Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and perform...Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and performance of the connection joints are analyzed and studied. The research results indicate that energy-storage welding is able to realize the spot welding connection of AZ9ID Mg alloy ribbons. The welding nugget consists of developed α-Mg equiaxed grains with the sizes of 1.2-2.7 μm and intergranular distributed β-Mg17Al12 compounds. The thickness of bond zone is about 4 μm and the solidification microstructure is characterized by the fine equiaxed grains with the sizes of 0.8-1.2μm and grain boundary has become coarsening. The columnar crystal in HAZ also becomes slightly coarsening and the grain boundary has broadened, however, there is no obvious change in its primitive morphology and crystallographic direction. When welding energy is about 2.0 J, the welding joints with higher shear strength and smaller electrical resistivity are obtained.展开更多
介绍了一种新的切实可行的能量俘获方法,即通过压电结构的力/电转换功能从环境振动中提取能量,实现微电子器件的无线供能.这种由压电结构制作的能从环境振动中提取能量的声波器件称为压电俘能器,可分为两类:一类是压电结构在环境振动激...介绍了一种新的切实可行的能量俘获方法,即通过压电结构的力/电转换功能从环境振动中提取能量,实现微电子器件的无线供能.这种由压电结构制作的能从环境振动中提取能量的声波器件称为压电俘能器,可分为两类:一类是压电结构在环境振动激励下所输出的功率直接供给微电子器件工作,不进行能量储存,这类俘能器称为第一类压电俘能器(piezoelectric power harvester);另一类是环境振动较弱,压电结构的输出功率低于器件的瞬时耗能,考虑到某些器件大部分时间处于休眠状态,而俘能器却随时可以从环境振动中提取能量,因此经过一段时间的能量累积后,由俘能器所储存的能量仍能满足器件的短期工作耗能.显然,这类俘能器需要具备能量储存功能,称为第二类压电俘能器(piezoelectric energy harvester).本文详细介绍了压电俘能器结构以及两类俘能器的不同分析方法,阐述了提高俘能效率的有效措施并揭示了相关的改进机理,对压电俘能器的设计和应用具有重要意义.展开更多
Fast charging stations play an important role in the use of electric vehicles(EV)and significantly affect the distribution network owing to the fluctuation of their power.For exploiting the rapid adjustment feature of...Fast charging stations play an important role in the use of electric vehicles(EV)and significantly affect the distribution network owing to the fluctuation of their power.For exploiting the rapid adjustment feature of the energy-storage system(ESS),a configuration method of the ESS for EV fast charging stations is proposed in this paper,which considers the fluctuation of the wind power as well as the characteristics of the charging load.The configuration of the ESS can not only mitigate the effects of fast charging stations on the connected distribution network but also improve its economic efficiency.First,the scenario method is adopted to model the wind power in the distribution network,and according to the characteristics of the EV and the driving probability,the charging demand of each station is calculated.Then,considering factors such as the investment cost,maintenance cost,discharging benefit,and wind curtailment cost,the ESS configuration model of the distribution network is set up,which takes the optimal total costs of the ESS for EV fast charging stations within its lifecycle as an objective.Finally,General Algebraic Modelling System(GAMS)is used to linearize and solve the proposed model.A simulation on an improved IEEE-69 bus system verifies the feasibility and economic efficiency of the proposed model.展开更多
Energy-storage technologies based on lithium-ion batteries are advancing rapidly.However,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially ...Energy-storage technologies based on lithium-ion batteries are advancing rapidly.However,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially leads to severe accidents.To address the detection and early warning of battery thermal runaway faults,this study conducted a comprehensive review of recent advances in lithium battery fault monitoring and early warning in energy-storage systems from various physical perspectives.The focus was electrical,thermal,acoustic,and mechanical aspects,which provide effective insights for energy-storage system safety enhancement.展开更多
