Considering the emergence of severe electromagnetic interference problems,it is vital to develop electromagnetic(EM)wave absorbing materials with high dielectric,magnetic loss and optimized impedance matching.However,...Considering the emergence of severe electromagnetic interference problems,it is vital to develop electromagnetic(EM)wave absorbing materials with high dielectric,magnetic loss and optimized impedance matching.However,realizing the synergistic dielectric and magnetic losses in a single phase material is still a challenge.Herein,high entropy(HE)rare earth hexaborides(REB6)powders with coupling of dielectric and magnetic losses were designed and successfully synthesized through a facial one-step boron carbide reduction method,and the effects of high entropy borates intermedia phases on the EM wave absorption properties were investigated.Five HE REB6 ceramics including(Ce0.2Y0.2Sm0.2Er0.2Yb0.2)B6,(Ce0.2Hu0.2Sm0.2Er0.2Yb0.2)B6,(Ce0.2Y0.2Eu0.2Er0.2Yb0.2)B6,(Ce0.2Ya2Sm0.2Eu0.2Yb0.2)B6,and(Nd0.2Y0.2Sm0.2Eu0.2Yb0.2)B6 possess CsCl-type cubic crystal structure,and their theoretical densities range from 4.84 to 5.25 g/cm^(3).(Ce02Y0.2Sm0.2Er0.2Yb02)B6 powders with the average particle size of 1.86 jim were found to possess the best EM wave absorption properties among these hexaborides.The RLmin value of(Ce0.2Y0.2Sm0.2Er0.2Yb0.2)B6 reaches-33.4 dB at 11.5 GHz at thickness of 2 mm;meanwhile,the optimized effective absorption bandwidth(EAB)is 3.9 GHz from 13.6 to 17.5 GHz with a thickness of 1.5 mm.The introduction of HE REB03(RE=Ce,Y,Sm,Eu,Er,Yb)as intermediate phase will give rise to the mismatching impedance,which will further lead to the reduction of reflection loss.Intriguingly,the HEREB6/HEREB03 still possess wide effective absorption bandwidth of 4.1 GHz with the relative low thickness of 1.7 mm.Considering the better stability,low density,and good EM wave absorption properties,HE REB6 ceramics are promising as a new type of EM wave absorbing materials.展开更多
Based on the maximum entropy principle, a probability density function (PDF) is derived for the distribution of wave heights in a random wave field, without any more hypothesis. The present PDF, being a non-Rayleigh f...Based on the maximum entropy principle, a probability density function (PDF) is derived for the distribution of wave heights in a random wave field, without any more hypothesis. The present PDF, being a non-Rayleigh form, involves two parameters: the average wave height H— and the state parameter γ. The role of γ in the distribution of wave heights is examined. It is found that γ may be a certain measure of sea state. A least square method for determining γ from measured data is proposed. In virtue of the method, the values of γ are determined for three sea states from the data measured in the East China Sea. The present PDF is compared with the well known Rayleigh PDF of wave height and it is shown that it much better fits the data than the Rayleigh PDF. It is expected that the present PDF would fit some other wave variables, since its derivation is not restricted only to the wave height.展开更多
The increasing electromagnetic hazards including electromagnetic interference and electromagnetic pollution,which were stemmed from massive usage of electromagnetic technology,have triggered widespread concerns.To cop...The increasing electromagnetic hazards including electromagnetic interference and electromagnetic pollution,which were stemmed from massive usage of electromagnetic technology,have triggered widespread concerns.To cope with this challenge,electromagnetic wave absorbing materials with high performance are greatly needed.Composite construction has been widely applied in electromagnetic(EM)wave absorbing materials to achieve high permittivity,high permeability and impedance matching.However,high-temperature stability,oxidation and corrosion resistance are still unignorable issues.Herein,high entropy hexaborides/tetraborides(HE REB_(6)/HE REB_(4))composites with synergistic dielectric and magnetic losses were designed and successfully synthesized through a one-step boron carbide reduction method.The five as-prepared(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(4),(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(4),(Y_(0.2) Nd_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(4),(Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(4) and(Y_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(4) contain two phases of HE REB_(6) and HE REB_(4).Among them(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(4)(HE REB_(6)/HE REB_(4)-1)and(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(4)(HE REB_(6)/HE REB_(4)-2)exhibit excellent EM wave absorption properties.The optimal minimum reflection loss(RL_(m in))and effective absorption bandwidth(E_(AB))of HE REB_(6)/HE REB_(4)-1 and HE REB_(6)/HE REB_(4)-2 are–53.3 dB(at 1.7 mm),4.2 GHz(at 1.5 mm)and–43.5 dB(1.3 mm),4.2 GHz(1.5 mm),respectively.The combination of conducting HE REB_(4) with magnetism into HE REB_(6) as a second phase enhances dielectric an展开更多
