Rock bursts signify extreme behavior in coal mine strata and severely threaten the safety of the lives of miners, as well as the effectiveness and productivity of miners. In our study, an elastic-plastic-brittle model...Rock bursts signify extreme behavior in coal mine strata and severely threaten the safety of the lives of miners, as well as the effectiveness and productivity of miners. In our study, an elastic-plastic-brittle model for the deformation and failure of coal/rock was established through theoretical analyses, laboratory experiments and field testing, simulation and other means, which perfectly predict sudden and delayed rock bursts. Based on electromagnetic emission (EME), acoustic emission (AE) and microseism (MS) effects in the process from deformation until impact rupture of coal-rock combination samples, a multi-parameter identification of premonitory technology was formed, largely depending on these three forms of emission. Thus a system of classification for forecasting rock bursts in space and time was established. We have presented the intensity weakening theory for rock bursts and a strong-soft-strong (3S) structural model for controlling the impact on rock surrounding roadways, with the objective of laying a theoretical foundation and establishing references for parameters for the weakening control of rock bursts. For the purpose of prevention, key technical parameters of directional hydraulic fracturing are revealed. Based on these results, as well as those from deep-hole controlled blasting in coal seams and rock, integrated control techniques were established and anti-impact hydraulic props, suitable for roadways subject to hazards from rockbursts have also been developed. These technologies have been widely used in most coal mines in China, subject to these hazards and have achieved remarkable economic and social benefits.展开更多
Objective To evaluate the environmental and technical efficiencies of China's industrial sectors and provide appropriate advice for policy makers in the context of rapid economic growth and concurrent serious environ...Objective To evaluate the environmental and technical efficiencies of China's industrial sectors and provide appropriate advice for policy makers in the context of rapid economic growth and concurrent serious environmental damages caused by industrial pollutants. Methods A data of envelopment analysis (DEA) framework crediting both reduction of pollution outputs and expansion of good outputs was designed as a model to compute environmental efficiency of China's regional industrial systems. Results As shown by the geometric mean of environmental efficiency, if other inputs were made constant and good outputs were not to be improved, the air pollution outputs would have the potential to be decreased by about 60% in the whole China. Conclusion Both environmental and technical efficiencies have the potential to be greatly improved in China, which may provide some advice for policy-makers.展开更多
An overview of the development and current status of the directional solidification process assisted by liquid metal cooling (LMC) has been presented in this paper. The driving force of the rapid development of the ...An overview of the development and current status of the directional solidification process assisted by liquid metal cooling (LMC) has been presented in this paper. The driving force of the rapid development of the LMC process has been analyzed by considering the demands of (1) newer technologies that can provide higher thermal gradients for alleviated segregation in advanced alloy systems, and (2) better production yield of the large directionally solidified superalloy components. The brief history of the industrialization of the LMC process has been reviewed, followed by the discussion on the LMC parameters including selection of the cooling media, using of the dynamic baffle, and the influence of withdrawal rates and so on. The microstructure and mechanical properties of the traditional superalloys processed by LMC, as well as the new alloys particularly developed for LMC process were then described. Finally, future aspects concerning the LMC process have been summarized.展开更多
Animal and clinical studies have confirmed the therapeutic effect of bone marrow mesenchymal stem cells on cerebral ischemia, but their mechanisms of action remain poorly understood. Here, we summarize the transplanta...Animal and clinical studies have confirmed the therapeutic effect of bone marrow mesenchymal stem cells on cerebral ischemia, but their mechanisms of action remain poorly understood. Here, we summarize the transplantation approaches, directional migration, differentiation, replacement, neural circuit reconstruction,angiogenesis, neurotrophic factor secretion, apoptosis, immunomodulation, multiple mechanisms of action,and optimization strategies for bone marrow mesenchymal stem cells in the treatment of ischemic stroke.We also explore the safety of bone marrow mesenchymal stem cell transplantation and conclude that bone marrow mesenchymal stem cell transplantation is an important direction for future treatment of cerebral ischemia. Determining the optimal timing and dose for the transplantation are important directions for future research.展开更多
