随着环境污染与化石能源枯竭的问题凸显,电-气-热多能互补的综合能源系统(integrated energy systems,IES)成为了研究热点。针对IES能量流计算中数学模型详细性问题以及未来电制气(power-to-gas,P2G)广泛应用带来的异质气体注入问题,构...随着环境污染与化石能源枯竭的问题凸显,电-气-热多能互补的综合能源系统(integrated energy systems,IES)成为了研究热点。针对IES能量流计算中数学模型详细性问题以及未来电制气(power-to-gas,P2G)广泛应用带来的异质气体注入问题,构建了能反映不同气体成分下P2G效率与不同温度条件下电热泵(electric heat pump,EHP)能效的详细模型,考虑了不同成分气体注入对气体参数与系统运行状态的影响以及相应的建模,在传统天然气系统稳态分析方法的基础上介绍了可以反映异质气体注入对网络状态影响的稳态分析方法。以此为基础提出了计及异质气体混合与耦合元件详细模型的电-气-热IES能量流交替迭代计算方法,并采用电力系统分析综合程序(power system analysis software package,PSASP)实现电力系统的潮流计算。最后通过仿真算例验证了所提方法的有效性。展开更多
A regional ocean atmosphere coupled model (ROAM) is developed through coupler OASIS3,and is composed of regional climate model RegCM3 and CREM (Climate version of Regional Eta Model) as its atmospheric component and o...A regional ocean atmosphere coupled model (ROAM) is developed through coupler OASIS3,and is composed of regional climate model RegCM3 and CREM (Climate version of Regional Eta Model) as its atmospheric component and of a revised Princeton ocean model (POM2000) as its oceanic component.The performance of the ROAM over the western North Pacific summer monsoon region is assessed by the case simulation of warm season in 1998.Impacts of different atmospheric model components on the performance of ROAM are investigated.Compared with stand-alone simulation,CREM (RegCM3) produces more (or less) rainfall over ocean area with inclusion of the air-sea coupling.Different biases of rainfall are caused by the different biases of SST derived from the coupled simulation.Warm (or cold) SST bias simulated by CREM_CPL (RegCM3_CPL) increases (or decreases) the evaporation at sea surface,then increases (or decreases) the rainfall over ocean.The analyses suggest that the biases of vertical profile of temperature and specific humidity in stand-alone simulations may be responsible for the SST biases in regional coupled simulations.Compared with reanalysis data,the warmer (or colder) and moister (or dryer) lower troposphere simulated in CREM (RegCM3) produces less (or more) sea surface latent heat flux.Meanwhile,the more unstable (or stable) lower troposphere produces less (or more) cloudiness at low-level,which increases (or decreases) the solar radiation reaching on the sea surface.CREM (RegCM3) forced by observed SST overestimates (or underestimates) the sea surface net heat flux,implying a potential warm (or cold) heat source.After coupling with POM2000,the warm (or cold) heat source would further increase (or decrease) the SST.The biases of vertical profile of temperature and specific humidity may be ascribed to the different representation of cumulus convection in atmospheric models.展开更多
A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as th...A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as the catalyst and dimethyl carbonate(DMC)as the solvent,a diverse range of 2-acylbenzoic acid derivatives and primary amines worked well to give the C3-phosphinoyl-functionalized 3,3-disubstituted isoindolinones with the yield range of 61%-87%.Advantages of this transformation include green catalyst and solvent,available starting materials,broad substrate scope,high efficiency and operational simplicity with water as the sole by-product.The strategy achieved an efficient and green molecular fragment assembly to access isoindolinones,which would provide opportunities for the synthesis of potential biologically active molecules in a green manner.展开更多
The construction of C-N bonds is of great importance in the fields of biology,medicine,chemistry and materials science.Here,the replacement of organic base from pyridine to piperidine in the Knoevenagel condensation p...The construction of C-N bonds is of great importance in the fields of biology,medicine,chemistry and materials science.Here,the replacement of organic base from pyridine to piperidine in the Knoevenagel condensation process unexpectedly yields a series of novel organic molecules containing C-N bonds.Interestingly,the synthesis method does not require any external transition-metals catalysis,and photo-/electro-catalysis.Additionally,when the new compound 1b is added as a third component to a well-known binary system of PM6:Y6,the efficiency of the organic solar cell is significantly improved,resulting in an outstanding efficiency of 18.0%,which is one of the highest values reported to date for PM6:Y6-based ternary organic solar cells.展开更多
