Carbon fiber yarns（CFY） are promising as a new type of flexible building blocks for the construction of flexible architectures for the energy storage applications. The main hurdle with CFY is how to make them high e...Carbon fiber yarns（CFY） are promising as a new type of flexible building blocks for the construction of flexible architectures for the energy storage applications. The main hurdle with CFY is how to make them high energy and power capable by using economically and environmentally viable materials. Here,we report reduced graphene oxide（r GO） and Prussian blue（PB） coated CFY, derived from a facile electrochemical process at room temperature for supercapacitor electrodes. The PB coated CFY and r GO coated CFY electrodes exhibit the excellent gravimetric capacitance of 339 F/g and 160.2 F/g, respectively, in aqueous KCl electrolyte in three-electrode cell configuration. When we coupled these electrodes inside the flexible plastic tube and separated by the electrolyte wet filter paper in order to construct flexible architecture, the resulting device delivers excellent specific energy of 52.1 Wh/kg and 26.5 Wh/kg with offering specific power of 3100 W/kg and 14400 W/kg respectively, under a wide operating potential of1.8 V with excellent rate capability. The device shows high tolerance towards bending, and retained its efficiency to the capacitance after being bent at an angle of 360° for 200 bending cycles.展开更多
As a promising candidate for future demand, fiber-shaped electrochemical energy storage devices, such as supercapacitors and lithium-ion batteries have obtained considerable attention from academy to industry. Carbon ...As a promising candidate for future demand, fiber-shaped electrochemical energy storage devices, such as supercapacitors and lithium-ion batteries have obtained considerable attention from academy to industry. Carbon nanomaterials, such as carbon nanotube and graphene, have been widely investigated as electrode materials due to their merits of light weight, flexibility and high capacitance. In this review, recent progress of carbon nanomaterials in flexible fiber-shaped energy storage devices has been summarized in accordance with the development of fibrous electrodes, including the diversified electrode preparation, functional and intelligent device structure, and large-scale production of fibrous electrodes or devices.展开更多
基金CNPq, Govt. of Brazil for providing financial support under the scheme of Science without Border to carry out this research work
文摘Carbon fiber yarns（CFY） are promising as a new type of flexible building blocks for the construction of flexible architectures for the energy storage applications. The main hurdle with CFY is how to make them high energy and power capable by using economically and environmentally viable materials. Here,we report reduced graphene oxide（r GO） and Prussian blue（PB） coated CFY, derived from a facile electrochemical process at room temperature for supercapacitor electrodes. The PB coated CFY and r GO coated CFY electrodes exhibit the excellent gravimetric capacitance of 339 F/g and 160.2 F/g, respectively, in aqueous KCl electrolyte in three-electrode cell configuration. When we coupled these electrodes inside the flexible plastic tube and separated by the electrolyte wet filter paper in order to construct flexible architecture, the resulting device delivers excellent specific energy of 52.1 Wh/kg and 26.5 Wh/kg with offering specific power of 3100 W/kg and 14400 W/kg respectively, under a wide operating potential of1.8 V with excellent rate capability. The device shows high tolerance towards bending, and retained its efficiency to the capacitance after being bent at an angle of 360° for 200 bending cycles.
基金supported by the National Natural Science Foundation of China(Nos.21634003,21604012)
文摘As a promising candidate for future demand, fiber-shaped electrochemical energy storage devices, such as supercapacitors and lithium-ion batteries have obtained considerable attention from academy to industry. Carbon nanomaterials, such as carbon nanotube and graphene, have been widely investigated as electrode materials due to their merits of light weight, flexibility and high capacitance. In this review, recent progress of carbon nanomaterials in flexible fiber-shaped energy storage devices has been summarized in accordance with the development of fibrous electrodes, including the diversified electrode preparation, functional and intelligent device structure, and large-scale production of fibrous electrodes or devices.