In this research,molecular structure models were developed respectively for Shenhua coal vitrinite concentrates(SDV)and inertinite concentrates(SDI),on the basis of information on constitutional unit of Shenhau coal a...In this research,molecular structure models were developed respectively for Shenhua coal vitrinite concentrates(SDV)and inertinite concentrates(SDI),on the basis of information on constitutional unit of Shenhau coal and elemental analysis results obtained from^(13)C-NMR analysis characterization,FTIR analysis characterization,X-ray diffraction XRD and XPS analysis characterization.It can be observed from characterization data and molecular structure models that the structure of SDV and SDI is dominated by aromatic hydrocarbon,with aromaticity of SDI higher than that of SDV;SDV mainly consists of small molecule basic structure unit,while SDI is largely made from macromolecular structure unit.Based on bond-level parameters of the molecular model,the research found through the autoclave experiment that vitrinite liquefaction process goes under thermodynamics control and inertinite liquefaction process under dynamics control.The research developed an efficient directional direct coal liquefaction technology based on the maceral characteristics of Shenhua coal,which can effectively improve oil yield and lower gas yield.展开更多
The multi-terminal VSC-HVDC grid is believed to be widely applied in the future power system. The dc line protection is the key technique for operation security and power supply reliability of the dc grid. In this pap...The multi-terminal VSC-HVDC grid is believed to be widely applied in the future power system. The dc line protection is the key technique for operation security and power supply reliability of the dc grid. In this paper, the single-ended protections, namely, the traveling-wave based protection and transient-variable based protection, as well as the pilot protections, mainly including the directional pilot protection and current differential protection, are discussed in detail. With the analyzed protections, the effective main and back-up protection strategy can be configured for the dc line in multi-terminal VSC-HVDC grid.展开更多
A set of granitic and amphibole mylonite are exposed in the Altyn Tagh fault zone. The preliminary study shows that these rocks are the product of the syntectonic anatexis in the process of the left-lat- eral strike-s...A set of granitic and amphibole mylonite are exposed in the Altyn Tagh fault zone. The preliminary study shows that these rocks are the product of the syntectonic anatexis in the process of the left-lat- eral strike-slip shear, and are the result of the ductile transpression. There are two types of zircon sorted from the mylonite formed with syn-shear anatexis. Among them, one is the anatectic long co-lumnar zircon and another is the residual metamorphic sub-rounded columnar zircon. Two groups of age for single zircon measured by ion microprobe (SHRIMP) are obtained: one is 461-547 Ma for the sub-rounded columnar residual metamorphic zircon, and the other is 239-244 Ma for the long-columnar anatectic zircon. This type of zircon is direc-tionally spread in rock, and the long axis direction of its crystal is identical to that of stretching lineation, represent-ing the direction of tectonic stress in the process of the strike-slip. 40Ar-39Ar age of the directional growth horn-blende in the same mylonite展开更多
The process of grain selection in the spiral selector was investigated by both a ProCAST simulation based on a cellular automaton finite element(CAFE) model and experimental confirmation.The results show that the he...The process of grain selection in the spiral selector was investigated by both a ProCAST simulation based on a cellular automaton finite element(CAFE) model and experimental confirmation.The results show that the height of starter block,the spiral diameter and initial angle play an important role in grain selection.The dimension of selector should be maintained in a stable range to optimize the grain orientation and select a single crystal efficiently.A selector which can efficiently select a single crystal had been successfully designed.Grain orientation fluctuation in the spiral part was also studied by means of the variation of thermal condition.展开更多