The primary challenge in renewable-energy utilization is an energy-storage system involving its power converter.The systems have to promise high efficiency,reliability and durability.Also,all of these can be realized ...The primary challenge in renewable-energy utilization is an energy-storage system involving its power converter.The systems have to promise high efficiency,reliability and durability.Also,all of these can be realized at an economical cost.Buck and boost converters connected in parallel can convert power in both directions.It is the basic non-isolated bidirectional topology commonly used with energy-storage systems.The primary issue with the buck-boost non-isolated bidirectional converter is how to enhance its performance,so the modification involving this topology is still conducted.This paper examines 29 proposed converters from 30 research publications published in the last 10 years,the most recent of which focuses on modified non-isolated bidirectional converters based on the buck-boost topology.These are classified into eight modification schemes,which involve adding new components or circuits to the base topology.Each is evaluated against six parameters:the number of components,control complexity,power-rating applications,soft-switching ability,efficiency outcome and capacity to minimize losses.Moreover,each modified non-isolated bidirectional converter was compared from the renewable-energy-based power-generation-source perspective utilized.Based on these studies,researchers might think of ways to improve the buck-boost converter by changing it to make a new non-isolated bidirectional converter that can be used in systems that need it.展开更多
In the last few decades,dielectric capacitors have gotten a lot of attention because they can store more power and charge and discharge very quickly.But it has a low energy-storage density(Wrec),efficiency(h),and temp...In the last few decades,dielectric capacitors have gotten a lot of attention because they can store more power and charge and discharge very quickly.But it has a low energy-storage density(Wrec),efficiency(h),and temperature stability.By adding Pb(Mg1/3Nb2/3)O3(PMN)and(Bi0$1Sr0.85)TiO3(BST)to a nonstoichiometric(Bi0$51Na0.5)TiO3(BNT)matrix,the goal is to change the phase transition properties and make the material more relaxor ferroelectric(RFE)by lowering the remnant polarization Pr and keeping the maximum polarization Pmax.A viscous polymer process(VPP)is used to improve the electric breakdown strength,which is also a key part of being able to store energy.By working together,ceramics with the formula 0.79[0.85BNT-0.15PMN]-0.21BST(BP-0.21BST)are made.The phase structure has been changed from a rhombohedral phase to a rhombohedral-tetragonal coexisted phase.This is beneficial for RFE properties and gives a Wrec of 6.45 J/cm^(3) and a h of 90%at 400 kV/cm.Also,the energy-storage property is very temperature stable between 30 and 150C.These results show that process optimization and composition design can be used to improve the energy storage properties,and that the dielectric ceramic materials made can be used in high-powder pulse dielectric capacitors.展开更多
Metal-ion capacitors(including Li^(+),Na^(+),and K^(+))effectively combine a battery negative electrode capable of reversibly intercalating metal cations,together with an electrical double-layer positive electrode.How...Metal-ion capacitors(including Li^(+),Na^(+),and K^(+))effectively combine a battery negative electrode capable of reversibly intercalating metal cations,together with an electrical double-layer positive electrode.However,such novel cell design has a birth defect,namely kinetics mismatch between sluggish negative electrode and fast positive electrode,thus limiting the energy-power performance.Herein,we design a MoS_(2)-carbon composite anode with the ordered macroporous architecture and interlayer-expanded feature,exhibiting the fast and reversible Na^(+)redox processes.This kinetically favored anode is coupled with a homemade activated carbon cathode that allows for the excellent electrochemical performance of sodiumion capacitor with respect to large specific capacity,high-rate capability,and robust cycling.Through quantification of the potential swings of anode and cathode via a three-electrode Swagelok cell,we for the first time observe the abnormal variation law of potential swings and thus directly providing the evidence that the kinetics gap has been filled up by this kinetically favored anode.Our results represent a crucial step toward understanding the key issues of kinetics mismatch for hybrid cell,thus propelling the development of design of kinetically favored anode materials for high-performance metalion capacitors.展开更多
Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising techn...Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising technology without the limitation of water electrolysis, but they suffer from low electrolyte concentration and unsatisfactory battery performance. Here, a non-aqueous lithium bromine rechargeable battery is proposed, which is based on Br;/Br;and Li;/Li as active redox pairs, with fast redox kinetics and good stability. The Li/Br battery combines the advantages of high output voltage（;.1 V）,electrolyte concentration（3.0 mol/L）, maximum power density（29.1 m W/cm;） and practical energy density（232.6 Wh/kg）. Additionally, the battery displays a columbic efficiency（CE） of 90.0%, a voltage efficiency（VE） of 88.0% and an energy efficiency（EE） of 80.0% at 1.0 m A/cm;after continuously running for more than 1000 cycles, which is by far the longest cycle life reported for non-aqueous flow batteries.展开更多
Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2&l...Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2</sub>, and air showed that oxygen and air plasma efficiently decomposed 2,6-DBP to bromide ion, and inorganic carbon. The molecular orbital model was applied in the analysis of the degradation in electrophilic, nucleophilic, and radical reactions.展开更多
Compared with antiferroelectric(AFE)orthothombic R phases,AFE orthothombic P phases in Na NbO_(3)(NN)ceramics have been rarely investigated,particularly in the field of energy-storage capadtors.The main bottlenedk is ...Compared with antiferroelectric(AFE)orthothombic R phases,AFE orthothombic P phases in Na NbO_(3)(NN)ceramics have been rarely investigated,particularly in the field of energy-storage capadtors.The main bottlenedk is closely related to the contradiction between d fficultly achieved stable relaxor AFE P phase and easily induced P-R phase transition during modifying dhemical compositions.Herein,we reporta novel lead-free AFE ceramic of(1-x)NN-x(Bi_(0.5)K_(0.5))ZrO_(3)((1-x)NN-xBKZ)with a pure AFE P phase str ucture,which exhibits excellent energy-storage characteristics,such as an ultrahigh recoverable energy density(W_(rec))-4.4 J/cm^(3) at x=0.11,a large powder density P_(D)-104 MW/cm^(3) and a fast discharge rate t_(0.9)-45 ns.The analysis of polarization-field response,Raman spectrum and transmission elecron microscopy demonstrates that the giant amplification of W_(rec) by≥177% should be ma inly ascribed to the simultaneously and effectively enhanced AFE P phase stbility and its relaxor dharacteristics,resulting in a diffused reversible electric field-induced AFE P-ferroelectric phase transition with concurrently incre.ased driving electric fields.Different from mast(1-x)NN-xABO_(3) systems,it was found that the reduced polarizability of B-site cations dominates the enhanced AFE P-phase stability in(1-x)NN-xBKZ ceramics,but the almost unchanged tolerance factor tends to ause the AFE R phase to be induced at a relatively high x value.展开更多
文摘Energy-storage welding connection characteristics of rapidly solidified AZ91D Mg alloy ribbons with 40-70 μm thickness are investigated using a microtype energy-storage welding machine. The microstructure and performance of the connection joints are analyzed and studied. The research results indicate that energy-storage welding is able to realize the spot welding connection of AZ9ID Mg alloy ribbons. The welding nugget consists of developed α-Mg equiaxed grains with the sizes of 1.2-2.7 μm and intergranular distributed β-Mg17Al12 compounds. The thickness of bond zone is about 4 μm and the solidification microstructure is characterized by the fine equiaxed grains with the sizes of 0.8-1.2μm and grain boundary has become coarsening. The columnar crystal in HAZ also becomes slightly coarsening and the grain boundary has broadened, however, there is no obvious change in its primitive morphology and crystallographic direction. When welding energy is about 2.0 J, the welding joints with higher shear strength and smaller electrical resistivity are obtained.
文摘介绍了一种新的切实可行的能量俘获方法,即通过压电结构的力/电转换功能从环境振动中提取能量,实现微电子器件的无线供能.这种由压电结构制作的能从环境振动中提取能量的声波器件称为压电俘能器,可分为两类:一类是压电结构在环境振动激励下所输出的功率直接供给微电子器件工作,不进行能量储存,这类俘能器称为第一类压电俘能器(piezoelectric power harvester);另一类是环境振动较弱,压电结构的输出功率低于器件的瞬时耗能,考虑到某些器件大部分时间处于休眠状态,而俘能器却随时可以从环境振动中提取能量,因此经过一段时间的能量累积后,由俘能器所储存的能量仍能满足器件的短期工作耗能.显然,这类俘能器需要具备能量储存功能,称为第二类压电俘能器(piezoelectric energy harvester).本文详细介绍了压电俘能器结构以及两类俘能器的不同分析方法,阐述了提高俘能效率的有效措施并揭示了相关的改进机理,对压电俘能器的设计和应用具有重要意义.
