A recently developed advanced hot-formed （AHF） steel for automobile is introduced and three physical metallurgy concepts based on which the AHF steel was designed are reviewed, they are dynamic carbon partitioning ...A recently developed advanced hot-formed （AHF） steel for automobile is introduced and three physical metallurgy concepts based on which the AHF steel was designed are reviewed, they are dynamic carbon partitioning （DCP）, flash copper precipitation and bake toughening. AHF steel is an upgrade of the existing hot-formed steel especially suitable for making components with superior crashworthiness; it can be processed by regular hot stamping equipment and process. A kinetics model for DCP is expressed in detail, which can be used to calculate the volume fraction of retained austenite based on four materials and processing parameters. The flash copper precipitation used as an additional strengthening mechanism for AHF steel is also discussed and its ultrafast kinetics can be attributed to the enhancement of quenched-in vacancies on copper diffusion. Also, the bake toughening of AHF steel is addressed; the mechanism of which may be related to the elimination of the less stable block-like retained austenite.展开更多
Platinum-group elements （PGE） in PGE-rich porphyry copper （gold） deposits are mainly Pt and Pd, whereas the concentrations of other PGE （Ru, Rh, Os, Ir） are significantly low. Moreover, Pt and Pd mainly exist in...Platinum-group elements （PGE） in PGE-rich porphyry copper （gold） deposits are mainly Pt and Pd, whereas the concentrations of other PGE （Ru, Rh, Os, Ir） are significantly low. Moreover, Pt and Pd mainly exist in sulfides in the forms of crystal lattice or tiny platinum-group mineral （PGM） inclusions. The present data show that there is a positive relationship between Pt and Pd concentrations and Cu （Au） in porphyry copper （gold） deposits. The comparison of chondrite-normalized PGE distribution patterns between the ore-bearing porphyry intrusions and ore-barren porphyry intrusions in arc setting, 187^Os/188^Os, 87^Sr/86^Sr and S isotopes for porphyry copper （gold） deposits shows that PGEs were mainly derived from the mantle, and fluids from subduction zones devoted trivial PGE to the magma. The porphyry copper （gold） deposits associated with subducted events are most probably enriched in PGE, whereas those related to crustal thickening, lithospheric delamination or underplating rarely concentrate PGE. The osmium isotopic compositions in porphyry copper （gold） deposits reveal that （187^Os/188^Os）i values are highly variable and not lower than those of primitive upper mantle （PUM） and mantle peridotite, however, osmium concentrations are commonly lower than mantle peridotite, suggesting that parental magmas of some porphyry intrusions had experienced crustal contamination during magma evolution. Experimental investigations have proved that PGE exist in the forms of Cl^- and HS^- complexes during transportation and migration of the oreforming fluids. This paper summarizes previous studies including crucial controlling factors and mechanisms for PGE enrichment, and points out that the mantle-derived magmas parental to porphyry intrusions are the prerequisite for PGE enrichment in porphyry copper （gold） deposits. Favorable physical and chemical conditions （including salinity, temperature, pressure, pH, and oxygen fugacity） in hydrothermal fluids crucially control the 展开更多
基金supported by the National Natural Science Foundation of China (No. 51034009)
文摘A recently developed advanced hot-formed （AHF） steel for automobile is introduced and three physical metallurgy concepts based on which the AHF steel was designed are reviewed, they are dynamic carbon partitioning （DCP）, flash copper precipitation and bake toughening. AHF steel is an upgrade of the existing hot-formed steel especially suitable for making components with superior crashworthiness; it can be processed by regular hot stamping equipment and process. A kinetics model for DCP is expressed in detail, which can be used to calculate the volume fraction of retained austenite based on four materials and processing parameters. The flash copper precipitation used as an additional strengthening mechanism for AHF steel is also discussed and its ultrafast kinetics can be attributed to the enhancement of quenched-in vacancies on copper diffusion. Also, the bake toughening of AHF steel is addressed; the mechanism of which may be related to the elimination of the less stable block-like retained austenite.
基金Supported by the Teaching and Research Award Program for Outstanding Young Teachersin Higher Educations of MOE,P.R.C(TRAPOYT,No.2002-40),the Science Fund for Distinguished Overseas Chinese Scholars of MOP,P.R.C(SFDOCS,No.2003-50)and the Guizhou Governor’s Foundation for Outstanding Scientistsin Science,Technology and Education(GFOSTE,No.2003-04)
基金supported by the 12th Five-Year Plan project of State Key Laboratory of Ore Deposit Geochemistry,Chinese Academy of Sciences(SKLOG-ZY125-06)the Knowledge Innovation Project,Chinese Academic Sciences(KZCX2-YW-136-1)
文摘Platinum-group elements （PGE） in PGE-rich porphyry copper （gold） deposits are mainly Pt and Pd, whereas the concentrations of other PGE （Ru, Rh, Os, Ir） are significantly low. Moreover, Pt and Pd mainly exist in sulfides in the forms of crystal lattice or tiny platinum-group mineral （PGM） inclusions. The present data show that there is a positive relationship between Pt and Pd concentrations and Cu （Au） in porphyry copper （gold） deposits. The comparison of chondrite-normalized PGE distribution patterns between the ore-bearing porphyry intrusions and ore-barren porphyry intrusions in arc setting, 187^Os/188^Os, 87^Sr/86^Sr and S isotopes for porphyry copper （gold） deposits shows that PGEs were mainly derived from the mantle, and fluids from subduction zones devoted trivial PGE to the magma. The porphyry copper （gold） deposits associated with subducted events are most probably enriched in PGE, whereas those related to crustal thickening, lithospheric delamination or underplating rarely concentrate PGE. The osmium isotopic compositions in porphyry copper （gold） deposits reveal that （187^Os/188^Os）i values are highly variable and not lower than those of primitive upper mantle （PUM） and mantle peridotite, however, osmium concentrations are commonly lower than mantle peridotite, suggesting that parental magmas of some porphyry intrusions had experienced crustal contamination during magma evolution. Experimental investigations have proved that PGE exist in the forms of Cl^- and HS^- complexes during transportation and migration of the oreforming fluids. This paper summarizes previous studies including crucial controlling factors and mechanisms for PGE enrichment, and points out that the mantle-derived magmas parental to porphyry intrusions are the prerequisite for PGE enrichment in porphyry copper （gold） deposits. Favorable physical and chemical conditions （including salinity, temperature, pressure, pH, and oxygen fugacity） in hydrothermal fluids crucially control the