An experimental scheme for the generation of directional focusing waves in a wave basin is established in this paper. The effects of the directional range, frequency width and center frequency on the wave focusing are...An experimental scheme for the generation of directional focusing waves in a wave basin is established in this paper. The effects of the directional range, frequency width and center frequency on the wave focusing are studied. The distribution of maximum amplitude and the evolution of time series and spectra during wave packet propagation and the variation of water surface parameters are extensively investigated. The results reveal that the characteristics of focusing waves are significantly influenced by wave directionality and that the breaking criteria for directional waves are distinctly different from those for unidirectional waves.展开更多
Bioinspired superhydrophobic surfaces have attracted many industrial and academic interests in recent years.Inspired by unique superhydrophobicity and anisotropic friction properties of snake scale surfaces,this study...Bioinspired superhydrophobic surfaces have attracted many industrial and academic interests in recent years.Inspired by unique superhydrophobicity and anisotropic friction properties of snake scale surfaces,this study explores the feasibility to produce a bionic superhydrophobic stainless steel surface via laser precision engineering,which allows the realization of directional superhydrophobicity and dynamic control of its water transportation.Dynamic mechanism of water sliding on hierarchical snake scale structures is studied,which is the key to reproduce artificially bioinspired multifunctional materials with great potentials to be used for water harvesting,droplet manipulation,pipeline transportation,and vehicle acceleration.展开更多
In this study, the phase field method was used to study the multi-controlling factors of dendrite growth in directional solidification. The effects of temperature gradient, propelling velocity, thermal disturbance and...In this study, the phase field method was used to study the multi-controlling factors of dendrite growth in directional solidification. The effects of temperature gradient, propelling velocity, thermal disturbance and growth orientation angle on the growth morphology of the dendritic growth in the solid/liquid interface were discussed. It is found that the redistribution of solute leads to multilevel cavity and multilevel fusion to form multistage solute segregation, and the increase of temperature gradient and propelling velocity can accelerate the dendrite growth of directional solidification, and also make the second dendrites more developed, which reduces the primary distance and the solute segregation. When the temperature gradient is large, the solid-liquid interface will move forward in a flat interface mode,and the thermal disturbance does not affect the steady state behavior of the directionally solidified dendrite tip. It only promotes the generation and growth of the second dendrites and forms the asymmetric dendrite. Meanwhile, it is found that the inclined dendrite is at a disadvantage in the competitive growth compared to the normal dendrite, and generally it will disappear. When the inclination angle is large, the initial primary dendrite may be eliminated by its secondary or third dendrite.展开更多
It is still a great challenge to effectively optimize the electronic structure of photocatalysts for the sustainable and efficient conversion of solar energy to H2 energy.To resolve this issue,we report on the optimiz...It is still a great challenge to effectively optimize the electronic structure of photocatalysts for the sustainable and efficient conversion of solar energy to H2 energy.To resolve this issue,we report on the optimization of the electronic structure of hollow-concave carbon nitride(C3N4)by deviating the sp2-hybridized structure of its tri-s-triazine component from the two-dimensional plane.The embedded CuInS2 into C3N4(CuInS2@C3N4)demonstrates an increased light-capturing capability and the promoted directional transfer of the charge carrier.Research results reveal that the hollow structure with an apparent potential difference between the concave and convex C3N4 drives the directional transfer of the photoinduced electrons from the Cu 2p orbital of CuInS2 to the N 1s orbital of C3N4 with the S-scheme principle.The H2 evolution efficiency over CuInS2@C3N4 is up to 373μmol?h^-1 g^-1 under visible irradiation,which is 1.57 and 1.35 times higher than those over the bulk g-C3N4 with 1 wt%Pt(238μmol?h^-1 g^-1)and g-C3N4 with 3 wt%Pd(276μmol?h^-1 g^-1),respectively.This suggests that the apparent potential difference of the hollow C3N4 results in an efficient reaction between the photogenerated electrons and H2O.This work supplies a new strategy for enhancing the sustainable solar conversion performance of carbon nitride,which can also be suitable for other semiconductors.展开更多
