot. In addition, for effectively converting the sunlight into electrical power, the pyramid size, pyramid density and roughness of surface of the Cz-Si wafer were investigated by scanning electron microscope （SEM） and transmission electron microscope （TEM）. Furthermore, the dependence of SHJ solar cell open- circuit voltage on the surface topography was discussed, which indicated that the uniformity of surface pyramid helps to improve the open-circuit voltage and conversion efficiency. Moreover, the simulation revealed that the highest efficiency of the SHJ solar cell could be achieved by the wafer with a thickness of 100 μm. Fortunately, over 23% of the conversion efficiency of the SHJ solar cell with a wafer thickness of 100 μm was obtained based on the systematic optimization of cell fabrication process in the pilot production line. Evidently, the large availability of both n-type ingot and thinner wafer strongly supported the lower cost fabrication of high efficiency SHJ solar cell.
文摘A metamorphic GaInP/GaAs/GaInAs/Ge multi-junction solar cell with InAs quantum dots is investigated, and the analytical expression of the energy conversion efficiency on the multi-junction tandem solar cell is derived using the detailed balance principle and the Kronig-Penney model.The influences of interdot distance, quantum-dot size and the intermediate band location on the energy conversion efficiency are studied.This shows that the maximum efficiency,as a function of quantum-dot size and distance,is about 60.15%under the maximum concentration for only one InAs/GaAs subcell,and is even up to 39.69%for the overall cell.In addition,other efficiency factors such as current mismatch,the formation of a quasicontinuum conduction band and concentrated light are examined.
文摘Development of highly-efficient photovoltaic (PV) modules and expanding its application fields are significant for the further development of PV technologies and realization of innovative green energy infrastructure based on PV. Especially, development of solar-powered vehicles as a new application is highly desired and very important for this end. This paper presents the impact of PV cell/module conversion efficiency on reduction in CO</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;"> emission and increase in driving range of the electric based vehicles. Our studies show that the utilization of a highly-efficient (higher than 30%) PV module enables the solar-powered vehicle to drive 30 km/day without charging in the case of light weig</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">h</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">t cars with elec</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">t</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">ric mileage of 17</span></span></span><span><span><span style="font-family:""> </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">km/kWh under solar irrad</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">i</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">a</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">t</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"