Rational designing of one-dimensional(1D)magnetic alloy to facilitate electromagnetic(EM)wave attenuation capability in low-frequency(2-6 GHz)microwave absorption field is highly desired but remains a significant chal...Rational designing of one-dimensional(1D)magnetic alloy to facilitate electromagnetic(EM)wave attenuation capability in low-frequency(2-6 GHz)microwave absorption field is highly desired but remains a significant challenge.In this study,a composite EM wave absorber made of a FeCoNi medium-entropy alloy embedded in a 1D carbon matrix framework is rationally designed through an improved electrospinning method.The 1D-shaped FeCoNi alloy embedded composite demonstrates the high-density and continuous magnetic network using off-axis electronic holography technique,indicating the excellent magnetic loss ability under an external EM field.Then,the in-depth analysis shows that many factors,including 1D anisotropy and intrinsic physical features of the magnetic medium-entropy alloy,primarily contribute to the enhanced EM wave absorption performance.Therefore,the fabricated EM wave absorber shows an increasing effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm.Thus,this study opens up a new method for the design and preparation of high-performance 1D magnetic EM absorbers.展开更多
We are concerned with the stability of steady multi-wave configurations for the full Euler equations of compressible fluid flow. In this paper, we focus on the stability of steady four-wave configurations that are the...We are concerned with the stability of steady multi-wave configurations for the full Euler equations of compressible fluid flow. In this paper, we focus on the stability of steady four-wave configurations that are the solutions of the Riemann problem in the flow direction, consisting of two shocks, one vortex sheet, and one entropy wave, which is one of the core multi-wave configurations for the two-dimensional Euler equations. It is proved that such steady four-wave configurations in supersonic flow are stable in structure globally, even under the BV perturbation of the incoming flow in the flow direction. In order to achieve this, we first formulate the problem as the Cauchy problem （initial value problem） in the flow direction, and then develop a modified Glimm difference scheme and identify a Glimm-type functional to obtain the required BV estimates by tracing the interactions not only between the strong shocks and weak waves, but also between the strong vortex sheet/entropy wave and weak waves. The key feature of the Euler equations is that the reflection coefficient is always less than 1, when a weak wave of different family interacts with the strong vortex sheet/entropy wave or the shock wave, which is crucial to guarantee that the Glimm functional is decreasing. Then these estimates are employed to establish the convergence of the approximate solutions to a global entropy solution, close to the background solution of steady four-wave configuration.展开更多
Herein,a novel kind of high-entropy MAX phases,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders were success-fully synthesized by a newly proposed two-step solid state reaction process.The oxidation experiments...Herein,a novel kind of high-entropy MAX phases,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders were success-fully synthesized by a newly proposed two-step solid state reaction process.The oxidation experiments demonstrate that the oxidation products of Al_(2)Mo_(3)O_(12) and rutile TiO 2 are formed at about 600 and 800℃,respectively.Besides,the dielectric and electromagnetic(EM)wave absorption properties of(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders and those after oxidation at different temperatures were also exam-ined.The results show that the as-synthesized(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders possess excellent EM wave absorption performances with the minimum reflection loss(RL)of-45.80 dB(at 1.7 mm thickness)and the maximum effective absorption bandwidth(E AB)of 3.6 GHz(at 1.5 mm thickness).After oxidation at 400-800℃,due to the coupling of conductivity loss and polarization loss,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders can retain good EM wave absorption properties in a certain frequency range.In this paper,the effects of oxidation on EM wave absorption properties of high-entropy MAX phases were systematically investigated for the first time.This work manifests that high-entropy MAX phases are promising EM wave absorbing candidates and can maintain good EM wave absorption performances after oxidation.展开更多
