Biomass-derived porous carbons show great potential as electrode materials for supercapacitors due to the environmental friendliness. However, most of the carbonaceous electrode materials suffer from low specific capa...Biomass-derived porous carbons show great potential as electrode materials for supercapacitors due to the environmental friendliness. However, most of the carbonaceous electrode materials suffer from low specific capacitance and rate capacity because of the poor porosity. Here, we reported a simple and effective approach to prepare micro/nano-hierarchical structured carbon materials derived from rice husk by NaOH-KOH molten salt co-activation. The as-prepared activated carbons exhibit high porosity and suitable pore size distributions for more electrolyte ion adsorption, which are all beneficial for achieving remarkable electrochemical performances, such as high specific capacitance（194.6 F/g）, excellent rate capability（retention of 85.9%） and outstanding cycling stability. Thus, the above biomass-derived carbon materials with high porosity and micro/nano structures obtained by co-activation method offered a new insight into novel electrode material for the use in energy storage systems with high energy density and excellent rate performance.展开更多
Ionic conductivity is one of the crucial parameters for inorganic solid-state electrolytes.To explore the relationship between porosity and ionic conductivity,a series of Li_(6.4)Ga_(0.2)La_(3)Zr_(2)O_(12) garnet type...Ionic conductivity is one of the crucial parameters for inorganic solid-state electrolytes.To explore the relationship between porosity and ionic conductivity,a series of Li_(6.4)Ga_(0.2)La_(3)Zr_(2)O_(12) garnet type solid-state electrolytes with different porosities were prepared via solid-state reaction.Based on the quantified data,an empirical decay relationship was summarized and discussed by means of mathematical model and dimensional analysis method.It suggests that open porosity causes ionic conductivity to decrease exponentially.The pre-exponential factor obeys the Arrhenius Law quite well with the activation energy of 0.23 eV,and the decay constant is averaged to be 2.62%.While the closed porosity causes ionic conductivity to decrease linearly.The slope and intercept of this linear pattern also obey the Arrhenius Law and the activation energies are 0.24 and 0.27 eV,respectively.Moreover,the total porosity is linearly dependent on the open porosity,and different sintering conditions will lead to different linear patterns with different slopes and intercepts.展开更多
Natural water bodies mostly contain cations,and the type and content of these cations are the main factors affecting the flocculation of fine-grained cohesive sediments and the floc sedimentation rate at the interface...Natural water bodies mostly contain cations,and the type and content of these cations are the main factors affecting the flocculation of fine-grained cohesive sediments and the floc sedimentation rate at the interface between clear and turbid water.From the microscopic aspect,this study examined the changing patterns of porosity and the fractal dimension of the flocs of fine-grained cohesive sediments.Sedimentation experiments under different sediment contents and electrolyte conditions were conducted,and microscopic images of the flocs were analysed using Image-Pro Plus(IPP)and MATLAB based on the fractal theory.From the macroscopic aspect,this study experimentally investigated the flocculation and sedimentation of fine-grained cohesive sediments and proposed a sedimentation rate equation by introducing an ion concentration-related parameter into an existing sedimentation rate equation(stagnation zone)based on the adsorption isotherm equation.The equation proposed in this study was validated with measured data.The calculated values were in good agreement with the measured values,with a relative error of 16%.The findings of this study provide a reference for further research on the flocculation and sedimentation of fine-grained cohesive sediments in different water bodies.展开更多
The optical metal nanoantenna on thin film solar cell is effective to enhance light absorption. In this paper, the diamond-type Ag nanoantenna arrays are proposed for increasing the efficiency of solar cells by locali...The optical metal nanoantenna on thin film solar cell is effective to enhance light absorption. In this paper, the diamond-type Ag nanoantenna arrays are proposed for increasing the efficiency of solar cells by localized surface plasmons resonance(LSPR). The effect of metal nanoantenna on the absorption enhancement is theoretically investigated by the finite difference time domain(FDTD) method. Broadband absorption enhancements in both visible and near-infrared regions are demonstrated in case of solar cell with diamond-type Ag nanoantennas. The spectral response is manipulated by geometrical parameters of the nanoantennas. The maximum enhancement factor of 1.51 for solar cell is obtained. For comparison, the other three nanoantennas are also analyzed. The results show that the solar cell with optimized diamond-type nanoantenna arrays is more efficient in optical absorption.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.21573093, 21671194） and the Guangdong Innovative and Entrepreneurial Research Team Program, China（No.2013C092）.
