The developed SEMK model is used to provide an insight into the contribution of individual reactions in the cracking of methylcyclohexane as well as the site coverage by various carbenium ions. The preferred reaction ...The developed SEMK model is used to provide an insight into the contribution of individual reactions in the cracking of methylcyclohexane as well as the site coverage by various carbenium ions. The preferred reaction pathways for the conversion of methylcyclohexane are hydride transfer reactions followed by PCP-isomerizations, deprotonation and endocyclic β-scission, accounting for 61%, 22% and 12% of its disappearance, respectively, at 693 K and 30% conversion of methylcyclohexane. Protolysis plays a minor role in the cracking of methylcyclohexane. Once cyclic diolefins are formed, all of them can be instantaneously transformed to aromatics, which are easily interconverted via disproportionation. Judging from the carbenium ion concentrations it is evident that, at the investigated operating conditions, less than 5% of the acid sites are covered by carbenium ions, less than 2% of which corresponds to cyclic type species including allylic ones.展开更多
The spatiotemporal variations of the site and regional droughts in China during 1960–2009 were analyzed by applying a daily composite-drought index （CDI） to 722 stations in China's Mainland. Droughts frequently...The spatiotemporal variations of the site and regional droughts in China during 1960–2009 were analyzed by applying a daily composite-drought index （CDI） to 722 stations in China's Mainland. Droughts frequently happened in a zone extended from Southwest China to the Yellow River, North China, and the southwestern part of Northeast China, with two centers of high frequency in North China and Southwest China. In Southwest and South China, droughts tend to happen during the winter. In North China and along the Yellow River, droughts mainly occur during the winter and during May–June. During the past 50 years, the geographical distribution of site drought events showed high frequencies （0.9–1.3 times per year） in the upper Yellow River basin and North China, comparing with moderate frequencies （0.6–0.9 times per year） in Southwest China and the southwestern part of Northeast China and with lower frequencies over the middle and lower Yangtze River basin. And the frequencies increased over China's Mainland except for the upper reaches of the Yangtze River. A regional drought （RD） event is a widespread and persistent event that covers at least five adjacent sites and lasts for at least 10 days. There were 252 RD events in the past 50 years—five times per year. Most RD events lasted for 100 days and covered 100 stations, but the longest and largest RD event lasted for 307 days from 6 September 1998 to 9 July 1999 and covered 327 stations from North to Southwest China.展开更多
基金the financial support from the China Scholarship Councilthe Long Term Structural Methusalem Funding by the Flemish Government
文摘The developed SEMK model is used to provide an insight into the contribution of individual reactions in the cracking of methylcyclohexane as well as the site coverage by various carbenium ions. The preferred reaction pathways for the conversion of methylcyclohexane are hydride transfer reactions followed by PCP-isomerizations, deprotonation and endocyclic β-scission, accounting for 61%, 22% and 12% of its disappearance, respectively, at 693 K and 30% conversion of methylcyclohexane. Protolysis plays a minor role in the cracking of methylcyclohexane. Once cyclic diolefins are formed, all of them can be instantaneously transformed to aromatics, which are easily interconverted via disproportionation. Judging from the carbenium ion concentrations it is evident that, at the investigated operating conditions, less than 5% of the acid sites are covered by carbenium ions, less than 2% of which corresponds to cyclic type species including allylic ones.
基金supported jointly bythe National Natural Science Foundation of China (GrantNo. 40975039)the Key Technologies R&D Program(Grant No. 2009BAC51B04)+1 种基金the Chinese COPES Project (Grant No. GYHY201006018)The CDI data was provided by the Key Technologies R&D Program (GrantNo. 2007BAC29B06).
文摘The spatiotemporal variations of the site and regional droughts in China during 1960–2009 were analyzed by applying a daily composite-drought index （CDI） to 722 stations in China's Mainland. Droughts frequently happened in a zone extended from Southwest China to the Yellow River, North China, and the southwestern part of Northeast China, with two centers of high frequency in North China and Southwest China. In Southwest and South China, droughts tend to happen during the winter. In North China and along the Yellow River, droughts mainly occur during the winter and during May–June. During the past 50 years, the geographical distribution of site drought events showed high frequencies （0.9–1.3 times per year） in the upper Yellow River basin and North China, comparing with moderate frequencies （0.6–0.9 times per year） in Southwest China and the southwestern part of Northeast China and with lower frequencies over the middle and lower Yangtze River basin. And the frequencies increased over China's Mainland except for the upper reaches of the Yangtze River. A regional drought （RD） event is a widespread and persistent event that covers at least five adjacent sites and lasts for at least 10 days. There were 252 RD events in the past 50 years—five times per year. Most RD events lasted for 100 days and covered 100 stations, but the longest and largest RD event lasted for 307 days from 6 September 1998 to 9 July 1999 and covered 327 stations from North to Southwest China.
