Groundwater from karst subterranean streams is among the world＇s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are impacted by both natural environment and pe...Groundwater from karst subterranean streams is among the world＇s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are impacted by both natural environment and people. Therefore, the study of hydrochemistry and its solutes＇ sources is very important to ensure the normal function of life support systems. In this paper, thirty-five representative karst groundwater samples were collected from different aquifers （limestone and dolomite） and various land use types in Chongqing to trace the sources of solutes and relative hydrochemical processes. Hydrogeochemical types of karst groundwater in Chongqing were mainly of the Ca-HCO3 type or Ca （Mg）-HCO3 type. However, some hydrochemical types of karst groundwater were the K＋Na＋Ca-SO4 type （G25 site） or Ca-HCO3＋SO4 type （G26 and G14 site）, indicating that the hydrochemistry of these sites might be strongly influenced by anthropogenic activities or unique geological characteristics. The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06 ~tmmol/L, and the STSr/S6Sr varied from 0.70751 to 0.71627. The j34S-SO42- fell into a range of-6.8%o-21.5%o, with a mean value of 5.6%o. The variations of both 87Sr/S6Sr and Sr values of the groundwater samples indicated that the Sr element was controlled by the weathering of limestone, dolomite and silicate rock. However, the figure of STSr/S6Sr vs. Sr2＋/[K＋＋Na＋] showed that the anthropogenic inputs also obviously contributed to the Sr contents. For tracing the detailed anthropogenic effects, we traced the sources of solutes collected karst groundwater samples in Chongqing according to the j34S value of potential sulfate sources. The variations of both j34S and 1/ SO42- values of the groundwater samples indicated that the atmospheric acid deposition （AAD）, dissolution of gypsum （GD）, oxidation of sulfide mineral （OS） or anthropogenic inputs （SF： sewage or fertilizer） have contributed to solutes in karst gro展开更多
基金supported by the National Natural Science Foundation of China(No:41072192)the Natural Science Foundation Project of Chongqing,CSTC(No. CSTC2010BC7004)+2 种基金the Special Fund for Public Benefit Scientific Research of Ministry of Land and Resources of China(201111022)the Guangxi Natural Science Foundation Project(2012GXNSFBA053137)IGCP/ SIDA 598 Project
文摘Groundwater from karst subterranean streams is among the world＇s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are impacted by both natural environment and people. Therefore, the study of hydrochemistry and its solutes＇ sources is very important to ensure the normal function of life support systems. In this paper, thirty-five representative karst groundwater samples were collected from different aquifers （limestone and dolomite） and various land use types in Chongqing to trace the sources of solutes and relative hydrochemical processes. Hydrogeochemical types of karst groundwater in Chongqing were mainly of the Ca-HCO3 type or Ca （Mg）-HCO3 type. However, some hydrochemical types of karst groundwater were the K＋Na＋Ca-SO4 type （G25 site） or Ca-HCO3＋SO4 type （G26 and G14 site）, indicating that the hydrochemistry of these sites might be strongly influenced by anthropogenic activities or unique geological characteristics. The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06 ~tmmol/L, and the STSr/S6Sr varied from 0.70751 to 0.71627. The j34S-SO42- fell into a range of-6.8%o-21.5%o, with a mean value of 5.6%o. The variations of both 87Sr/S6Sr and Sr values of the groundwater samples indicated that the Sr element was controlled by the weathering of limestone, dolomite and silicate rock. However, the figure of STSr/S6Sr vs. Sr2＋/[K＋＋Na＋] showed that the anthropogenic inputs also obviously contributed to the Sr contents. For tracing the detailed anthropogenic effects, we traced the sources of solutes collected karst groundwater samples in Chongqing according to the j34S value of potential sulfate sources. The variations of both j34S and 1/ SO42- values of the groundwater samples indicated that the atmospheric acid deposition （AAD）, dissolution of gypsum （GD）, oxidation of sulfide mineral （OS） or anthropogenic inputs （SF： sewage or fertilizer） have contributed to solutes in karst gro
