Polyurethane elastomers with graded structure were prepared in the graded temperature field. The samples were characterized by FTIR technology. The results show that the degree of microphase separation in the samples ...Polyurethane elastomers with graded structure were prepared in the graded temperature field. The samples were characterized by FTIR technology. The results show that the degree of microphase separation in the samples decreases with the decrease of the curing temperature. As far as the molar ratio of NH2 and NCO is concerned, the sample exhibits better graded morphology when the ratio is 0.95. The transparence of the samples prepared also changes gradually, increasing along the direction, in which temperature decreases.展开更多
The grade crossings and adjacent pavements of urban trams are generally subjected to complex load conditions and are susceptible to damage.Therefore,in this study,a novel pavement structure between tram tracks and roa...The grade crossings and adjacent pavements of urban trams are generally subjected to complex load conditions and are susceptible to damage.Therefore,in this study,a novel pavement structure between tram tracks and roads constructed using polyurethane(PU)elastic concrete and ultra-high-performance concrete(UHPC),referred to as a track-road transitional pavement(TRTP),is proposed.Subsequently,its performance and feasibility are evaluated using experimental and numerical methods.First,the mechanical properties of the PU elastic concrete are evaluated.The performance of the proposed structure is investigated using a three-dimensional finite element model,where vehicleinduced dynamic and static loads are considered.The results show that PU elastic concrete and the proposed combined TRTP are applicable and functioned as intended.Additionally,the PU elastic concrete achieved sufficient performance.The recommended width of the TRTP is approximately 50 mm.Meanwhile,the application of UHPC under a PU elastic concrete layer significantly reduces vertical deformation.Results of numerical calculations confirmed the high structural performance and feasibility of the proposed TRTP.Finally,material performance standards are recommended to provide guidance for pavement design and the construction of tram-grade crossings in the future.展开更多
文中以医用级高分子聚氨酯(TPU)为原材料,通过热压成型制备厚1.2 mm TPU片材,并制取75×4哑铃型拉伸试样。在电子万能试验机上以较高的恒定拉伸速率进行拉伸,预先设定应力到某一设定值后停止拉伸,然后应力以一定速度进行减载。实验...文中以医用级高分子聚氨酯(TPU)为原材料,通过热压成型制备厚1.2 mm TPU片材,并制取75×4哑铃型拉伸试样。在电子万能试验机上以较高的恒定拉伸速率进行拉伸,预先设定应力到某一设定值后停止拉伸,然后应力以一定速度进行减载。实验探索了整个拉伸-回复循环中应力与应变的关系,研究了拉伸速度对医用级TPU拉伸强度及断裂伸长率的影响,并对拉伸过程中出现应力发白现象进行探究。结果表明,TPU是一种强而韧的硬弹性高分子材料,在高应力大形变下由弹性提供的可逆形变约80%,粘性提供的不可逆形变约20%。在高应力下材料内部孔洞尺寸变大,由此引起材料由透明转而发白,此光学现象可反复发生。展开更多
文摘Polyurethane elastomers with graded structure were prepared in the graded temperature field. The samples were characterized by FTIR technology. The results show that the degree of microphase separation in the samples decreases with the decrease of the curing temperature. As far as the molar ratio of NH2 and NCO is concerned, the sample exhibits better graded morphology when the ratio is 0.95. The transparence of the samples prepared also changes gradually, increasing along the direction, in which temperature decreases.
文摘The grade crossings and adjacent pavements of urban trams are generally subjected to complex load conditions and are susceptible to damage.Therefore,in this study,a novel pavement structure between tram tracks and roads constructed using polyurethane(PU)elastic concrete and ultra-high-performance concrete(UHPC),referred to as a track-road transitional pavement(TRTP),is proposed.Subsequently,its performance and feasibility are evaluated using experimental and numerical methods.First,the mechanical properties of the PU elastic concrete are evaluated.The performance of the proposed structure is investigated using a three-dimensional finite element model,where vehicleinduced dynamic and static loads are considered.The results show that PU elastic concrete and the proposed combined TRTP are applicable and functioned as intended.Additionally,the PU elastic concrete achieved sufficient performance.The recommended width of the TRTP is approximately 50 mm.Meanwhile,the application of UHPC under a PU elastic concrete layer significantly reduces vertical deformation.Results of numerical calculations confirmed the high structural performance and feasibility of the proposed TRTP.Finally,material performance standards are recommended to provide guidance for pavement design and the construction of tram-grade crossings in the future.
文摘文中以医用级高分子聚氨酯(TPU)为原材料,通过热压成型制备厚1.2 mm TPU片材,并制取75×4哑铃型拉伸试样。在电子万能试验机上以较高的恒定拉伸速率进行拉伸,预先设定应力到某一设定值后停止拉伸,然后应力以一定速度进行减载。实验探索了整个拉伸-回复循环中应力与应变的关系,研究了拉伸速度对医用级TPU拉伸强度及断裂伸长率的影响,并对拉伸过程中出现应力发白现象进行探究。结果表明,TPU是一种强而韧的硬弹性高分子材料,在高应力大形变下由弹性提供的可逆形变约80%,粘性提供的不可逆形变约20%。在高应力下材料内部孔洞尺寸变大,由此引起材料由透明转而发白,此光学现象可反复发生。
