A novel metal-organic framework, namely [Zn（C20H13OsP）]n （1）, has been hydro- thermally synthesized through the reaction of 5-（oxidediphenylphosphino）isophthalic acid （H2L） with Zn（II） salt. The title compou...A novel metal-organic framework, namely [Zn（C20H13OsP）]n （1）, has been hydro- thermally synthesized through the reaction of 5-（oxidediphenylphosphino）isophthalic acid （H2L） with Zn（II） salt. The title compound crystallizes in monoclinic, space group P21/c with a = 11.0966（10）, b = 14.5651（14）, c = 14.7311（15） A, fl = 130.022（6）°, C2oH13OsPZn, Mr = 429.64, V= 1823.3（3） ./k3, Dc = 1.565 g/cm3, F（000） = 872, g = 1.463 mm＂1, S = 1.054 and Z = 4. The final R = 0.0270 and wR = 0.0739 for 2769 observed reflections with 1 〉 20（/）. In the title complex, the Zn2（CO2）2 binuclear clusters are linked by L2- ligands to result in a pillared layer structure in the bc plane, which is a （4,4）-net composed of helical chains with opposite chirality by sharing Zn2（CO2）2 units. Adjacent＇layers are further associated together through Zn-O bonds involving the metal center and the oxygen atom of P=O group to achieve a 3D architecture, in which one-dimensional qua＆angled channel displays the interweaving of two pairs of coaxial double-helical chains with opposite chirality. The luminescence property and thermogravimetric analysis of the title complex were investigated.展开更多
This paper presents a new type of double-helical rotor wave energy converter(WEC),which consists of two isolated sets of helical rotor structures(inner and outer).This device can generate electricity by using the risi...This paper presents a new type of double-helical rotor wave energy converter(WEC),which consists of two isolated sets of helical rotor structures(inner and outer).This device can generate electricity by using the rising and falling energy of a wave.The rotors are simulated and optimized by Fluent.Each rotor’s blades are simulated and analyzed,which are separately changed in terms of helix angle,shape,and thickness.The simulation result shows that,for both inner and outer helical rotors,the energy harvesting efficiency is the highest when the blade helix angle is 45°.Triangular blades have better hydrodynamic performance than square and circular blades.The energy harvesting efficiency of 15 mm thick blades is higher than that of 75 mm thick blades.展开更多
基金supported by the International Technology Cooperation Project of Science and Technology Department of Henan Province(No.124300510050)the National Natural Science Foundation of China(No.5119003)
文摘A novel metal-organic framework, namely [Zn（C20H13OsP）]n （1）, has been hydro- thermally synthesized through the reaction of 5-（oxidediphenylphosphino）isophthalic acid （H2L） with Zn（II） salt. The title compound crystallizes in monoclinic, space group P21/c with a = 11.0966（10）, b = 14.5651（14）, c = 14.7311（15） A, fl = 130.022（6）°, C2oH13OsPZn, Mr = 429.64, V= 1823.3（3） ./k3, Dc = 1.565 g/cm3, F（000） = 872, g = 1.463 mm＂1, S = 1.054 and Z = 4. The final R = 0.0270 and wR = 0.0739 for 2769 observed reflections with 1 〉 20（/）. In the title complex, the Zn2（CO2）2 binuclear clusters are linked by L2- ligands to result in a pillared layer structure in the bc plane, which is a （4,4）-net composed of helical chains with opposite chirality by sharing Zn2（CO2）2 units. Adjacent＇layers are further associated together through Zn-O bonds involving the metal center and the oxygen atom of P=O group to achieve a 3D architecture, in which one-dimensional qua＆angled channel displays the interweaving of two pairs of coaxial double-helical chains with opposite chirality. The luminescence property and thermogravimetric analysis of the title complex were investigated.
基金Supported by the National Key Research and Development Program of China(2019YFB1504402).
文摘This paper presents a new type of double-helical rotor wave energy converter(WEC),which consists of two isolated sets of helical rotor structures(inner and outer).This device can generate electricity by using the rising and falling energy of a wave.The rotors are simulated and optimized by Fluent.Each rotor’s blades are simulated and analyzed,which are separately changed in terms of helix angle,shape,and thickness.The simulation result shows that,for both inner and outer helical rotors,the energy harvesting efficiency is the highest when the blade helix angle is 45°.Triangular blades have better hydrodynamic performance than square and circular blades.The energy harvesting efficiency of 15 mm thick blades is higher than that of 75 mm thick blades.