The presence of seam gas in the form of methane or carbon dioxide presents a hazard to underground coal mining operations.In-seam drilling has been undertaken for the past three decades for gas drainage to reduce the ...The presence of seam gas in the form of methane or carbon dioxide presents a hazard to underground coal mining operations.In-seam drilling has been undertaken for the past three decades for gas drainage to reduce the risk of gas outburst and lower the concentrations of seam gas in the underground ventilation.The drilling practices have reflected the standards of the times and have evolved with the development of technology and equipment and the needs to provide a safe mining environment underground.Early practice was to adapt equipment from other felds,with rotary drilling being the only form of drilling available.This form of drainage allowed various levels of gas drainage coverage but with changing emphasis,research and development within the coal industry has created specifc equipment,technology and practices to accurately place in-seam boreholes to provide effcient and effective gas drainage.Research into gas content determination established a standard for the process and safe levels for mining operations to continue.Surveying technology improved from the wire-line,single-shot Eastman survey instruments which was time-dependent on borehole depth to electronic instruments located in the drill string which transmitted accurate survey data to the drilling crew without time delays.This allowed improved directional control and increased drilling rates.Directional drilling technology has now been established as the industry standard to provide effective gas drainage drilling.Exploration was identifed as an additional beneft with directional drilling as it has the ability to provide exploration data from long boreholes.The ability of the technology to provide safe and reliable means to investigate the need for inrush protection and water drainage ahead of mining has been established.Directional drilling technology has now been introduced to the Chinese coal industry for gas drainage through a practice of auditing,design,supply,training and ongoing support.Experienced drilling crews can offer site specifc gas draina展开更多
This paper proposes a novel directional pilot protection method based on the transient energy for bipolar HVDC line.Supposing the positive direction of current is from DC bus to the DC line,in the case of an internal ...This paper proposes a novel directional pilot protection method based on the transient energy for bipolar HVDC line.Supposing the positive direction of current is from DC bus to the DC line,in the case of an internal line fault,the transient energies detected on both sides of the line are all negative within a short time,which denotes the positive direction fault;while for an external fault,the transient energy on one end is positive,which means a negative direction fault,but the transient energy on the opposite end is negative,which indicates that the fault direction is positive.According to these characteristics,an integration criterion identifying fault direction is constructed.In addition,through setting a fixed energy threshold,the faulted line and lightning disturbance can also be discriminated.Simulation results from UHVDC transmission system show the validity of the proposed protection method.展开更多
Numercial simulation of sea surface directional wave spectra under typhoon wind forcing in the South China Sea (SCS) was carreid out using the WAVEWATCH-Ⅲ wave model. The simulation was run for 210 h until the Typh...Numercial simulation of sea surface directional wave spectra under typhoon wind forcing in the South China Sea (SCS) was carreid out using the WAVEWATCH-Ⅲ wave model. The simulation was run for 210 h until the Typhoon Damrey (2005) approached Vietnam. The simulated data were compared with buoy observations, which were obtained in the northwest sea area of Hainan Island. The results show that the significant wave height, wave direction, wave length and frequency spetra agree well with buoy observations. The spatial characteristics of the signifciant wave height, mean wave period, mean wave length, wave age and directional spectra depend on the relative position from the typhoon center. Also, the misalignment between local wind and wave directions were investigated.展开更多
Row crops are a kind of typical vegetation canopy between discrete canopy and continuous canopy.Kimes et al.studied the directional thermal radiation of row crops using the geometrical optical model,which simplified r...Row crops are a kind of typical vegetation canopy between discrete canopy and continuous canopy.Kimes et al.studied the directional thermal radiation of row crops using the geometrical optical model,which simplified row structure as'box'and neglected the gap among foliage and did not consider the emissivity effects.In this work we take account of the gaps along illumination and viewing directions and propose a bi-direction gap model on the basis of the idea of gap probability of discrete vegetation canopy introduced by'Li-Strahler'and inter-correlation of continuous vegetation developed by Kuusk.It can be used to explain'hot spot'effects in thermal infrared region.The gap model has been validated by field experiment on winter wheat planted in shape of rows and results show that the gap model is better than Kimes'model in describing the directionality of thermal infrared emission for row crops.展开更多