Perovskite-type rare-earth ferrites(REFeO_(3))are promising materials for absorbing electromagnetic(EM)wave pollution.However,insufficient dielectric loss and poor impedance matching are key factors that limit the bro...Perovskite-type rare-earth ferrites(REFeO_(3))are promising materials for absorbing electromagnetic(EM)wave pollution.However,insufficient dielectric loss and poor impedance matching are key factors that limit the broader implementation of REFeO_(3).Herein,a series of multicomponent perovskite-type ferrites with strong EM wave absorption capabilities was prepared.Through the synergistic effect of chemical constitution regulation and entropy regulation,optimization of the dielectric loss and impedance matching is achieved by strengthening the structural defect mechanism,thus further adjusting the EM wave absorption performance.Compared with(LaGdSmNdBa)FeO_(3)(HE-1)and(LaGdPrSmNdBa)FeO_(3)(HE-2),(LaGdBa)FeO_(3)(ME-1)and(LaGdSmBa)FeO_(3)(ME-2)exhibit favorable performance,with optimal minimum reflection loss(RL_(min))of-56.35 dB(at 11.12 GHz)and-63.25 dB(at 7.22 GHz)and effective absorption bandwidth(EAB)of 4.46 and 4.72 GHz,respectively.This multicomponent design provides a new strategy for the development of EM wave absorption materials.展开更多
Here we report a TiHfNbTa bulk medium-entropy alloy(MEA)superconductor crystallized in the body-centered cubic structure with the unit cell parameter a=3.35925?,which is synthesized by an arc melting method.Supercondu...Here we report a TiHfNbTa bulk medium-entropy alloy(MEA)superconductor crystallized in the body-centered cubic structure with the unit cell parameter a=3.35925?,which is synthesized by an arc melting method.Superconducting properties of the TiHfNbTa are studied by employing magnetic susceptibility,resistivity,and specific heat measurements.Experimental results show a bulk superconducting transition temperature(Tc)of around 6.75 K.The lower and upper critical fields for TiHfNbTa are45.8 m T and 10.46 T,respectively.First-principles calculations show that the d electrons of Ti,Hf,Nb,and Ta are the main contribution to the total density of states near the Fermi level.Our results indicate that the superconductivity is a conventional swave type with extremely strong coupling(△C_(el)/γ_(n)T_(c)=2.88,2△_(0)/k_(B)T_(c)=5.02,and λ_(ep)=2.77).The extremely strong coupling behavior in the s-wave type Ti Hf Nb Ta MEA superconductor is unusual because it generally happens in cuprates,pnictides,and other unconventional superconductors.展开更多
This paper introduces the refrigeration cycle process of the gas wave oscillation tube(GWOT).Aiming at the problem that the strong reverse compression waves generated during the refrigeration process affect the perfor...This paper introduces the refrigeration cycle process of the gas wave oscillation tube(GWOT).Aiming at the problem that the strong reverse compression waves generated during the refrigeration process affect the performance,this paper proposes a variable-section GWOT that weakens the reverse compression waves and a variable-section structure designed using a numerical method.Results showed that the variable-section structure could reduce the intensity of the incident shock wave by approximately 7%and the total entropy production in the refrigeration cycle by approximately 8%under the design condition.Moreover,the variable-section structure can effectively weaken the strength of the reverse compression waves and improve the refrigeration efficiency by approximately 4%under the same working conditions.The variable-section structure can also widen the highperformance working range of the GWOT.The experimental results reveal that the high-performance working range can be expanded by more than two times under the design condition.The research can guide the subsequent development of gas wave refrigeration technology and a reference for other wave rotor application technologies.展开更多
Lean-burn combustor is particularly susceptible to combustion instability and the unsteady heat release is usually considered as the excitation of the self-maintained thermoacoustic oscillations. The transverse coolan...Lean-burn combustor is particularly susceptible to combustion instability and the unsteady heat release is usually considered as the excitation of the self-maintained thermoacoustic oscillations. The transverse coolant injection is widely used to reduce the temperature of burnt gas, but on the other hand, it will introduce temperature fluctuation inside the combustor.Therefore, it is necessary to consider the influence of the coolant injection on combustion instability, and evaluate its dynamic feature. In this paper, Large-Eddy Simulation（LES） of the self-excited pressure oscillations in a model combustor with coolant injection is carried out. The analysis of transient flow characteristics and the identification of the pressure modes confirm that one of the low frequency pressure oscillations is related to entropy fluctuations, which is known as rumble combustion instability. The LES results show that transient coolant injection is another excitation of temperature fluctuation other than unsteady combustion. The amplitude of the entropy mode oscillation increases with increasing coolant air mass whereas the change of its frequency is insignificant. According to the major feature of entropy wave oscillation caused by coolant injection, a compact coolant injection model is proposed and applied in the One Dimensional（1 D） Acoustic Network Method（ANM）. Key correlations used in the model match well with LES data in low frequency range. This means that the coolant injection model is a complex one reflecting the interaction of the fluctuating coolant mass, pressure and temperature. Finally, the combustion instability frequencies and modes predicted by acoustic network method are also in good agreement with LES results.展开更多
