针对甘肃白银碱化盐土质地黏重、透水性差、难以改良利用等瓶颈问题,在统一施用有机肥30 t hm-2的基础上,采用灌溉淋洗及施用脱硫石膏、糠醛渣进行改良。通过室内土柱入渗试验,研究施用改良剂对碱化盐土的入渗率、累积入渗量、湿润锋随...针对甘肃白银碱化盐土质地黏重、透水性差、难以改良利用等瓶颈问题,在统一施用有机肥30 t hm-2的基础上,采用灌溉淋洗及施用脱硫石膏、糠醛渣进行改良。通过室内土柱入渗试验,研究施用改良剂对碱化盐土的入渗率、累积入渗量、湿润锋随时间的变化规律及盐分离子的影响。试验结果表明:改良措施对土壤入渗和盐分离子动态影响显著,在统一施用脱硫石膏30 t hm-2、糠醛渣7.5 t hm-2和有机肥30 t hm-2的条件下,处理后土壤任意时刻入渗率、湿润锋推进距离、累积入渗量与入渗时间呈幂函数关系;pH值、碱化度、全盐含量显著降低,Na+、CO32-、HCO3-含量显著降低。展开更多
The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and micr...The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and microtopography.The results showed a significant decrease in Na_(2)O content(>30 wt.%)of FGD gypsum-treated bauxite residue after 30 min of mechanical ball milling.Mechanical ball milling resulted in differentiation of the elemental distribution,modification of the minerals in crystalline structure,and promotion in the dissolution of alkaline minerals,thus enhancing the acid neutralization capacity of bauxite residue.5 wt.%FGD gypsum combined with 30 min mechanical ball milling was optimal for the dealkalization of bauxite residue.展开更多
Neutralization of alkaline properties of bauxite residue(BR)by using organic acid and gypsum additions may effectively improve electrochemical properties and alleviate physicochemical barriers to ecological rehabilita...Neutralization of alkaline properties of bauxite residue(BR)by using organic acid and gypsum additions may effectively improve electrochemical properties and alleviate physicochemical barriers to ecological rehabilitation.Mineral acids,citric acid and hybrid acid–gypsum additions were compared for their potential to transform and improve zeta potential,isoelectric point(IEP),surface protonation and active alkaline-OH groups,which are critical factors for further improvement of physicochemical and biological properties later.Isoelectric points of untransformed bauxite residue and six transformed derivatives were determined by using electroacoustic methods.Electrochemical characteristics were significantly improved by the amendments used,resulting in reduced IEP and-OH groups and decreased surface protonation for transformed residues.XRD results revealed that the primary alkaline minerals of cancrinite,calcite and grossular were transformed by the treatments.The treatments of citric acid and gypsum promoted the dissolution of cancrinite.From the SEM examination,citric acid and gypsum treatments contributed to the reduction in IEP and redistribution of-OH groups on particle surfaces.The collective evidence suggested that citric acid and gypsum amendments may be used firstly to rapidly amend bauxite residues for alleviating the caustic conditions prior to the consideration of soil formation in bauxite residue.展开更多
文摘针对甘肃白银碱化盐土质地黏重、透水性差、难以改良利用等瓶颈问题,在统一施用有机肥30 t hm-2的基础上,采用灌溉淋洗及施用脱硫石膏、糠醛渣进行改良。通过室内土柱入渗试验,研究施用改良剂对碱化盐土的入渗率、累积入渗量、湿润锋随时间的变化规律及盐分离子的影响。试验结果表明:改良措施对土壤入渗和盐分离子动态影响显著,在统一施用脱硫石膏30 t hm-2、糠醛渣7.5 t hm-2和有机肥30 t hm-2的条件下,处理后土壤任意时刻入渗率、湿润锋推进距离、累积入渗量与入渗时间呈幂函数关系;pH值、碱化度、全盐含量显著降低,Na+、CO32-、HCO3-含量显著降低。
基金the National Natural Science Foundation of China(Nos.42177391,42077379)the Natural Science Foundation of Hunan Province,China(No.2022JJ20060)+1 种基金the Central South University Innovation-driven Research Program,China(No.2023CXQD065)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2023ZZTS0800).
文摘The synergistic impact of mechanical ball milling and flue gas desulfurization(FGD)gypsum on the dealkalization of bauxite residue was investigated through integrated analyses of solution chemistry,mineralogy,and microtopography.The results showed a significant decrease in Na_(2)O content(>30 wt.%)of FGD gypsum-treated bauxite residue after 30 min of mechanical ball milling.Mechanical ball milling resulted in differentiation of the elemental distribution,modification of the minerals in crystalline structure,and promotion in the dissolution of alkaline minerals,thus enhancing the acid neutralization capacity of bauxite residue.5 wt.%FGD gypsum combined with 30 min mechanical ball milling was optimal for the dealkalization of bauxite residue.
基金Projects(41877511,41842020)supported by the National Natural Science Foundation of China
文摘Neutralization of alkaline properties of bauxite residue(BR)by using organic acid and gypsum additions may effectively improve electrochemical properties and alleviate physicochemical barriers to ecological rehabilitation.Mineral acids,citric acid and hybrid acid–gypsum additions were compared for their potential to transform and improve zeta potential,isoelectric point(IEP),surface protonation and active alkaline-OH groups,which are critical factors for further improvement of physicochemical and biological properties later.Isoelectric points of untransformed bauxite residue and six transformed derivatives were determined by using electroacoustic methods.Electrochemical characteristics were significantly improved by the amendments used,resulting in reduced IEP and-OH groups and decreased surface protonation for transformed residues.XRD results revealed that the primary alkaline minerals of cancrinite,calcite and grossular were transformed by the treatments.The treatments of citric acid and gypsum promoted the dissolution of cancrinite.From the SEM examination,citric acid and gypsum treatments contributed to the reduction in IEP and redistribution of-OH groups on particle surfaces.The collective evidence suggested that citric acid and gypsum amendments may be used firstly to rapidly amend bauxite residues for alleviating the caustic conditions prior to the consideration of soil formation in bauxite residue.
