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对苯二酚在碳纳米管修饰玻碳电极的电化学行为及电化学动力学研究 被引量:16
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作者 梁斌 孙玉琴 +1 位作者 赵元弟 高作宁 《化学研究与应用》 CAS CSCD 北大核心 2007年第1期89-92,共4页
The multi-wall carbon nanotubes(MWNTs)modified glassy carbon electrode(CNT/GCE)was fabricated and its electrocatalytic activity of hydroquinone was investigated.It was found that the electrochemical behaviors were... The multi-wall carbon nanotubes(MWNTs)modified glassy carbon electrode(CNT/GCE)was fabricated and its electrocatalytic activity of hydroquinone was investigated.It was found that the electrochemical behaviors were greatly improved at CNT/GC,indicating that the redox of hydroquinone could be catalyzed at CNT/GC.The kinetic parameters of thisprocess were calculated.The diffusiong coefficient was 1.7×10-5cm2·s-1,the heterogeneouselectron transfer rate constant k was 0.678s-1,α value was 0.538 and electron transfer numbers was 2. 展开更多
关键词 碳纳米管修饰电极 对苯二酚 电化学 电化学动力学
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