High-entropy MXenes,as a new emerging class of materials,possess diverse compositions,unexpected physicochemical characteristics,and great potentials for electromagnetic(EM)wave absorption.Herein,two single-to-few-lay...High-entropy MXenes,as a new emerging class of materials,possess diverse compositions,unexpected physicochemical characteristics,and great potentials for electromagnetic(EM)wave absorption.Herein,two single-to-few-layer high-entropy MXenes,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))3 C2 T_(x)and(Mo_(0.2)Cr_(0.2)Nb_(0.2)Ti_(0.2)V_(0.2))_(4)C_(3)T_(x),were synthesized for the first time.During the exfoliation and delamination processes,the structural,morphological,and compositional evolutions were analyzed,verifying the successful formation of single-to-few-layer two-dimensional MXene nanosheets.Investigations indicate that with the filling content of only 35 wt%,MXene powder filled composites exhibit high-efficiency EM wave absorption performances.The f-(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)C_(2)T_(x)possesses the minimum reflection loss(RL min)of−45.0 dB with the matching thickness of 1.52 mm and the maximum effective absorption bandwidth(EAB)of 5.6 GHz at 1.65 mm thickness.Also,f-(Mo_(0.2)Cr_(0.2)Nb_(0.2)Ti_(0.2)V_(0.2))_(4)C_(3)T_(x)can attain an RL min of−52.8 dB with the thickness of 1.58 mm and an optimum EAB value of 3.6 GHz at 1.50 mm.The satisfactory EM wave absorption efficiency and bandwidth,thin matching thickness,and low filling content prove the lightweight advantage and great application potential of high-entropy MXenes in EM wave absorption.In this work,the high-entropy strategy is applied to tune the EM wave absorption performances for MXenes.Furthermore,high-entropy engineering is expected to provide control and tunability of many other properties,such as electrochemical,catalytic,and mechanical behaviors.展开更多
We study the generalized Riemann problem of the Chapman-Jouguet model for an ideal combustible Chaplygin gas. By analyzing the wave curves in the phase plane, we construct uniquely the solution of the generalized Riem...We study the generalized Riemann problem of the Chapman-Jouguet model for an ideal combustible Chaplygin gas. By analyzing the wave curves in the phase plane, we construct uniquely the solution of the generalized Riemann problem under the global entropy conditions. We find that although there is no combustion wave of the corresponding Riemann solution, the combustion wave may occur after perturbation which reveals the instability of the unburnt gas.展开更多
In this paper, following the paper [7], we analysis the 'sharp' estimate of the rate of entropy dissipation of the fully discrete MUSCL type Godunov schemes by the general compact theory introduced by Coquel-L...In this paper, following the paper [7], we analysis the 'sharp' estimate of the rate of entropy dissipation of the fully discrete MUSCL type Godunov schemes by the general compact theory introduced by Coquel-LeFloch [1, 2], and find: because of small viscosity of the above schemes, in the vincity of shock wave, the estimate of the above schemes is more easily obtained, but for rarefaction wave, we must impose a 'sharp' condition on limiter function in order to keep its entropy dissipation and its convergence.展开更多
The generalized Riemann problem for gas dynamic combustion in a neighborhood of the origin t 0 in the （x, t） plane is considered. Under the modified entropy conditions, the unique solutions are constructed, which ar...The generalized Riemann problem for gas dynamic combustion in a neighborhood of the origin t 0 in the （x, t） plane is considered. Under the modified entropy conditions, the unique solutions are constructed, which are the limits of the selfsimilar Zeldovich-von Neumann-Dring （ZND） combustion model. The results show that, for some cases, there are intrinsical differences between the structures of the perturbed Riemann solutions and the corresponding Riemann solutions. Especially, a strong detonation in the corresponding Riemann solution may be transformed into a weak deflagration coalescing with the pre-compression shock wave after perturbation. Moreover, in some cases, although no combustion wave exists in the corresponding Riemann solution, the combustion wave may occur after perturbation, which shows the instability of the unburnt gases.展开更多
基金the National Natural Science Foundation of China under Grant Nos.51972089,51672064,U1435206.