文摘Biomass-derived porous carbons show great potential as electrode materials for supercapacitors due to the environmental friendliness. However, most of the carbonaceous electrode materials suffer from low specific capacitance and rate capacity because of the poor porosity. Here, we reported a simple and effective approach to prepare micro/nano-hierarchical structured carbon materials derived from rice husk by NaOH-KOH molten salt co-activation. The as-prepared activated carbons exhibit high porosity and suitable pore size distributions for more electrolyte ion adsorption, which are all beneficial for achieving remarkable electrochemical performances, such as high specific capacitance（194.6 F/g）, excellent rate capability（retention of 85.9%） and outstanding cycling stability. Thus, the above biomass-derived carbon materials with high porosity and micro/nano structures obtained by co-activation method offered a new insight into novel electrode material for the use in energy storage systems with high energy density and excellent rate performance.
基金supported by the Innovation and Entrepreneurship Project of Hunan Province,China(No.2019GK5053)Program of Huxiang Young Talents,China(No.2019RS2002)+1 种基金the Natural Science Foundation for Distinguished Young Scholars of Hunan Province,China(No.2020JJ2047)the Fundamental Research Funds for the Central Universities of Central South University,China。
文摘Ionic conductivity is one of the crucial parameters for inorganic solid-state electrolytes.To explore the relationship between porosity and ionic conductivity,a series of Li_(6.4)Ga_(0.2)La_(3)Zr_(2)O_(12) garnet type solid-state electrolytes with different porosities were prepared via solid-state reaction.Based on the quantified data,an empirical decay relationship was summarized and discussed by means of mathematical model and dimensional analysis method.It suggests that open porosity causes ionic conductivity to decrease exponentially.The pre-exponential factor obeys the Arrhenius Law quite well with the activation energy of 0.23 eV,and the decay constant is averaged to be 2.62%.While the closed porosity causes ionic conductivity to decrease linearly.The slope and intercept of this linear pattern also obey the Arrhenius Law and the activation energies are 0.24 and 0.27 eV,respectively.Moreover,the total porosity is linearly dependent on the open porosity,and different sintering conditions will lead to different linear patterns with different slopes and intercepts.
基金funded by The Nature Foundation of Inner Mongolia Autonomous Region 2021MS05042The National Natural Science Foundation of China project 51969021,52169016The Major Science and Technology Projects of Inner Mongolia Autonomous Region 2021ZD0008.
文摘Natural water bodies mostly contain cations,and the type and content of these cations are the main factors affecting the flocculation of fine-grained cohesive sediments and the floc sedimentation rate at the interface between clear and turbid water.From the microscopic aspect,this study examined the changing patterns of porosity and the fractal dimension of the flocs of fine-grained cohesive sediments.Sedimentation experiments under different sediment contents and electrolyte conditions were conducted,and microscopic images of the flocs were analysed using Image-Pro Plus(IPP)and MATLAB based on the fractal theory.From the macroscopic aspect,this study experimentally investigated the flocculation and sedimentation of fine-grained cohesive sediments and proposed a sedimentation rate equation by introducing an ion concentration-related parameter into an existing sedimentation rate equation(stagnation zone)based on the adsorption isotherm equation.The equation proposed in this study was validated with measured data.The calculated values were in good agreement with the measured values,with a relative error of 16%.The findings of this study provide a reference for further research on the flocculation and sedimentation of fine-grained cohesive sediments in different water bodies.
基金supported by the International Scientific and Technological Cooperation Projects of Guizhou Province in China(No.[2011]7035)
文摘The optical metal nanoantenna on thin film solar cell is effective to enhance light absorption. In this paper, the diamond-type Ag nanoantenna arrays are proposed for increasing the efficiency of solar cells by localized surface plasmons resonance(LSPR). The effect of metal nanoantenna on the absorption enhancement is theoretically investigated by the finite difference time domain(FDTD) method. Broadband absorption enhancements in both visible and near-infrared regions are demonstrated in case of solar cell with diamond-type Ag nanoantennas. The spectral response is manipulated by geometrical parameters of the nanoantennas. The maximum enhancement factor of 1.51 for solar cell is obtained. For comparison, the other three nanoantennas are also analyzed. The results show that the solar cell with optimized diamond-type nanoantenna arrays is more efficient in optical absorption.