基金Project 2010CB226805 supported by the National Natural Science Foundation of Chinaprovided by the National Basic Research Program of China (2010CB226805)+1 种基金the National Eleventh Five-Year Key Science & Technology Project (2006BAK04B02, 2006BAK04B06)the National Natural Science Foundation of China (50474068), are gratefully acknowledged
文摘Rock bursts signify extreme behavior in coal mine strata and severely threaten the safety of the lives of miners, as well as the effectiveness and productivity of miners. In our study, an elastic-plastic-brittle model for the deformation and failure of coal/rock was established through theoretical analyses, laboratory experiments and field testing, simulation and other means, which perfectly predict sudden and delayed rock bursts. Based on electromagnetic emission (EME), acoustic emission (AE) and microseism (MS) effects in the process from deformation until impact rupture of coal-rock combination samples, a multi-parameter identification of premonitory technology was formed, largely depending on these three forms of emission. Thus a system of classification for forecasting rock bursts in space and time was established. We have presented the intensity weakening theory for rock bursts and a strong-soft-strong (3S) structural model for controlling the impact on rock surrounding roadways, with the objective of laying a theoretical foundation and establishing references for parameters for the weakening control of rock bursts. For the purpose of prevention, key technical parameters of directional hydraulic fracturing are revealed. Based on these results, as well as those from deep-hole controlled blasting in coal seams and rock, integrated control techniques were established and anti-impact hydraulic props, suitable for roadways subject to hazards from rockbursts have also been developed. These technologies have been widely used in most coal mines in China, subject to these hazards and have achieved remarkable economic and social benefits.
文摘Objective To evaluate the environmental and technical efficiencies of China's industrial sectors and provide appropriate advice for policy makers in the context of rapid economic growth and concurrent serious environmental damages caused by industrial pollutants. Methods A data of envelopment analysis (DEA) framework crediting both reduction of pollution outputs and expansion of good outputs was designed as a model to compute environmental efficiency of China's regional industrial systems. Results As shown by the geometric mean of environmental efficiency, if other inputs were made constant and good outputs were not to be improved, the air pollution outputs would have the potential to be decreased by about 60% in the whole China. Conclusion Both environmental and technical efficiencies have the potential to be greatly improved in China, which may provide some advice for policy-makers.
文摘An overview of the development and current status of the directional solidification process assisted by liquid metal cooling (LMC) has been presented in this paper. The driving force of the rapid development of the LMC process has been analyzed by considering the demands of (1) newer technologies that can provide higher thermal gradients for alleviated segregation in advanced alloy systems, and (2) better production yield of the large directionally solidified superalloy components. The brief history of the industrialization of the LMC process has been reviewed, followed by the discussion on the LMC parameters including selection of the cooling media, using of the dynamic baffle, and the influence of withdrawal rates and so on. The microstructure and mechanical properties of the traditional superalloys processed by LMC, as well as the new alloys particularly developed for LMC process were then described. Finally, future aspects concerning the LMC process have been summarized.
基金supported by the Natural Science Foundation of Heilongjiang Province of China,No.H2015083a grant from Higher Education Reform Project of Mudanjaing Medical University of China,No.2013016
文摘Animal and clinical studies have confirmed the therapeutic effect of bone marrow mesenchymal stem cells on cerebral ischemia, but their mechanisms of action remain poorly understood. Here, we summarize the transplantation approaches, directional migration, differentiation, replacement, neural circuit reconstruction,angiogenesis, neurotrophic factor secretion, apoptosis, immunomodulation, multiple mechanisms of action,and optimization strategies for bone marrow mesenchymal stem cells in the treatment of ischemic stroke.We also explore the safety of bone marrow mesenchymal stem cell transplantation and conclude that bone marrow mesenchymal stem cell transplantation is an important direction for future treatment of cerebral ischemia. Determining the optimal timing and dose for the transplantation are important directions for future research.