文摘Considering the emergence of severe electromagnetic interference problems,it is vital to develop electromagnetic(EM)wave absorbing materials with high dielectric,magnetic loss and optimized impedance matching.However,realizing the synergistic dielectric and magnetic losses in a single phase material is still a challenge.Herein,high entropy(HE)rare earth hexaborides(REB6)powders with coupling of dielectric and magnetic losses were designed and successfully synthesized through a facial one-step boron carbide reduction method,and the effects of high entropy borates intermedia phases on the EM wave absorption properties were investigated.Five HE REB6 ceramics including(Ce0.2Y0.2Sm0.2Er0.2Yb0.2)B6,(Ce0.2Hu0.2Sm0.2Er0.2Yb0.2)B6,(Ce0.2Y0.2Eu0.2Er0.2Yb0.2)B6,(Ce0.2Ya2Sm0.2Eu0.2Yb0.2)B6,and(Nd0.2Y0.2Sm0.2Eu0.2Yb0.2)B6 possess CsCl-type cubic crystal structure,and their theoretical densities range from 4.84 to 5.25 g/cm^(3).(Ce02Y0.2Sm0.2Er0.2Yb02)B6 powders with the average particle size of 1.86 jim were found to possess the best EM wave absorption properties among these hexaborides.The RLmin value of(Ce0.2Y0.2Sm0.2Er0.2Yb0.2)B6 reaches-33.4 dB at 11.5 GHz at thickness of 2 mm;meanwhile,the optimized effective absorption bandwidth(EAB)is 3.9 GHz from 13.6 to 17.5 GHz with a thickness of 1.5 mm.The introduction of HE REB03(RE=Ce,Y,Sm,Eu,Er,Yb)as intermediate phase will give rise to the mismatching impedance,which will further lead to the reduction of reflection loss.Intriguingly,the HEREB6/HEREB03 still possess wide effective absorption bandwidth of 4.1 GHz with the relative low thickness of 1.7 mm.Considering the better stability,low density,and good EM wave absorption properties,HE REB6 ceramics are promising as a new type of EM wave absorbing materials.
文摘Based on the maximum entropy principle, a probability density function (PDF) is derived for the distribution of wave heights in a random wave field, without any more hypothesis. The present PDF, being a non-Rayleigh form, involves two parameters: the average wave height H— and the state parameter γ. The role of γ in the distribution of wave heights is examined. It is found that γ may be a certain measure of sea state. A least square method for determining γ from measured data is proposed. In virtue of the method, the values of γ are determined for three sea states from the data measured in the East China Sea. The present PDF is compared with the well known Rayleigh PDF of wave height and it is shown that it much better fits the data than the Rayleigh PDF. It is expected that the present PDF would fit some other wave variables, since its derivation is not restricted only to the wave height.
基金financially supported by the National Natural Science Foundation of China(Nos.51972089,51672064 and U1435206)。
文摘The increasing electromagnetic hazards including electromagnetic interference and electromagnetic pollution,which were stemmed from massive usage of electromagnetic technology,have triggered widespread concerns.To cope with this challenge,electromagnetic wave absorbing materials with high performance are greatly needed.Composite construction has been widely applied in electromagnetic(EM)wave absorbing materials to achieve high permittivity,high permeability and impedance matching.However,high-temperature stability,oxidation and corrosion resistance are still unignorable issues.Herein,high entropy hexaborides/tetraborides(HE REB_(6)/HE REB_(4))composites with synergistic dielectric and magnetic losses were designed and successfully synthesized through a one-step boron carbide reduction method.The five as-prepared(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(4),(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(4),(Y_(0.2) Nd_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(4),(Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(4) and(Y_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2) Yb_(0.2))B_(4) contain two phases of HE REB_(6) and HE REB_(4).Among them(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Eu_(0.2) Er_(0.2))B_(4)(HE REB_(6)/HE REB_(4)-1)and(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(6)/(Y_(0.2) Nd_(0.2) Sm_(0.2) Er_(0.2) Yb_(0.2))B_(4)(HE REB_(6)/HE REB_(4)-2)exhibit excellent EM wave absorption properties.The optimal minimum reflection loss(RL_(m in))and effective absorption bandwidth(E_(AB))of HE REB_(6)/HE REB_(4)-1 and HE REB_(6)/HE REB_(4)-2 are–53.3 dB(at 1.7 mm),4.2 GHz(at 1.5 mm)and–43.5 dB(1.3 mm),4.2 GHz(1.5 mm),respectively.The combination of conducting HE REB_(4) with magnetism into HE REB_(6) as a second phase enhances dielectric an
基金supported by the National Natural Science Foundation of China(Nos.51725101,11727807,51672050,61790581,22088101)the Ministry of Science and Technology of China(973 Project Nos.2018YFA0209102 and 2021YFA1200600)Infrastructure and Facility Construction Project of Zhejiang Laboratory.
