The three-dimensional interactions of a perturbed premixed flame interface with a planar incident shock wave and its reflected shock waves are numerically simulated by solving the compressible,reactive Navier-Stokes e...The three-dimensional interactions of a perturbed premixed flame interface with a planar incident shock wave and its reflected shock waves are numerically simulated by solving the compressible,reactive Navier-Stokes equations with the high-resolution scheme and a single-step chemical reaction.The effects of the initial incident shock wave strength (Mach number) and the initial perturbation pattern of interface on the interactions are investigated.The distinct properties of perturbation growth on the flame interface during the interactions are presented.Our results show that perturbation growth is mainly attributed to the flame stretching and propagation.The flame stretching is associated with the larger-scale vortical flow due to RichtmyerMeshkov instability while the flame propagation is due to the chemical reaction.The mixing properties of unburned/burned gases on both sides of the flame are quantitatively analyzed by using integral and statistical diagnostics.The results show that the large-scale flow due to the vortical motion always plays a dominating role during the reactive interaction process;however,the effect of chemistry becomes more important at the later stage of the interactions,especially for higher Mach number cases.The scalar dissipation due to the molecular diffusion is always small in the present study and can be negligible.展开更多
Multi-stage ignition and/or double NTC(negative temperature coefficient)behavior resulted from the low-temperature oxidation of ether compounds are still not clearly explained.We have investigated the oxidation mechan...Multi-stage ignition and/or double NTC(negative temperature coefficient)behavior resulted from the low-temperature oxidation of ether compounds are still not clearly explained.We have investigated the oxidation mechanism of a stoichiometric DEE(diethyl ether)/air mixture by using a micro flow reactor with a controlled temperature profile to see the detail of low-temperature weak flame structure.The simulation was also performed to understand the chemical kinetics mechanism of observed weak flame structure.Chemiluminescence measurement showed separated weak flame in the temperature range of 600 K-800 K.The simulation also qualitatively reproduced this separated weak flame,and showed four peak of heat release.From the reaction flow analysis,it was found that(1)O-O bond scission reaction of keto-hydroperoxide produced by DEE,(2)O-O bond scission reaction of CH3O2H,CH3CO3H,and C2H5O2H,(3)O-O bond scission reaction of H2O2,and(4)H+O2=O+OH are key chain branching reactions to explain the multi-stage oxidation.展开更多
基金The work was supported by the National Natural Science Foundation of China(11372140).
文摘The three-dimensional interactions of a perturbed premixed flame interface with a planar incident shock wave and its reflected shock waves are numerically simulated by solving the compressible,reactive Navier-Stokes equations with the high-resolution scheme and a single-step chemical reaction.The effects of the initial incident shock wave strength (Mach number) and the initial perturbation pattern of interface on the interactions are investigated.The distinct properties of perturbation growth on the flame interface during the interactions are presented.Our results show that perturbation growth is mainly attributed to the flame stretching and propagation.The flame stretching is associated with the larger-scale vortical flow due to RichtmyerMeshkov instability while the flame propagation is due to the chemical reaction.The mixing properties of unburned/burned gases on both sides of the flame are quantitatively analyzed by using integral and statistical diagnostics.The results show that the large-scale flow due to the vortical motion always plays a dominating role during the reactive interaction process;however,the effect of chemistry becomes more important at the later stage of the interactions,especially for higher Mach number cases.The scalar dissipation due to the molecular diffusion is always small in the present study and can be negligible.
基金supported by JSPS KAKENHI Grant Number JP16K06112Collaborative Research Project of the Institute of Fluid Science,Tohoku University。
文摘Multi-stage ignition and/or double NTC(negative temperature coefficient)behavior resulted from the low-temperature oxidation of ether compounds are still not clearly explained.We have investigated the oxidation mechanism of a stoichiometric DEE(diethyl ether)/air mixture by using a micro flow reactor with a controlled temperature profile to see the detail of low-temperature weak flame structure.The simulation was also performed to understand the chemical kinetics mechanism of observed weak flame structure.Chemiluminescence measurement showed separated weak flame in the temperature range of 600 K-800 K.The simulation also qualitatively reproduced this separated weak flame,and showed four peak of heat release.From the reaction flow analysis,it was found that(1)O-O bond scission reaction of keto-hydroperoxide produced by DEE,(2)O-O bond scission reaction of CH3O2H,CH3CO3H,and C2H5O2H,(3)O-O bond scission reaction of H2O2,and(4)H+O2=O+OH are key chain branching reactions to explain the multi-stage oxidation.