基金Supported by the National Engineering Labo-ratory of Direct Coal Liquefaction(MZY-16).
文摘In this research,molecular structure models were developed respectively for Shenhua coal vitrinite concentrates(SDV)and inertinite concentrates(SDI),on the basis of information on constitutional unit of Shenhau coal and elemental analysis results obtained from^(13)C-NMR analysis characterization,FTIR analysis characterization,X-ray diffraction XRD and XPS analysis characterization.It can be observed from characterization data and molecular structure models that the structure of SDV and SDI is dominated by aromatic hydrocarbon,with aromaticity of SDI higher than that of SDV;SDV mainly consists of small molecule basic structure unit,while SDI is largely made from macromolecular structure unit.Based on bond-level parameters of the molecular model,the research found through the autoclave experiment that vitrinite liquefaction process goes under thermodynamics control and inertinite liquefaction process under dynamics control.The research developed an efficient directional direct coal liquefaction technology based on the maceral characteristics of Shenhua coal,which can effectively improve oil yield and lower gas yield.
基金supported by the National Natural Science Foundation of China(No.U1866205).
文摘The multi-terminal VSC-HVDC grid is believed to be widely applied in the future power system. The dc line protection is the key technique for operation security and power supply reliability of the dc grid. In this paper, the single-ended protections, namely, the traveling-wave based protection and transient-variable based protection, as well as the pilot protections, mainly including the directional pilot protection and current differential protection, are discussed in detail. With the analyzed protections, the effective main and back-up protection strategy can be configured for the dc line in multi-terminal VSC-HVDC grid.
基金The work was supported by the National Key Basic Research Project (Grant No. G1998040800) Sino-France Collaborative Project of "Altun Shan-Qilianshan" Tectonic Evolution and Lithosphere Shearing.
文摘A set of granitic and amphibole mylonite are exposed in the Altyn Tagh fault zone. The preliminary study shows that these rocks are the product of the syntectonic anatexis in the process of the left-lat- eral strike-slip shear, and are the result of the ductile transpression. There are two types of zircon sorted from the mylonite formed with syn-shear anatexis. Among them, one is the anatectic long co-lumnar zircon and another is the residual metamorphic sub-rounded columnar zircon. Two groups of age for single zircon measured by ion microprobe (SHRIMP) are obtained: one is 461-547 Ma for the sub-rounded columnar residual metamorphic zircon, and the other is 239-244 Ma for the long-columnar anatectic zircon. This type of zircon is direc-tionally spread in rock, and the long axis direction of its crystal is identical to that of stretching lineation, represent-ing the direction of tectonic stress in the process of the strike-slip. 40Ar-39Ar age of the directional growth horn-blende in the same mylonite
基金supported by the National Basic Research Program of China ("973 Program") under grant Nos. (2010CB631200 and 2010CB631206)the National Natural Science Foundation of China undergrant No.50931004
文摘The process of grain selection in the spiral selector was investigated by both a ProCAST simulation based on a cellular automaton finite element(CAFE) model and experimental confirmation.The results show that the height of starter block,the spiral diameter and initial angle play an important role in grain selection.The dimension of selector should be maintained in a stable range to optimize the grain orientation and select a single crystal efficiently.A selector which can efficiently select a single crystal had been successfully designed.Grain orientation fluctuation in the spiral part was also studied by means of the variation of thermal condition.