文摘Rational designing of one-dimensional(1D)magnetic alloy to facilitate electromagnetic(EM)wave attenuation capability in low-frequency(2-6 GHz)microwave absorption field is highly desired but remains a significant challenge.In this study,a composite EM wave absorber made of a FeCoNi medium-entropy alloy embedded in a 1D carbon matrix framework is rationally designed through an improved electrospinning method.The 1D-shaped FeCoNi alloy embedded composite demonstrates the high-density and continuous magnetic network using off-axis electronic holography technique,indicating the excellent magnetic loss ability under an external EM field.Then,the in-depth analysis shows that many factors,including 1D anisotropy and intrinsic physical features of the magnetic medium-entropy alloy,primarily contribute to the enhanced EM wave absorption performance.Therefore,the fabricated EM wave absorber shows an increasing effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm.Thus,this study opens up a new method for the design and preparation of high-performance 1D magnetic EM absorbers.
基金supported in part by the UK Engineering and Physical Sciences Research Council Award EP/E035027/1 and EP/L015811/1
文摘We are concerned with the stability of steady multi-wave configurations for the full Euler equations of compressible fluid flow. In this paper, we focus on the stability of steady four-wave configurations that are the solutions of the Riemann problem in the flow direction, consisting of two shocks, one vortex sheet, and one entropy wave, which is one of the core multi-wave configurations for the two-dimensional Euler equations. It is proved that such steady four-wave configurations in supersonic flow are stable in structure globally, even under the BV perturbation of the incoming flow in the flow direction. In order to achieve this, we first formulate the problem as the Cauchy problem （initial value problem） in the flow direction, and then develop a modified Glimm difference scheme and identify a Glimm-type functional to obtain the required BV estimates by tracing the interactions not only between the strong shocks and weak waves, but also between the strong vortex sheet/entropy wave and weak waves. The key feature of the Euler equations is that the reflection coefficient is always less than 1, when a weak wave of different family interacts with the strong vortex sheet/entropy wave or the shock wave, which is crucial to guarantee that the Glimm functional is decreasing. Then these estimates are employed to establish the convergence of the approximate solutions to a global entropy solution, close to the background solution of steady four-wave configuration.
基金This work was financially supported by the Major Basic Re-search Projects of Shandong Natural Science Foundation(No.ZR2018ZB0104)the Science and Technology Development Project of Shandong Province(Nos.2016GGX102003,2017GGX20105)the Natural Science Foundation of Shandong Province(No.ZR2017BEM032).
文摘Herein,a novel kind of high-entropy MAX phases,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders were success-fully synthesized by a newly proposed two-step solid state reaction process.The oxidation experiments demonstrate that the oxidation products of Al_(2)Mo_(3)O_(12) and rutile TiO 2 are formed at about 600 and 800℃,respectively.Besides,the dielectric and electromagnetic(EM)wave absorption properties of(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders and those after oxidation at different temperatures were also exam-ined.The results show that the as-synthesized(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders possess excellent EM wave absorption performances with the minimum reflection loss(RL)of-45.80 dB(at 1.7 mm thickness)and the maximum effective absorption bandwidth(E AB)of 3.6 GHz(at 1.5 mm thickness).After oxidation at 400-800℃,due to the coupling of conductivity loss and polarization loss,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)AlC_(2)powders can retain good EM wave absorption properties in a certain frequency range.In this paper,the effects of oxidation on EM wave absorption properties of high-entropy MAX phases were systematically investigated for the first time.This work manifests that high-entropy MAX phases are promising EM wave absorbing candidates and can maintain good EM wave absorption performances after oxidation.
