1.3 mm SWP-B弹簧钢丝生产的扭转弹簧在客户装配前发生断裂,弹簧断口以沿晶断裂为主。分析材料化学成分和组织,对弹簧断口附近和正常组织进行纵截面显微硬度测定,采用扫描电镜对断口进行宏观和微观检查,并用X射线能谱仪对断口进行分...1.3 mm SWP-B弹簧钢丝生产的扭转弹簧在客户装配前发生断裂,弹簧断口以沿晶断裂为主。分析材料化学成分和组织,对弹簧断口附近和正常组织进行纵截面显微硬度测定,采用扫描电镜对断口进行宏观和微观检查,并用X射线能谱仪对断口进行分析。结果表明:扭转弹簧在电镀锌初期局部产生非正常组织马氏体,由于马氏体存在组织应力,与在酸洗和电镀锌时弹簧基体中的氢造成的内应力相互作用,导致扭转弹簧出现裂纹并滞后断裂。展开更多
A A cerium-based chemical conversion process was studied. First, zinc coating obtained from a free-cyanide alkaline bath, with derivative of imidazol with new brightener, was investigated, zinc-plated steel specimens...A A cerium-based chemical conversion process was studied. First, zinc coating obtained from a free-cyanide alkaline bath, with derivative of imidazol with new brightener, was investigated, zinc-plated steel specimens were treated with a solution of 50 mmol· L^-1 Ce（NO3 ）3 The corrosion behavior of bare and treated mild galvanized steel was evaluated during exposure to 0.5 mol · L^-1 NaCl for different immersion time, using Tafel polarization curves and electrochemical impedance spectroscopy （EIS） measurements. The surface morphology of the coating was studied using scanning electron microscopy （SEM）. The composition and chemical percent of the coating were examined by X-ray dispersion energy （EDAX）. The results of these measurements showed that the newly developed cerium-based conversion coating process was a promising candidate for replacing the conventional chromate treatments used at present for galvanized steel.展开更多
钢丝的耐腐蚀性能影响桥梁缆索的使用寿命。采用电镀锌和热镀锌铝对4.3 mm SWRS82B钢丝进行表面处理,对电镀锌和热镀锌铝钢丝在0.1 mol/L HCl溶液中进行耐腐蚀性能研究,对腐蚀后的形貌进行观察并分析腐蚀机理。结果表明:电镀锌后钢丝表...钢丝的耐腐蚀性能影响桥梁缆索的使用寿命。采用电镀锌和热镀锌铝对4.3 mm SWRS82B钢丝进行表面处理,对电镀锌和热镀锌铝钢丝在0.1 mol/L HCl溶液中进行耐腐蚀性能研究,对腐蚀后的形貌进行观察并分析腐蚀机理。结果表明:电镀锌后钢丝表面粗糙度Ra=1.024μm,热镀锌铝后钢丝表面粗糙度Ra=0.637μm,热镀锌铝试样表面粗糙度明显小于电镀锌试样;电镀锌的锌层厚度约为15μm,扩散层为35μm,热镀锌铝合金的镀锌层约为24μm,扩散层为50μm,热镀锌铝试样的耐腐蚀性能明显优于电镀锌试样。展开更多
Strip-shaped chromatic aberration defects on the surface of an electro-galvanized fingerprint-resistant sheet were systematically studied using Thermo-Calc thermodynamic calculations,scanning electron microscope and X...Strip-shaped chromatic aberration defects on the surface of an electro-galvanized fingerprint-resistant sheet were systematically studied using Thermo-Calc thermodynamic calculations,scanning electron microscope and X-ray diffractometer analyses,and rapid heat treatment simulation technology.The formation mechanism of these defects was also analyzed.The results show a strong correlation between the defects and the uneven distribution of the Fe(001)component on the surface of the steel substrate.The relatively high proportion of Fe(001)components on the surface of the steel substrate affects the distribution density of the Zn crystal cells in different orientations during the electrodeposition process,which causes the reflection intensity of the light of the galvanized layer to differ from various visual perspectives,and macroscopic strip-shaped chromatic aberration defects are finally formed.The high proportion of the Fe(001)component on the surface of the steel substrate is mainly related to the following two factors.First,when the strip steel is hot-rolled,the finishing hot-rolling temperature is close to theγ→αphase transition temperature.When the local temperature on the upper surface of the strip steel is low,γ+αtwo-phase rolling easily occurs,and this results in an uneven stress distribution between theγandαphases after the hot-rolling process.This uneven distribution of hot-rolling stress results in the formation of a coarse grain structure in the local area on the surface of the hot-rolled sheet,which strongly affects the subsequent cold rolling and annealing process,and the annealed steel sheet substrate ultimately contains a greater proportion of the Fe(001)component.And second,a fast cooling rate(>10 K/s)during the slow cooling stage in the continuous annealing process inhibits the transformation of the Fe(001)to the Fe(111)component on the surface of the cold-rolled steel sheet,and it is then not possible to effectively eliminate the influence of the unevenly distributed Fe(001)component on th展开更多
Nine distinct zinc-nickel-tin films with different compositions have been galvanostatically electrodeposited. The films have been characterized by scanning electron microscopy(SEM) and energy dispersive spectrometry(E...Nine distinct zinc-nickel-tin films with different compositions have been galvanostatically electrodeposited. The films have been characterized by scanning electron microscopy(SEM) and energy dispersive spectrometry(EDS). Their corrosion potentials and densities have been estimated using Tafel extrapolation. Next, the electrochemical behaviors of the films(deposited through the electrolytes containing 0, 6, 8, and10 g/L SnCl2?6H2O) have been examined based on cyclic voltammetry(CV) measurements. Further, these films have been immersed in 3.5 wt%Na Cl solution for 1 h, 1 d, 7 d, 14 d, 28 d, and 42 d followed by application of Tafel extrapolation and electrochemical impedance spectroscopy(EIS) tests on each aged sample. Finally, to analyze the morphologies and the compositions of the oxide films covering the surfaces of the 42-d aged films, FT-IR and SEM analyses have been performed. The results indicated that the Zn–Ni–Sn film produced through the bath including 6g/L SnCl2?6H2 O exhibits superior corrosion resistance because of the high Ni content in the presence of Sn that promotes the barrier protection capability of the deposit.展开更多