Ureas are widely used in drugs,materials and catalysts because of their diamide structure,which can form strong hydrogen bonds.Therefore,it is of great scientific significance to develop efficient and green methods fo...Ureas are widely used in drugs,materials and catalysts because of their diamide structure,which can form strong hydrogen bonds.Therefore,it is of great scientific significance to develop efficient and green methods for the synthesis of urea compounds,especially unsymmetrical ureas.Here,we have disclosed novel and highly efficient three-component coupling reactions of organic halides,sodium cyanate and amines enabled by nickel/photoredox dual catalysis for the preparation of unsymmetrical ureas.The reaction features simple and safe operations,broad substrate scopes,and product diversities.It allows the facile synthesis of N-aryl/vinyl ureas from readily available,user-friendly feedstocks under mild conditions(27 examples,36%—98%yields).In addition,this method is further derived to alcohols as nucleophiles to synthesize a series of carbamates(15 examples,40%—95%yields).The mechanism experiment shows that the isocyanate produced by the coupling of halide and sodium cyanate may be the key intermediate in this reaction.展开更多
Component-based software engineering is concerned with the develop-ment of software that can satisfy the customer prerequisites through reuse or inde-pendent development.Coupling and cohesion measurements are primaril...Component-based software engineering is concerned with the develop-ment of software that can satisfy the customer prerequisites through reuse or inde-pendent development.Coupling and cohesion measurements are primarily used to analyse the better software design quality,increase the reliability and reduced system software complexity.The complexity measurement of cohesion and coupling component to analyze the relationship between the component module.In this paper,proposed the component selection framework of Hexa-oval optimization algorithm for selecting the suitable components from the repository.It measures the interface density modules of coupling and cohesion in a modular software sys-tem.This cohesion measurement has been taken into two parameters for analyz-ing the result of complexity,with the help of low cohesion and high cohesion.In coupling measures between the component of inside parameters and outside parameters.Thefinal process of coupling and cohesion,the measured values were used for the average calculation of components parameter.This paper measures the complexity of direct and indirect interaction among the component as well as the proposed algorithm selecting the optimal component for the repository.The better result is observed for high cohesion and low coupling in compo-nent-based software engineering.展开更多
The ground state of osmium monoxide(OsO) has long been controversial. In this paper, the low-lying Λ–S and ? electronic states of OsO have been comprehensively studied by the high-precision multi-reference calculati...The ground state of osmium monoxide(OsO) has long been controversial. In this paper, the low-lying Λ–S and ? electronic states of OsO have been comprehensively studied by the high-precision multi-reference calculations. The ground state of OsO is unexpectedly the closed-shell1Σ+state with a double bond instead of the previously reported3Φ or5Σ+state;after including the spin–orbit coupling effects, the ground state becomes3Π2. With the help of the theoretical spectroscopic constants and transition dipole moments, the emission spectra in the region of 405 nm–875 nm are assigned.Our results will facilitate the future studies of absorption and emission spectra of OsO.展开更多
State estimation(SE)is essential for combined heat and electric networks(CHENs)to provide a global and selfconsistent solution for multi-energy flow analysis.This paper proposes an SE approach for CHEN based on steady...State estimation(SE)is essential for combined heat and electric networks(CHENs)to provide a global and selfconsistent solution for multi-energy flow analysis.This paper proposes an SE approach for CHEN based on steady models of electric networks(ENs)and district heating networks(DHNs).A range of coupling components are considered.The performance of the proposed estimator is evaluated using Monte Carlo simulations and case studies.Results show that a relationship between the measurements from ENs and DHNs can improve the estimation accuracy for the entire network by using the combined SE model,especially when ENs and DHNs are strongly coupled.The coupling constraints could also provide extra redundancy to detect bad data in the boundary injection measurements of both networks.An analysis of computation time shows that the proposed method is suitable for online applications.展开更多