基金Project supported by the National Key Research and Development Program of China(2022YFB3504302)the Young Elite Scientists Sponsorship Program by CAST(YESS20210336)+1 种基金the Fujian Provincial Natural Fund Project(2021J05101)the XIREM Autonomously Deployment Project(2023GG03)。
文摘Perovskite-type rare-earth ferrites(REFeO_(3))are promising materials for absorbing electromagnetic(EM)wave pollution.However,insufficient dielectric loss and poor impedance matching are key factors that limit the broader implementation of REFeO_(3).Herein,a series of multicomponent perovskite-type ferrites with strong EM wave absorption capabilities was prepared.Through the synergistic effect of chemical constitution regulation and entropy regulation,optimization of the dielectric loss and impedance matching is achieved by strengthening the structural defect mechanism,thus further adjusting the EM wave absorption performance.Compared with(LaGdSmNdBa)FeO_(3)(HE-1)and(LaGdPrSmNdBa)FeO_(3)(HE-2),(LaGdBa)FeO_(3)(ME-1)and(LaGdSmBa)FeO_(3)(ME-2)exhibit favorable performance,with optimal minimum reflection loss(RL_(min))of-56.35 dB(at 11.12 GHz)and-63.25 dB(at 7.22 GHz)and effective absorption bandwidth(EAB)of 4.46 and 4.72 GHz,respectively.This multicomponent design provides a new strategy for the development of EM wave absorption materials.
基金supported by the National Natural Science Foundation of China(Grant Nos.12274471,and 11922415)the Guangdong Basic and Applied Basic Research Foundation(Grant Nos.2022A1515011168,and 2019A1515011718)+6 种基金the Key Research and Development Program of Guangdong Province,China(Grant No.2019B110209003)supported by the Foreign Young Talents Program of China(Grant No.22KW041C211)supported by the Key-Area Research and Development Program of Guangdong Province(Grant No.2020B0101340002)supported by the NKRDPC(Grant Nos.2022YFA1402802,and 2018YFA0306001)the National Natural Science Foundation of China(Grant Nos.11974432,and 92165204)the Leading Talent Program of Guangdong Special Projects(Grant No.201626003)the Shenzhen International Quantum Academy(Grant No.SIQA202102)。
文摘Here we report a TiHfNbTa bulk medium-entropy alloy(MEA)superconductor crystallized in the body-centered cubic structure with the unit cell parameter a=3.35925?,which is synthesized by an arc melting method.Superconducting properties of the TiHfNbTa are studied by employing magnetic susceptibility,resistivity,and specific heat measurements.Experimental results show a bulk superconducting transition temperature(Tc)of around 6.75 K.The lower and upper critical fields for TiHfNbTa are45.8 m T and 10.46 T,respectively.First-principles calculations show that the d electrons of Ti,Hf,Nb,and Ta are the main contribution to the total density of states near the Fermi level.Our results indicate that the superconductivity is a conventional swave type with extremely strong coupling(△C_(el)/γ_(n)T_(c)=2.88,2△_(0)/k_(B)T_(c)=5.02,and λ_(ep)=2.77).The extremely strong coupling behavior in the s-wave type Ti Hf Nb Ta MEA superconductor is unusual because it generally happens in cuprates,pnictides,and other unconventional superconductors.
基金supported by the National Key Research and Development Program of China (Grant No.2018YFA0704601)the National Natural Science Foundation of China (Grant No.22078040)the Fundamental Research Funds for the Central Universities (Grant No.DUT22LAB604)。
文摘This paper introduces the refrigeration cycle process of the gas wave oscillation tube(GWOT).Aiming at the problem that the strong reverse compression waves generated during the refrigeration process affect the performance,this paper proposes a variable-section GWOT that weakens the reverse compression waves and a variable-section structure designed using a numerical method.Results showed that the variable-section structure could reduce the intensity of the incident shock wave by approximately 7%and the total entropy production in the refrigeration cycle by approximately 8%under the design condition.Moreover,the variable-section structure can effectively weaken the strength of the reverse compression waves and improve the refrigeration efficiency by approximately 4%under the same working conditions.The variable-section structure can also widen the highperformance working range of the GWOT.The experimental results reveal that the high-performance working range can be expanded by more than two times under the design condition.The research can guide the subsequent development of gas wave refrigeration technology and a reference for other wave rotor application technologies.
基金The funding of the National Natural Science Foundation of China (No. 51776191)
文摘Lean-burn combustor is particularly susceptible to combustion instability and the unsteady heat release is usually considered as the excitation of the self-maintained thermoacoustic oscillations. The transverse coolant injection is widely used to reduce the temperature of burnt gas, but on the other hand, it will introduce temperature fluctuation inside the combustor.Therefore, it is necessary to consider the influence of the coolant injection on combustion instability, and evaluate its dynamic feature. In this paper, Large-Eddy Simulation（LES） of the self-excited pressure oscillations in a model combustor with coolant injection is carried out. The analysis of transient flow characteristics and the identification of the pressure modes confirm that one of the low frequency pressure oscillations is related to entropy fluctuations, which is known as rumble combustion instability. The LES results show that transient coolant injection is another excitation of temperature fluctuation other than unsteady combustion. The amplitude of the entropy mode oscillation increases with increasing coolant air mass whereas the change of its frequency is insignificant. According to the major feature of entropy wave oscillation caused by coolant injection, a compact coolant injection model is proposed and applied in the One Dimensional（1 D） Acoustic Network Method（ANM）. Key correlations used in the model match well with LES data in low frequency range. This means that the coolant injection model is a complex one reflecting the interaction of the fluctuating coolant mass, pressure and temperature. Finally, the combustion instability frequencies and modes predicted by acoustic network method are also in good agreement with LES results.