文摘1.3 mm SWP-B弹簧钢丝生产的扭转弹簧在客户装配前发生断裂,弹簧断口以沿晶断裂为主。分析材料化学成分和组织,对弹簧断口附近和正常组织进行纵截面显微硬度测定,采用扫描电镜对断口进行宏观和微观检查,并用X射线能谱仪对断口进行分析。结果表明:扭转弹簧在电镀锌初期局部产生非正常组织马氏体,由于马氏体存在组织应力,与在酸洗和电镀锌时弹簧基体中的氢造成的内应力相互作用,导致扭转弹簧出现裂纹并滞后断裂。
基金Project supported by the Office of the New Material and Clean Chemistry Research of the Tabriz University
文摘A A cerium-based chemical conversion process was studied. First, zinc coating obtained from a free-cyanide alkaline bath, with derivative of imidazol with new brightener, was investigated, zinc-plated steel specimens were treated with a solution of 50 mmol· L^-1 Ce（NO3 ）3 The corrosion behavior of bare and treated mild galvanized steel was evaluated during exposure to 0.5 mol · L^-1 NaCl for different immersion time, using Tafel polarization curves and electrochemical impedance spectroscopy （EIS） measurements. The surface morphology of the coating was studied using scanning electron microscopy （SEM）. The composition and chemical percent of the coating were examined by X-ray dispersion energy （EDAX）. The results of these measurements showed that the newly developed cerium-based conversion coating process was a promising candidate for replacing the conventional chromate treatments used at present for galvanized steel.
文摘钢丝的耐腐蚀性能影响桥梁缆索的使用寿命。采用电镀锌和热镀锌铝对4.3 mm SWRS82B钢丝进行表面处理,对电镀锌和热镀锌铝钢丝在0.1 mol/L HCl溶液中进行耐腐蚀性能研究,对腐蚀后的形貌进行观察并分析腐蚀机理。结果表明:电镀锌后钢丝表面粗糙度Ra=1.024μm,热镀锌铝后钢丝表面粗糙度Ra=0.637μm,热镀锌铝试样表面粗糙度明显小于电镀锌试样;电镀锌的锌层厚度约为15μm,扩散层为35μm,热镀锌铝合金的镀锌层约为24μm,扩散层为50μm,热镀锌铝试样的耐腐蚀性能明显优于电镀锌试样。
文摘Strip-shaped chromatic aberration defects on the surface of an electro-galvanized fingerprint-resistant sheet were systematically studied using Thermo-Calc thermodynamic calculations,scanning electron microscope and X-ray diffractometer analyses,and rapid heat treatment simulation technology.The formation mechanism of these defects was also analyzed.The results show a strong correlation between the defects and the uneven distribution of the Fe(001)component on the surface of the steel substrate.The relatively high proportion of Fe(001)components on the surface of the steel substrate affects the distribution density of the Zn crystal cells in different orientations during the electrodeposition process,which causes the reflection intensity of the light of the galvanized layer to differ from various visual perspectives,and macroscopic strip-shaped chromatic aberration defects are finally formed.The high proportion of the Fe(001)component on the surface of the steel substrate is mainly related to the following two factors.First,when the strip steel is hot-rolled,the finishing hot-rolling temperature is close to theγ→αphase transition temperature.When the local temperature on the upper surface of the strip steel is low,γ+αtwo-phase rolling easily occurs,and this results in an uneven stress distribution between theγandαphases after the hot-rolling process.This uneven distribution of hot-rolling stress results in the formation of a coarse grain structure in the local area on the surface of the hot-rolled sheet,which strongly affects the subsequent cold rolling and annealing process,and the annealed steel sheet substrate ultimately contains a greater proportion of the Fe(001)component.And second,a fast cooling rate(>10 K/s)during the slow cooling stage in the continuous annealing process inhibits the transformation of the Fe(001)to the Fe(111)component on the surface of the cold-rolled steel sheet,and it is then not possible to effectively eliminate the influence of the unevenly distributed Fe(001)component on th
文摘Nine distinct zinc-nickel-tin films with different compositions have been galvanostatically electrodeposited. The films have been characterized by scanning electron microscopy(SEM) and energy dispersive spectrometry(EDS). Their corrosion potentials and densities have been estimated using Tafel extrapolation. Next, the electrochemical behaviors of the films(deposited through the electrolytes containing 0, 6, 8, and10 g/L SnCl2?6H2O) have been examined based on cyclic voltammetry(CV) measurements. Further, these films have been immersed in 3.5 wt%Na Cl solution for 1 h, 1 d, 7 d, 14 d, 28 d, and 42 d followed by application of Tafel extrapolation and electrochemical impedance spectroscopy(EIS) tests on each aged sample. Finally, to analyze the morphologies and the compositions of the oxide films covering the surfaces of the 42-d aged films, FT-IR and SEM analyses have been performed. The results indicated that the Zn–Ni–Sn film produced through the bath including 6g/L SnCl2?6H2 O exhibits superior corrosion resistance because of the high Ni content in the presence of Sn that promotes the barrier protection capability of the deposit.