文摘Fast charging stations play an important role in the use of electric vehicles(EV)and significantly affect the distribution network owing to the fluctuation of their power.For exploiting the rapid adjustment feature of the energy-storage system(ESS),a configuration method of the ESS for EV fast charging stations is proposed in this paper,which considers the fluctuation of the wind power as well as the characteristics of the charging load.The configuration of the ESS can not only mitigate the effects of fast charging stations on the connected distribution network but also improve its economic efficiency.First,the scenario method is adopted to model the wind power in the distribution network,and according to the characteristics of the EV and the driving probability,the charging demand of each station is calculated.Then,considering factors such as the investment cost,maintenance cost,discharging benefit,and wind curtailment cost,the ESS configuration model of the distribution network is set up,which takes the optimal total costs of the ESS for EV fast charging stations within its lifecycle as an objective.Finally,General Algebraic Modelling System(GAMS)is used to linearize and solve the proposed model.A simulation on an improved IEEE-69 bus system verifies the feasibility and economic efficiency of the proposed model.
文摘Energy-storage technologies based on lithium-ion batteries are advancing rapidly.However,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially leads to severe accidents.To address the detection and early warning of battery thermal runaway faults,this study conducted a comprehensive review of recent advances in lithium battery fault monitoring and early warning in energy-storage systems from various physical perspectives.The focus was electrical,thermal,acoustic,and mechanical aspects,which provide effective insights for energy-storage system safety enhancement.
基金supported and funded by the Higher Education Leading Applied Research(PTUPT)programme of the Ministry of Education,Culture,Research,and Technology of the Republic of Indonesia under contract number 011/PL.PTUPT/BRIn.LPPM/VI/2022the Indonesia Endowment Funds for Education(LPDP),Ministry of Finance of the Republic of Indonesia[number:20200811214083].
文摘The primary challenge in renewable-energy utilization is an energy-storage system involving its power converter.The systems have to promise high efficiency,reliability and durability.Also,all of these can be realized at an economical cost.Buck and boost converters connected in parallel can convert power in both directions.It is the basic non-isolated bidirectional topology commonly used with energy-storage systems.The primary issue with the buck-boost non-isolated bidirectional converter is how to enhance its performance,so the modification involving this topology is still conducted.This paper examines 29 proposed converters from 30 research publications published in the last 10 years,the most recent of which focuses on modified non-isolated bidirectional converters based on the buck-boost topology.These are classified into eight modification schemes,which involve adding new components or circuits to the base topology.Each is evaluated against six parameters:the number of components,control complexity,power-rating applications,soft-switching ability,efficiency outcome and capacity to minimize losses.Moreover,each modified non-isolated bidirectional converter was compared from the renewable-energy-based power-generation-source perspective utilized.Based on these studies,researchers might think of ways to improve the buck-boost converter by changing it to make a new non-isolated bidirectional converter that can be used in systems that need it.
文摘In the last few decades,dielectric capacitors have gotten a lot of attention because they can store more power and charge and discharge very quickly.But it has a low energy-storage density(Wrec),efficiency(h),and temperature stability.By adding Pb(Mg1/3Nb2/3)O3(PMN)and(Bi0$1Sr0.85)TiO3(BST)to a nonstoichiometric(Bi0$51Na0.5)TiO3(BNT)matrix,the goal is to change the phase transition properties and make the material more relaxor ferroelectric(RFE)by lowering the remnant polarization Pr and keeping the maximum polarization Pmax.A viscous polymer process(VPP)is used to improve the electric breakdown strength,which is also a key part of being able to store energy.By working together,ceramics with the formula 0.79[0.85BNT-0.15PMN]-0.21BST(BP-0.21BST)are made.The phase structure has been changed from a rhombohedral phase to a rhombohedral-tetragonal coexisted phase.This is beneficial for RFE properties and gives a Wrec of 6.45 J/cm^(3) and a h of 90%at 400 kV/cm.Also,the energy-storage property is very temperature stable between 30 and 150C.These results show that process optimization and composition design can be used to improve the energy storage properties,and that the dielectric ceramic materials made can be used in high-powder pulse dielectric capacitors.
基金supported by National Natural Science Foundation of China(No.51902188)Natural Science Foundation of Jiangsu Province(No.BK20190207)+1 种基金Natural Science Doctoral Foundation of Shandong Province(No.ZR2019BB057)the CAS Key Laboratory of Carbon Materials(No.KLCMKFJJ2006).