基金supported by Major Basic Research Projects of Shandong Natural Science Foundation(ZR2018ZB0104)Science and Technology Development Project of Shandong Province(2016GGX102003,2017GGX20105)Natural Science Foundation of Shandong Province(ZR2017BEM032).
文摘High-entropy MXenes,as a new emerging class of materials,possess diverse compositions,unexpected physicochemical characteristics,and great potentials for electromagnetic(EM)wave absorption.Herein,two single-to-few-layer high-entropy MXenes,(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))3 C2 T_(x)and(Mo_(0.2)Cr_(0.2)Nb_(0.2)Ti_(0.2)V_(0.2))_(4)C_(3)T_(x),were synthesized for the first time.During the exfoliation and delamination processes,the structural,morphological,and compositional evolutions were analyzed,verifying the successful formation of single-to-few-layer two-dimensional MXene nanosheets.Investigations indicate that with the filling content of only 35 wt%,MXene powder filled composites exhibit high-efficiency EM wave absorption performances.The f-(Mo_(0.25)Cr_(0.25)Ti_(0.25)V_(0.25))_(3)C_(2)T_(x)possesses the minimum reflection loss(RL min)of−45.0 dB with the matching thickness of 1.52 mm and the maximum effective absorption bandwidth(EAB)of 5.6 GHz at 1.65 mm thickness.Also,f-(Mo_(0.2)Cr_(0.2)Nb_(0.2)Ti_(0.2)V_(0.2))_(4)C_(3)T_(x)can attain an RL min of−52.8 dB with the thickness of 1.58 mm and an optimum EAB value of 3.6 GHz at 1.50 mm.The satisfactory EM wave absorption efficiency and bandwidth,thin matching thickness,and low filling content prove the lightweight advantage and great application potential of high-entropy MXenes in EM wave absorption.In this work,the high-entropy strategy is applied to tune the EM wave absorption performances for MXenes.Furthermore,high-entropy engineering is expected to provide control and tunability of many other properties,such as electrochemical,catalytic,and mechanical behaviors.
文摘We study the generalized Riemann problem of the Chapman-Jouguet model for an ideal combustible Chaplygin gas. By analyzing the wave curves in the phase plane, we construct uniquely the solution of the generalized Riemann problem under the global entropy conditions. We find that although there is no combustion wave of the corresponding Riemann solution, the combustion wave may occur after perturbation which reveals the instability of the unburnt gas.
文摘In this paper, following the paper [7], we analysis the 'sharp' estimate of the rate of entropy dissipation of the fully discrete MUSCL type Godunov schemes by the general compact theory introduced by Coquel-LeFloch [1, 2], and find: because of small viscosity of the above schemes, in the vincity of shock wave, the estimate of the above schemes is more easily obtained, but for rarefaction wave, we must impose a 'sharp' condition on limiter function in order to keep its entropy dissipation and its convergence.
基金Project supported by the National Natural Science Foundation of China(No.10971130)the Shanghai Leading Academic Discipline Project(No.J50101)+1 种基金the Shanghai Municipal Education Commission of Scientific Research Innovation Project(No.11ZZ84)the Graduate Innovation Foundation of Shanghai University
文摘The generalized Riemann problem for gas dynamic combustion in a neighborhood of the origin t 0 in the （x, t） plane is considered. Under the modified entropy conditions, the unique solutions are constructed, which are the limits of the selfsimilar Zeldovich-von Neumann-Dring （ZND） combustion model. The results show that, for some cases, there are intrinsical differences between the structures of the perturbed Riemann solutions and the corresponding Riemann solutions. Especially, a strong detonation in the corresponding Riemann solution may be transformed into a weak deflagration coalescing with the pre-compression shock wave after perturbation. Moreover, in some cases, although no combustion wave exists in the corresponding Riemann solution, the combustion wave may occur after perturbation, which shows the instability of the unburnt gases.