文摘随着环境污染与化石能源枯竭的问题凸显,电-气-热多能互补的综合能源系统(integrated energy systems,IES)成为了研究热点。针对IES能量流计算中数学模型详细性问题以及未来电制气(power-to-gas,P2G)广泛应用带来的异质气体注入问题,构建了能反映不同气体成分下P2G效率与不同温度条件下电热泵(electric heat pump,EHP)能效的详细模型,考虑了不同成分气体注入对气体参数与系统运行状态的影响以及相应的建模,在传统天然气系统稳态分析方法的基础上介绍了可以反映异质气体注入对网络状态影响的稳态分析方法。以此为基础提出了计及异质气体混合与耦合元件详细模型的电-气-热IES能量流交替迭代计算方法,并采用电力系统分析综合程序(power system analysis software package,PSASP)实现电力系统的潮流计算。最后通过仿真算例验证了所提方法的有效性。
基金supported by the Ocean Projects of Public Science and Technology Research Funds (Grant No. 201105019-3)
文摘A regional ocean atmosphere coupled model (ROAM) is developed through coupler OASIS3,and is composed of regional climate model RegCM3 and CREM (Climate version of Regional Eta Model) as its atmospheric component and of a revised Princeton ocean model (POM2000) as its oceanic component.The performance of the ROAM over the western North Pacific summer monsoon region is assessed by the case simulation of warm season in 1998.Impacts of different atmospheric model components on the performance of ROAM are investigated.Compared with stand-alone simulation,CREM (RegCM3) produces more (or less) rainfall over ocean area with inclusion of the air-sea coupling.Different biases of rainfall are caused by the different biases of SST derived from the coupled simulation.Warm (or cold) SST bias simulated by CREM_CPL (RegCM3_CPL) increases (or decreases) the evaporation at sea surface,then increases (or decreases) the rainfall over ocean.The analyses suggest that the biases of vertical profile of temperature and specific humidity in stand-alone simulations may be responsible for the SST biases in regional coupled simulations.Compared with reanalysis data,the warmer (or colder) and moister (or dryer) lower troposphere simulated in CREM (RegCM3) produces less (or more) sea surface latent heat flux.Meanwhile,the more unstable (or stable) lower troposphere produces less (or more) cloudiness at low-level,which increases (or decreases) the solar radiation reaching on the sea surface.CREM (RegCM3) forced by observed SST overestimates (or underestimates) the sea surface net heat flux,implying a potential warm (or cold) heat source.After coupling with POM2000,the warm (or cold) heat source would further increase (or decrease) the SST.The biases of vertical profile of temperature and specific humidity may be ascribed to the different representation of cumulus convection in atmospheric models.
基金the National Natural Science Foundation of China(No.22001034)Jiangxi Provincial Natural Science Foundation(No.20212BAB213001).
文摘A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as the catalyst and dimethyl carbonate(DMC)as the solvent,a diverse range of 2-acylbenzoic acid derivatives and primary amines worked well to give the C3-phosphinoyl-functionalized 3,3-disubstituted isoindolinones with the yield range of 61%-87%.Advantages of this transformation include green catalyst and solvent,available starting materials,broad substrate scope,high efficiency and operational simplicity with water as the sole by-product.The strategy achieved an efficient and green molecular fragment assembly to access isoindolinones,which would provide opportunities for the synthesis of potential biologically active molecules in a green manner.
基金supported by the National Natural Science Foundation of China(U21A20331)the National Science Fund for Distinguished Young Scholars(21925506)the Zhejiang Provincial Natural Science Foundation of China(LQ22E030013)。
文摘The construction of C-N bonds is of great importance in the fields of biology,medicine,chemistry and materials science.Here,the replacement of organic base from pyridine to piperidine in the Knoevenagel condensation process unexpectedly yields a series of novel organic molecules containing C-N bonds.Interestingly,the synthesis method does not require any external transition-metals catalysis,and photo-/electro-catalysis.Additionally,when the new compound 1b is added as a third component to a well-known binary system of PM6:Y6,the efficiency of the organic solar cell is significantly improved,resulting in an outstanding efficiency of 18.0%,which is one of the highest values reported to date for PM6:Y6-based ternary organic solar cells.
