The gasification characteristics and gasification kinetics of coke in complex CO2/CO/H2/H2O/N2 systems similar to the gas system of industrial blast furnace (BF) were studied by the method of isothermal thermogravimet...The gasification characteristics and gasification kinetics of coke in complex CO2/CO/H2/H2O/N2 systems similar to the gas system of industrial blast furnace (BF) were studied by the method of isothermal thermogravimetric analysis. The experimental gas compositions and the corresponding temperature were chosen according to data reported for industrial BFs. The gasification behavior of coke was described by the Random Pore Model (RPM), Volumetric Model (VM), and Grain Model (GM). Results showed that the gas composition of the coke gasification zone in BF changes slightly and that the temperature is the most important factor affecting coke gasification. The lower activation energy of coke samples (Coke Reaction Index (CRI)>50) is due to the high Fe2O3 in the ash, lower degree of graphitization, and larger pore structure. In addition, the choice of kinetic model does not differ substantially in describing the gasification mechanism of coke in a BF.展开更多
Coal is the primary fossil fuel most used in the world for the electricity generation, iron making, and cement/concrete and chemical production. However, utilization of coal also results in emissions of CO_2, SO_x, NO...Coal is the primary fossil fuel most used in the world for the electricity generation, iron making, and cement/concrete and chemical production. However, utilization of coal also results in emissions of CO_2, SO_x, NO_x and other noxious compounds. The development of clean coal technology(CCT) is a main issue to maintain a clean environment. CCT in Japan is considered the highest level in the world. In this review, the developing CCTs in Japan including high efficiency combustion technologies, advanced gasification technologies, CO_2 recovery and utilization technologies, and flue gas cleaning technologies are introduced and discussed. It is expected to provide some new view-of-points for CCT development.展开更多
基金financially supported by the National Key Research and Development Program of China (Nos. 2017YFB0304300 and 2017YFB0304303)the National Science Foundation of China (No. 51774032)the Chinese Fundamental Research Funds for the Central Universities (No. FRF-TP-17-086A1)
文摘The gasification characteristics and gasification kinetics of coke in complex CO2/CO/H2/H2O/N2 systems similar to the gas system of industrial blast furnace (BF) were studied by the method of isothermal thermogravimetric analysis. The experimental gas compositions and the corresponding temperature were chosen according to data reported for industrial BFs. The gasification behavior of coke was described by the Random Pore Model (RPM), Volumetric Model (VM), and Grain Model (GM). Results showed that the gas composition of the coke gasification zone in BF changes slightly and that the temperature is the most important factor affecting coke gasification. The lower activation energy of coke samples (Coke Reaction Index (CRI)>50) is due to the high Fe2O3 in the ash, lower degree of graphitization, and larger pore structure. In addition, the choice of kinetic model does not differ substantially in describing the gasification mechanism of coke in a BF.
文摘Coal is the primary fossil fuel most used in the world for the electricity generation, iron making, and cement/concrete and chemical production. However, utilization of coal also results in emissions of CO_2, SO_x, NO_x and other noxious compounds. The development of clean coal technology(CCT) is a main issue to maintain a clean environment. CCT in Japan is considered the highest level in the world. In this review, the developing CCTs in Japan including high efficiency combustion technologies, advanced gasification technologies, CO_2 recovery and utilization technologies, and flue gas cleaning technologies are introduced and discussed. It is expected to provide some new view-of-points for CCT development.
