Silicone rubber composites filled with FeSiAI alloys and multi-walled carbon nanotubes （MWCNT）/graphite have been prepared for the first time by a coating process. The complex permittivity and permeability of the co...Silicone rubber composites filled with FeSiAI alloys and multi-walled carbon nanotubes （MWCNT）/graphite have been prepared for the first time by a coating process. The complex permittivity and permeability of the composites were measured with a vector network analyzer in a 1-4 GHz frequency range, and the DC electric conductivity was measured by a standard four-point contact method. These parameters were then used to calculate the reflection loss （RL） and shielding effectiveness （SE） of the composites. The results showed that the added MWCNT increased the permittivity and permeability of composites in the L-band, while the added graphite increased only the permittivity. The variation lies in the interactions between two carbonous absorbents. Addition of 1 wt% MWCNT enhanced the RL in the L-band （minimum -5.7 dB at 1 ram, -7.3 dB at 1.5 ram）, while the addition of graphite did not. Addition of MWCNT as well as graphite reinforced the shielding property of the composites （maximum SE 13.3 dB at 1 ram, 18.3 dB at 1.5 ram） owing to the increase of conductivity. The addition of these carbonous materials could hold the promise of enforcing the absorption and shielding property of the absorbers.展开更多
Pyrolytic carbon （PyC） was infiltrated into silicon nitride （Si3N4） ceramics by precursor infiltration and pyrolysis （PIP） of phenolic resin, and Ni nanoparticles were added into the phenolic resin to change the...Pyrolytic carbon （PyC） was infiltrated into silicon nitride （Si3N4） ceramics by precursor infiltration and pyrolysis （PIP） of phenolic resin, and Ni nanoparticles were added into the phenolic resin to change the electric conductivity of Si3N4-PyC composite ceramics. Dielectric permittivity, electromagnetic interference （EMI） shielding and absorption properties of Si3N4-PyC composite ceramics were studied as a function of Ni content at 8.2-12.4 GHz （X-band）. When Ni nanoparticles were added into phenolic resin, the electric conductivity of the prepared composite ceramics decreased with increasing Ni content, which was attributed to the decrease of graphitization degree of PyC. The decrease in electric conductivity led to the decrease in both permittivity and EMI shielding effectiveness. Since too high permittivity is harmful to the impendence match and results in the strong reflection, the electromagnetic wave absorption property of Si3N4-PyC composite ceramics increases with increasing Ni content. When the content of Ni nanoparticles added into phenolic resin was 2 wt%, the composite ceramics possessed the lowest electric conductivity and displayed the most excellent absorption property with a minimum reflection loss as low as -28.9 dB.展开更多
基金supported by the National Natural Science Foundation of China (No. 50805005)the National High Technology Research and Development Program of China ("863 Program", No. 2009AA043804)+1 种基金the Foundation for the Author of National Excellent Doctoral Dissertation of PR China (No. 2007B32)the Innovation Foundation of BUAA for Ph.D. Graduates
文摘Silicone rubber composites filled with FeSiAI alloys and multi-walled carbon nanotubes （MWCNT）/graphite have been prepared for the first time by a coating process. The complex permittivity and permeability of the composites were measured with a vector network analyzer in a 1-4 GHz frequency range, and the DC electric conductivity was measured by a standard four-point contact method. These parameters were then used to calculate the reflection loss （RL） and shielding effectiveness （SE） of the composites. The results showed that the added MWCNT increased the permittivity and permeability of composites in the L-band, while the added graphite increased only the permittivity. The variation lies in the interactions between two carbonous absorbents. Addition of 1 wt% MWCNT enhanced the RL in the L-band （minimum -5.7 dB at 1 ram, -7.3 dB at 1.5 ram）, while the addition of graphite did not. Addition of MWCNT as well as graphite reinforced the shielding property of the composites （maximum SE 13.3 dB at 1 ram, 18.3 dB at 1.5 ram） owing to the increase of conductivity. The addition of these carbonous materials could hold the promise of enforcing the absorption and shielding property of the absorbers.
基金supported by the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University,China(No.KB200920)the Natural Science Foundation of China(No.50972119)the Programme of Introducing Talents of Discipline to Universities, China(No.B08040)
文摘Pyrolytic carbon （PyC） was infiltrated into silicon nitride （Si3N4） ceramics by precursor infiltration and pyrolysis （PIP） of phenolic resin, and Ni nanoparticles were added into the phenolic resin to change the electric conductivity of Si3N4-PyC composite ceramics. Dielectric permittivity, electromagnetic interference （EMI） shielding and absorption properties of Si3N4-PyC composite ceramics were studied as a function of Ni content at 8.2-12.4 GHz （X-band）. When Ni nanoparticles were added into phenolic resin, the electric conductivity of the prepared composite ceramics decreased with increasing Ni content, which was attributed to the decrease of graphitization degree of PyC. The decrease in electric conductivity led to the decrease in both permittivity and EMI shielding effectiveness. Since too high permittivity is harmful to the impendence match and results in the strong reflection, the electromagnetic wave absorption property of Si3N4-PyC composite ceramics increases with increasing Ni content. When the content of Ni nanoparticles added into phenolic resin was 2 wt%, the composite ceramics possessed the lowest electric conductivity and displayed the most excellent absorption property with a minimum reflection loss as low as -28.9 dB.
