Fe+ ion beams with the energy of 110 keV were implanted into films of L(+)-cysteine (HSCH2CH(NH2)COOH). One of the single crystals grown in hydrochloric acid solution with the implanted samples through slow evaporatio...Fe+ ion beams with the energy of 110 keV were implanted into films of L(+)-cysteine (HSCH2CH(NH2)COOH). One of the single crystals grown in hydrochloric acid solution with the implanted samples through slow evaporation was structurally characterized by the X-ray crystallography. The crystal is monoclinic, space group C2, with a = 1.8534(4) nm, b=0.5234(1) nm, c = 0.7212(1) nm, β=103.722°, V = 0.67965(3) nm3, Z = 4, F(000) = 144.0, Dclac = 1.763 g·cm-3, μ (MoKa) = 1.06 mm-1, T = 293(2) K.R = 0.0379, wR = 0.0835 for 660 observed reflections (I】2σ(I)). The structural formula of the crystal compound is (CH2CH(NH2)NO2)ClFe (Mr = 180.38u). Products of heavy ion beam irradiation were purified and it was directly confirmed that the implanted Fe+ ions had been deposited in the novel molecules. The same doses of Fe+ ion beams of the same energy were implanted into films of L(+)-cysteine hydrochloride monohydrate. FTIR spectroscopy of the implanted samples proved that some of the original molecules were展开更多
基金This work was supported by the National Natural Science Foundation of China (Grant No.19975060)the Scientific Foundation of "95" Fundamental Research from the Chinese Academy of Sciences (Grant No. KJ952-S1-424).
文摘Fe+ ion beams with the energy of 110 keV were implanted into films of L(+)-cysteine (HSCH2CH(NH2)COOH). One of the single crystals grown in hydrochloric acid solution with the implanted samples through slow evaporation was structurally characterized by the X-ray crystallography. The crystal is monoclinic, space group C2, with a = 1.8534(4) nm, b=0.5234(1) nm, c = 0.7212(1) nm, β=103.722°, V = 0.67965(3) nm3, Z = 4, F(000) = 144.0, Dclac = 1.763 g·cm-3, μ (MoKa) = 1.06 mm-1, T = 293(2) K.R = 0.0379, wR = 0.0835 for 660 observed reflections (I】2σ(I)). The structural formula of the crystal compound is (CH2CH(NH2)NO2)ClFe (Mr = 180.38u). Products of heavy ion beam irradiation were purified and it was directly confirmed that the implanted Fe+ ions had been deposited in the novel molecules. The same doses of Fe+ ion beams of the same energy were implanted into films of L(+)-cysteine hydrochloride monohydrate. FTIR spectroscopy of the implanted samples proved that some of the original molecules were