基金This research was partially supported by the National Natural Science Foundation of China (Grant No. 50379002),the Korea Research Council of Public Science and Technology (Principal R&D Program) and Korea Ministry of Science and Technology (International Collaboration Research Program)
文摘An experimental scheme for the generation of directional focusing waves in a wave basin is established in this paper. The effects of the directional range, frequency width and center frequency on the wave focusing are studied. The distribution of maximum amplitude and the evolution of time series and spectra during wave packet propagation and the variation of water surface parameters are extensively investigated. The results reveal that the characteristics of focusing waves are significantly influenced by wave directionality and that the breaking criteria for directional waves are distinctly different from those for unidirectional waves.
基金This work was supported by the Advanced Remanufacturing and Technology Centre(ARTC)under its RIE2020 Advanced Manufacturing and Engineering(AME)IAF PP Grant(No.A19C2a0019).
文摘Bioinspired superhydrophobic surfaces have attracted many industrial and academic interests in recent years.Inspired by unique superhydrophobicity and anisotropic friction properties of snake scale surfaces,this study explores the feasibility to produce a bionic superhydrophobic stainless steel surface via laser precision engineering,which allows the realization of directional superhydrophobicity and dynamic control of its water transportation.Dynamic mechanism of water sliding on hierarchical snake scale structures is studied,which is the key to reproduce artificially bioinspired multifunctional materials with great potentials to be used for water harvesting,droplet manipulation,pipeline transportation,and vehicle acceleration.
基金financially supported by the National Natural Science Foundation of China(NSFC)under grant Nos.51774254,51774253,U1610123,51574207,51574206the Science and Technology Major Project of Shanxi Province under grant No.MC2016-06
文摘In this study, the phase field method was used to study the multi-controlling factors of dendrite growth in directional solidification. The effects of temperature gradient, propelling velocity, thermal disturbance and growth orientation angle on the growth morphology of the dendritic growth in the solid/liquid interface were discussed. It is found that the redistribution of solute leads to multilevel cavity and multilevel fusion to form multistage solute segregation, and the increase of temperature gradient and propelling velocity can accelerate the dendrite growth of directional solidification, and also make the second dendrites more developed, which reduces the primary distance and the solute segregation. When the temperature gradient is large, the solid-liquid interface will move forward in a flat interface mode,and the thermal disturbance does not affect the steady state behavior of the directionally solidified dendrite tip. It only promotes the generation and growth of the second dendrites and forms the asymmetric dendrite. Meanwhile, it is found that the inclined dendrite is at a disadvantage in the competitive growth compared to the normal dendrite, and generally it will disappear. When the inclination angle is large, the initial primary dendrite may be eliminated by its secondary or third dendrite.
基金Study was supported by the National Natural Science Foundation of China(21871155)the K.C.Wong Magna Fund in Ningbo University,Fan 3315 PlanYongjiang Scholar Plan~~
文摘It is still a great challenge to effectively optimize the electronic structure of photocatalysts for the sustainable and efficient conversion of solar energy to H2 energy.To resolve this issue,we report on the optimization of the electronic structure of hollow-concave carbon nitride(C3N4)by deviating the sp2-hybridized structure of its tri-s-triazine component from the two-dimensional plane.The embedded CuInS2 into C3N4(CuInS2@C3N4)demonstrates an increased light-capturing capability and the promoted directional transfer of the charge carrier.Research results reveal that the hollow structure with an apparent potential difference between the concave and convex C3N4 drives the directional transfer of the photoinduced electrons from the Cu 2p orbital of CuInS2 to the N 1s orbital of C3N4 with the S-scheme principle.The H2 evolution efficiency over CuInS2@C3N4 is up to 373μmol?h^-1 g^-1 under visible irradiation,which is 1.57 and 1.35 times higher than those over the bulk g-C3N4 with 1 wt%Pt(238μmol?h^-1 g^-1)and g-C3N4 with 3 wt%Pd(276μmol?h^-1 g^-1),respectively.This suggests that the apparent potential difference of the hollow C3N4 results in an efficient reaction between the photogenerated electrons and H2O.This work supplies a new strategy for enhancing the sustainable solar conversion performance of carbon nitride,which can also be suitable for other semiconductors.
