The constitutive model Hou/Lux,based on continuum damage mechanics and on the material model Lubby2 is presented and the damage,the healing of damage,the tertiary creep and the creep rupture of rock salt described. An...The constitutive model Hou/Lux,based on continuum damage mechanics and on the material model Lubby2 is presented and the damage,the healing of damage,the tertiary creep and the creep rupture of rock salt described. An application shows how phenomena observed in laboratory tests on axially perforated cylinder sample, such as softening, dilatancy, spalling and radial deformation into the axial bore as well as spalling can be numerically simulated with the model Hou/Lux. Furthermore,it is then evaluated against the measured permeability and stress profiles of a 37-year-old drift at the Sondershausen minein,Germany. Satisfactory agreement is obtained between the calculated and measured data.展开更多
Aggregate engineering of non-covalent networks endows supramolecular polymers with thermo-mechanical versatility,stimuli-responsive phase transitions and intrinsic damage-healing capabilities.However,most non-covalent...Aggregate engineering of non-covalent networks endows supramolecular polymers with thermo-mechanical versatility,stimuli-responsive phase transitions and intrinsic damage-healing capabilities.However,most non-covalent networks are vulnerable at elevated temperatures,which suppresses the robustness of supramolecular polymers.Herein,ureidocytosine(UCy)motifs,which are capable of forming extensive non-covalent networks and thus robust molecular aggregates via multivalent hydrogen bonds and aromatic stackings,are proposed to enable precise programming of the thermo-mechanical versatility.Molecular simulations reveal that the enthalpic contributions from the UCy aggregates play dominant roles to compensate the entropic loss from the redistributions of polymeric spacers and stabilize the non-covalent networks over wide temperature windows.Such aggregate-level strategy offers prospects for applications which require thermo-mechanical versatility of supramolecular polymers,such as 3D printing,microfabrication and damage-healing coating.展开更多
Based on the thermal kinetic and mass conservation, a series of controlling equations for the finite element are derived and related programs are developed to simulate the damage microcrack healing process controlled ...Based on the thermal kinetic and mass conservation, a series of controlling equations for the finite element are derived and related programs are developed to simulate the damage microcrack healing process controlled by surface diffusion. Two kinds of typical models for microcrack splitting are proposed, i.e., the grain boundary energy existing on the crack surface and residual stresses applying on the crack surface. And the conditions of microcrack splitting in the two models are given as a function of the microcrack aspect ratio. The microcrack with traction-free surfaces will directly evolve into a spheroid.展开更多
文摘The constitutive model Hou/Lux,based on continuum damage mechanics and on the material model Lubby2 is presented and the damage,the healing of damage,the tertiary creep and the creep rupture of rock salt described. An application shows how phenomena observed in laboratory tests on axially perforated cylinder sample, such as softening, dilatancy, spalling and radial deformation into the axial bore as well as spalling can be numerically simulated with the model Hou/Lux. Furthermore,it is then evaluated against the measured permeability and stress profiles of a 37-year-old drift at the Sondershausen minein,Germany. Satisfactory agreement is obtained between the calculated and measured data.
基金supported by the Research Grant Council of Hong Kong(No.CityU 11305219)City University of Hong Kong(Nos.6000685 and 9610348)Research Grant Council of Hong Kong(No.C1025-14E).
文摘Aggregate engineering of non-covalent networks endows supramolecular polymers with thermo-mechanical versatility,stimuli-responsive phase transitions and intrinsic damage-healing capabilities.However,most non-covalent networks are vulnerable at elevated temperatures,which suppresses the robustness of supramolecular polymers.Herein,ureidocytosine(UCy)motifs,which are capable of forming extensive non-covalent networks and thus robust molecular aggregates via multivalent hydrogen bonds and aromatic stackings,are proposed to enable precise programming of the thermo-mechanical versatility.Molecular simulations reveal that the enthalpic contributions from the UCy aggregates play dominant roles to compensate the entropic loss from the redistributions of polymeric spacers and stabilize the non-covalent networks over wide temperature windows.Such aggregate-level strategy offers prospects for applications which require thermo-mechanical versatility of supramolecular polymers,such as 3D printing,microfabrication and damage-healing coating.
基金The project supported by the National Natural Science Foundation of China(19972053 and 59889101)the National Outstanding Young Scientist Fund of China(59925104)
文摘Based on the thermal kinetic and mass conservation, a series of controlling equations for the finite element are derived and related programs are developed to simulate the damage microcrack healing process controlled by surface diffusion. Two kinds of typical models for microcrack splitting are proposed, i.e., the grain boundary energy existing on the crack surface and residual stresses applying on the crack surface. And the conditions of microcrack splitting in the two models are given as a function of the microcrack aspect ratio. The microcrack with traction-free surfaces will directly evolve into a spheroid.