基金the National Natural Science Foundation of Chinaa(Nos.22271113,92256301,21822103,91956201,21820102003 and 21602052)the Natural Science Foundation of Hubei Province(No.2022CFB413)the fund from Central China Normal University for support of this research.
文摘Ureas are widely used in drugs,materials and catalysts because of their diamide structure,which can form strong hydrogen bonds.Therefore,it is of great scientific significance to develop efficient and green methods for the synthesis of urea compounds,especially unsymmetrical ureas.Here,we have disclosed novel and highly efficient three-component coupling reactions of organic halides,sodium cyanate and amines enabled by nickel/photoredox dual catalysis for the preparation of unsymmetrical ureas.The reaction features simple and safe operations,broad substrate scopes,and product diversities.It allows the facile synthesis of N-aryl/vinyl ureas from readily available,user-friendly feedstocks under mild conditions(27 examples,36%—98%yields).In addition,this method is further derived to alcohols as nucleophiles to synthesize a series of carbamates(15 examples,40%—95%yields).The mechanism experiment shows that the isocyanate produced by the coupling of halide and sodium cyanate may be the key intermediate in this reaction.
基金We deeply acknowledge Taif University for Supporting this research through Taif University Researchers Supporting Project number(TURSP-2020/231),Taif University,Taif,Saudi Arabia.
文摘Component-based software engineering is concerned with the develop-ment of software that can satisfy the customer prerequisites through reuse or inde-pendent development.Coupling and cohesion measurements are primarily used to analyse the better software design quality,increase the reliability and reduced system software complexity.The complexity measurement of cohesion and coupling component to analyze the relationship between the component module.In this paper,proposed the component selection framework of Hexa-oval optimization algorithm for selecting the suitable components from the repository.It measures the interface density modules of coupling and cohesion in a modular software sys-tem.This cohesion measurement has been taken into two parameters for analyz-ing the result of complexity,with the help of low cohesion and high cohesion.In coupling measures between the component of inside parameters and outside parameters.Thefinal process of coupling and cohesion,the measured values were used for the average calculation of components parameter.This paper measures the complexity of direct and indirect interaction among the component as well as the proposed algorithm selecting the optimal component for the repository.The better result is observed for high cohesion and low coupling in compo-nent-based software engineering.
基金Project supported by the National Natural Science Foundation of China (Grant No. 22073072)the Double First-Class University Construction Project of Northwest University。
文摘The ground state of osmium monoxide(OsO) has long been controversial. In this paper, the low-lying Λ–S and ? electronic states of OsO have been comprehensively studied by the high-precision multi-reference calculations. The ground state of OsO is unexpectedly the closed-shell1Σ+state with a double bond instead of the previously reported3Φ or5Σ+state;after including the spin–orbit coupling effects, the ground state becomes3Π2. With the help of the theoretical spectroscopic constants and transition dipole moments, the emission spectra in the region of 405 nm–875 nm are assigned.Our results will facilitate the future studies of absorption and emission spectra of OsO.
基金This work was supported in part by the National Natural Science Foundation of China(61733010)the China Postdoctoral Science Foundation(2019M650675).
文摘State estimation(SE)is essential for combined heat and electric networks(CHENs)to provide a global and selfconsistent solution for multi-energy flow analysis.This paper proposes an SE approach for CHEN based on steady models of electric networks(ENs)and district heating networks(DHNs).A range of coupling components are considered.The performance of the proposed estimator is evaluated using Monte Carlo simulations and case studies.Results show that a relationship between the measurements from ENs and DHNs can improve the estimation accuracy for the entire network by using the combined SE model,especially when ENs and DHNs are strongly coupled.The coupling constraints could also provide extra redundancy to detect bad data in the boundary injection measurements of both networks.An analysis of computation time shows that the proposed method is suitable for online applications.