文摘The presence of seam gas in the form of methane or carbon dioxide presents a hazard to underground coal mining operations.In-seam drilling has been undertaken for the past three decades for gas drainage to reduce the risk of gas outburst and lower the concentrations of seam gas in the underground ventilation.The drilling practices have reflected the standards of the times and have evolved with the development of technology and equipment and the needs to provide a safe mining environment underground.Early practice was to adapt equipment from other felds,with rotary drilling being the only form of drilling available.This form of drainage allowed various levels of gas drainage coverage but with changing emphasis,research and development within the coal industry has created specifc equipment,technology and practices to accurately place in-seam boreholes to provide effcient and effective gas drainage.Research into gas content determination established a standard for the process and safe levels for mining operations to continue.Surveying technology improved from the wire-line,single-shot Eastman survey instruments which was time-dependent on borehole depth to electronic instruments located in the drill string which transmitted accurate survey data to the drilling crew without time delays.This allowed improved directional control and increased drilling rates.Directional drilling technology has now been established as the industry standard to provide effective gas drainage drilling.Exploration was identifed as an additional beneft with directional drilling as it has the ability to provide exploration data from long boreholes.The ability of the technology to provide safe and reliable means to investigate the need for inrush protection and water drainage ahead of mining has been established.Directional drilling technology has now been introduced to the Chinese coal industry for gas drainage through a practice of auditing,design,supply,training and ongoing support.Experienced drilling crews can offer site specifc gas draina
基金National Natural Science Foundation of China(51677109)National Key Research and Development Program of China(2016YFB0906003).
文摘This paper proposes a novel directional pilot protection method based on the transient energy for bipolar HVDC line.Supposing the positive direction of current is from DC bus to the DC line,in the case of an internal line fault,the transient energies detected on both sides of the line are all negative within a short time,which denotes the positive direction fault;while for an external fault,the transient energy on one end is positive,which means a negative direction fault,but the transient energy on the opposite end is negative,which indicates that the fault direction is positive.According to these characteristics,an integration criterion identifying fault direction is constructed.In addition,through setting a fixed energy threshold,the faulted line and lightning disturbance can also be discriminated.Simulation results from UHVDC transmission system show the validity of the proposed protection method.
文摘Numercial simulation of sea surface directional wave spectra under typhoon wind forcing in the South China Sea (SCS) was carreid out using the WAVEWATCH-Ⅲ wave model. The simulation was run for 210 h until the Typhoon Damrey (2005) approached Vietnam. The simulated data were compared with buoy observations, which were obtained in the northwest sea area of Hainan Island. The results show that the significant wave height, wave direction, wave length and frequency spetra agree well with buoy observations. The spatial characteristics of the signifciant wave height, mean wave period, mean wave length, wave age and directional spectra depend on the relative position from the typhoon center. Also, the misalignment between local wind and wave directions were investigated.
基金This work was supported by the Special Funds for Major State Basic Research Project(Grant No.G2000077900).
文摘Row crops are a kind of typical vegetation canopy between discrete canopy and continuous canopy.Kimes et al.studied the directional thermal radiation of row crops using the geometrical optical model,which simplified row structure as'box'and neglected the gap among foliage and did not consider the emissivity effects.In this work we take account of the gaps along illumination and viewing directions and propose a bi-direction gap model on the basis of the idea of gap probability of discrete vegetation canopy introduced by'Li-Strahler'and inter-correlation of continuous vegetation developed by Kuusk.It can be used to explain'hot spot'effects in thermal infrared region.The gap model has been validated by field experiment on winter wheat planted in shape of rows and results show that the gap model is better than Kimes'model in describing the directionality of thermal infrared emission for row crops.