A series of fluorotellurite glasses based on（81–x）Te O2-（10＋x）KF-9La2O3（TKL）, where x=0 mol.%, 5 mol.%, 10 mol.%, 15 mol.%, doped with 2000 ppm Tm2O3, were prepared by the conventional melt quenching method.Th...A series of fluorotellurite glasses based on（81–x）Te O2-（10＋x）KF-9La2O3（TKL）, where x=0 mol.%, 5 mol.%, 10 mol.%, 15 mol.%, doped with 2000 ppm Tm2O3, were prepared by the conventional melt quenching method.The influence of KF content on the thermal stability and optical spectroscopic properties of the Tm3＋ doped fluorotellurite glasses were investigated by differential scanning calorimetry（DSC）, X-ray diffraction（XRD）, density measurement, Fourier transform infrared spectroscopy（FTIR）, UV-VIS-NIR optical spectroscopy and fluorescence spectroscopy.Judd-Ofelt intensity parameters of Tm3＋ in as-prepared glasses were determined and used to calculate the spontaneous emission probabilities and the radiative lifetime for the 4f-4f transitions of the Tm3＋ ions.Stimulated emission cross sections in the 1470 nm region（σse） were evaluated by Füchtbauer-Ladenburg formula.The results showed that KF substitution of Te O2 was beneficial to improving the thermal stability, decreasing glass density and reducing the content of OH related groups for the investigated fluorotellurite glasses.The glass with composition of 66 Te O2-25KF-9La2O3（named TKL25） had the longest radiative lifetime of the 3H4（361 μs） and the largest FWHM×σse value（420.07×10–28 cm3）, which made it a promising material for S-band fiber amplifiers.展开更多
利用重复频率为1 k Hz,中心波长为800 nm,脉冲宽度为120 fs的超短脉冲激光在掺Er3+"无水"氟碲酸盐玻璃中利用狭缝整形技术横向刻写了I类和压低圆包层波导。在对波导刻写参数进行系统研究后,得到了两组导光模式较优的波导。利...利用重复频率为1 k Hz,中心波长为800 nm,脉冲宽度为120 fs的超短脉冲激光在掺Er3+"无水"氟碲酸盐玻璃中利用狭缝整形技术横向刻写了I类和压低圆包层波导。在对波导刻写参数进行系统研究后,得到了两组导光模式较优的波导。利用波导的近场模式强度分布重构了其折射率分布图,得到两类波导最大的折射率增加量分别为1×10-4和1.9×10-4。用散射法测试了I类波导的传输损耗为1.04 d B/cm;通过测量插入损耗得到压低圆包层波导的传输损耗小于1.88 d B/cm。因此,利用飞秒激光在掺Er3+"无水"氟碲酸盐玻璃中刻写的光波导,在集成激光光源制作方面具有很好的应用前景。展开更多
基金Project supported by Hunan Provincial Natural Science Foundation of China(2015JJ3004)National Natural Science Foundation of China(21276028)
文摘A series of fluorotellurite glasses based on（81–x）Te O2-（10＋x）KF-9La2O3（TKL）, where x=0 mol.%, 5 mol.%, 10 mol.%, 15 mol.%, doped with 2000 ppm Tm2O3, were prepared by the conventional melt quenching method.The influence of KF content on the thermal stability and optical spectroscopic properties of the Tm3＋ doped fluorotellurite glasses were investigated by differential scanning calorimetry（DSC）, X-ray diffraction（XRD）, density measurement, Fourier transform infrared spectroscopy（FTIR）, UV-VIS-NIR optical spectroscopy and fluorescence spectroscopy.Judd-Ofelt intensity parameters of Tm3＋ in as-prepared glasses were determined and used to calculate the spontaneous emission probabilities and the radiative lifetime for the 4f-4f transitions of the Tm3＋ ions.Stimulated emission cross sections in the 1470 nm region（σse） were evaluated by Füchtbauer-Ladenburg formula.The results showed that KF substitution of Te O2 was beneficial to improving the thermal stability, decreasing glass density and reducing the content of OH related groups for the investigated fluorotellurite glasses.The glass with composition of 66 Te O2-25KF-9La2O3（named TKL25） had the longest radiative lifetime of the 3H4（361 μs） and the largest FWHM×σse value（420.07×10–28 cm3）, which made it a promising material for S-band fiber amplifiers.
文摘利用重复频率为1 k Hz,中心波长为800 nm,脉冲宽度为120 fs的超短脉冲激光在掺Er3+"无水"氟碲酸盐玻璃中利用狭缝整形技术横向刻写了I类和压低圆包层波导。在对波导刻写参数进行系统研究后,得到了两组导光模式较优的波导。利用波导的近场模式强度分布重构了其折射率分布图,得到两类波导最大的折射率增加量分别为1×10-4和1.9×10-4。用散射法测试了I类波导的传输损耗为1.04 d B/cm;通过测量插入损耗得到压低圆包层波导的传输损耗小于1.88 d B/cm。因此,利用飞秒激光在掺Er3+"无水"氟碲酸盐玻璃中刻写的光波导,在集成激光光源制作方面具有很好的应用前景。