文摘Metal-ion capacitors(including Li^(+),Na^(+),and K^(+))effectively combine a battery negative electrode capable of reversibly intercalating metal cations,together with an electrical double-layer positive electrode.However,such novel cell design has a birth defect,namely kinetics mismatch between sluggish negative electrode and fast positive electrode,thus limiting the energy-power performance.Herein,we design a MoS_(2)-carbon composite anode with the ordered macroporous architecture and interlayer-expanded feature,exhibiting the fast and reversible Na^(+)redox processes.This kinetically favored anode is coupled with a homemade activated carbon cathode that allows for the excellent electrochemical performance of sodiumion capacitor with respect to large specific capacity,high-rate capability,and robust cycling.Through quantification of the potential swings of anode and cathode via a three-electrode Swagelok cell,we for the first time observe the abnormal variation law of potential swings and thus directly providing the evidence that the kinetics gap has been filled up by this kinetically favored anode.Our results represent a crucial step toward understanding the key issues of kinetics mismatch for hybrid cell,thus propelling the development of design of kinetically favored anode materials for high-performance metalion capacitors.
基金financial supported by the Natural Science Foundation of China(Grant No.21476224,21406219 and 51361135701)
文摘Flow batteries with high energy density and long cycle life have been pursued to advance the progress of energy storage and grid application. Non-aqueous batteries with wide voltage windows represent a promising technology without the limitation of water electrolysis, but they suffer from low electrolyte concentration and unsatisfactory battery performance. Here, a non-aqueous lithium bromine rechargeable battery is proposed, which is based on Br;/Br;and Li;/Li as active redox pairs, with fast redox kinetics and good stability. The Li/Br battery combines the advantages of high output voltage（;.1 V）,electrolyte concentration（3.0 mol/L）, maximum power density（29.1 m W/cm;） and practical energy density（232.6 Wh/kg）. Additionally, the battery displays a columbic efficiency（CE） of 90.0%, a voltage efficiency（VE） of 88.0% and an energy efficiency（EE） of 80.0% at 1.0 m A/cm;after continuously running for more than 1000 cycles, which is by far the longest cycle life reported for non-aqueous flow batteries.
文摘Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2</sub>, and air showed that oxygen and air plasma efficiently decomposed 2,6-DBP to bromide ion, and inorganic carbon. The molecular orbital model was applied in the analysis of the degradation in electrophilic, nucleophilic, and radical reactions.
基金Financial support from the National Natural Science Foundation of China(Grant No.52072103 and U19A2087)the AHPU innovation team project(S022021058)is gratefully acknowledged.
文摘Compared with antiferroelectric(AFE)orthothombic R phases,AFE orthothombic P phases in Na NbO_(3)(NN)ceramics have been rarely investigated,particularly in the field of energy-storage capadtors.The main bottlenedk is closely related to the contradiction between d fficultly achieved stable relaxor AFE P phase and easily induced P-R phase transition during modifying dhemical compositions.Herein,we reporta novel lead-free AFE ceramic of(1-x)NN-x(Bi_(0.5)K_(0.5))ZrO_(3)((1-x)NN-xBKZ)with a pure AFE P phase str ucture,which exhibits excellent energy-storage characteristics,such as an ultrahigh recoverable energy density(W_(rec))-4.4 J/cm^(3) at x=0.11,a large powder density P_(D)-104 MW/cm^(3) and a fast discharge rate t_(0.9)-45 ns.The analysis of polarization-field response,Raman spectrum and transmission elecron microscopy demonstrates that the giant amplification of W_(rec) by≥177% should be ma inly ascribed to the simultaneously and effectively enhanced AFE P phase stbility and its relaxor dharacteristics,resulting in a diffused reversible electric field-induced AFE P-ferroelectric phase transition with concurrently incre.ased driving electric fields.Different from mast(1-x)NN-xABO_(3) systems,it was found that the reduced polarizability of B-site cations dominates the enhanced AFE P-phase stability in(1-x)NN-xBKZ ceramics,but the almost unchanged tolerance factor tends to ause the AFE R phase to be induced at a relatively high x value.
